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Exploring the High-Entropy Oxide Composition Space: Insights through Comparing Experimental with Theoretical Models for the Oxygen Evolution Reaction ACS Catal. (IF 12.9) Pub Date : 2024-04-18 Vladislav A. Mints, Katrine L. Svane, Jan Rossmeisl, Matthias Arenz
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Substantial Impact of Spin State Evolution in OER/ORR Catalyzed by Fe–N–C ACS Catal. (IF 12.9) Pub Date : 2024-04-18 Mingyuan Yu, Ang Li, Erjun Kan, Cheng Zhan
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Revealing Formaldehyde-Mediated Methanol-to-Aromatics Reactions over Zn-Modified Zeolites by Observing the Oxygenated and Polyunsaturated Intermediates ACS Catal. (IF 12.9) Pub Date : 2024-04-18 Tianci Xiao, Jinsong Luo, Weixiong Huang, Lilin Lu, Chengyuan Liu, Yang Pan
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Unraveling Two Pathways for Electrocatalytic Acetonitrile Reduction ACS Catal. (IF 12.9) Pub Date : 2024-04-18 Qi Zhang, Zunjian Ke, Dong He, Chaoning Huang, Huan Dai, Chongyang Tang, Boling Liu, Xiangheng Xiao
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Ce4+/Ce3+ Redox-Promoted Electron Transfer for Efficient Neutral H2O2 Electrosynthesis from Two-Electron Oxygen Reduction ACS Catal. (IF 12.9) Pub Date : 2024-04-18 Sohee Kim, Young Jin Sa
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Catalytic N-Acylation for Access to N–N Atropisomeric N-Aminoindoles: Choice of Acylation Reagents and Mechanistic Insights ACS Catal. (IF 12.9) Pub Date : 2024-04-18 Chaoyang Song, Chen Pang, Youlin Deng, Hui Cai, Xiuhai Gan, Yonggui Robin Chi
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Functional Enhancement of Flavin-Containing Monooxygenase through Machine Learning Methodology ACS Catal. (IF 12.9) Pub Date : 2024-04-18 Takuma Matsushita, Shinji Kishimoto, Kodai Hara, Hiroshi Hashimoto, Hideki Yamaguchi, Yutaka Saito, Kenji Watanabe
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Improving the Catalytic Efficiency of a GH5 Processive Endoglucanase by a Combinatorial Strategy Using Consensus Mutagenesis and Loop Engineering ACS Catal. (IF 12.9) Pub Date : 2024-04-18 Kemin Lv, Xiaozhou Li, Kequan Chen, Bin Wu, Bingfang He, Gerhard Schenk
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Interplay between Catalyst Corrosion and Homogeneous Reactive Oxygen Species in Electrochemical Ozone Production ACS Catal. (IF 12.9) Pub Date : 2024-04-18 Rayan Alaufey, Lingyan Zhao, Andrew Lindsay, Tana Siboonruang, Qin Wu, John A. Keith, Ezra Wood, Maureen Tang
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Rational Design of Heteroatom-Doped Fe–N–C Single-Atom Catalysts for Oxygen Reduction Reaction via Simple Descriptor ACS Catal. (IF 12.9) Pub Date : 2024-04-18 Jin Liu, Jiqin Zhu, Haoxiang Xu, Daojian Cheng
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Mapping of the Reaction Trajectory Catalyzed by Class I Ketol-Acid Reductoisomerase ACS Catal. (IF 12.9) Pub Date : 2024-04-18 Xin Lin, Thierry Lonhienne, You Lv, Julia L. Kurz, Ross P. McGeary, Gerhard Schenk, Luke W. Guddat
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Water-Mediated Photocatalytic Coproduction of Diesel Fuel Additives and Hydrogen from Dimethyl Ether ACS Catal. (IF 12.9) Pub Date : 2024-04-17 Shiyang Liu, Yike Huang, Nengchao Luo, Jian Zhang, Botao Qiao, Feng Wang
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Differentiating Plasmon-Enhanced Chemical Reactions on AgPd Hollow Nanoplates through Surface-Enhanced Raman Spectroscopy ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Sulin Jiao, Kun Dai, Lucas V. Besteiro, Hongen Gao, Xuan Chen, Weichao Wang, Yuan Zhang, Chuntai Liu, Ignacio Pérez-Juste, Jorge Pérez-Juste, Isabel Pastoriza-Santos, Guangchao Zheng
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Arginine Kinase Activates Arginine for Phosphorylation by Pyramidalization and Polarization ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Fabio Falcioni, Robert W. Molt, Jr., Yi Jin, Jonathan P. Waltho, Sam Hay, Nigel G. J. Richards, G. Michael Blackburn
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Coupling Cu+ Species and Zr Single Atoms for Synergetic Catalytic Transfer Hydrodeoxygenation of 5-Hydroxymethylfurfural ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Lincai Peng, Yixuan Yu, Shenghan Gao, Miaomiao Wang, Junhua Zhang, Rui Zhang, Wenlong Jia, Yong Sun, Huai Liu
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Asymmetric Photoenolization/Diels–Alder Reaction of 2-Methylbenzaldehydes and 2-Alkylbenzophenones with Chromones ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Yuhao Mo, Lichao Ning, Zhe Luo, Liangkun Yang, Shi Tang, Shunxi Dong, Qi-Lin Zhou, Xiaoming Feng
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Halide Perovskites for Photoelectrochemical Water Splitting and CO2 Reduction: Challenges and Opportunities ACS Catal. (IF 12.9) Pub Date : 2024-04-15 Krzysztof Bienkowski, Renata Solarska, Linh Trinh, Justyna Widera-Kalinowska, Basheer Al-Anesi, Maning Liu, G. Krishnamurthy Grandhi, Paola Vivo, Burcu Oral, Beyza Yılmaz, Ramazan Yıldırım
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Key Role of CO Coverage for Chain Growth in Co-Based Fischer–Tropsch Synthesis ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Konstantijn T. Rommens, G.T. Kasun Kalhara Gunasooriya, Mark Saeys
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Plasma Catalysis for Hydrogen Production: A Bright Future for Decarbonization ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Ni Wang, Hope O. Otor, Gerardo Rivera-Castro, Jason C. Hicks
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Photoenzymatic Redox-Neutral Radical Hydrosulfonylation Initiated by FMN ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Linye Jiang, Dannan Zheng, Xiaoyang Chen, Dong Cui, Xinyu Duan, Zhiguo Wang, Jingyan Ge, Jian Xu
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Catalytic Consequences of Protons in Methanol Oxidative Dehydrogenation on Molybdenum-Based Polyoxometalate Clusters ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Guangming Cai, Ya-Huei Cathy Chin
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Coupling Waste Plastic Upgrading and CO2 Photoreduction to High-Value Chemicals by a Binuclear Re–Ru Heterogeneous Catalyst ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Mei Li, Shengbo Zhang
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Photocatalytic Regeneration of Reactive Cofactors with InP Quantum Dots for the Continuous Chemical Synthesis ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Indra Narayan Chakraborty, Vanshika Jain, Pradyut Roy, Pawan Kumar, Chathakudath P. Vinod, Pramod P. Pillai
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Synergistic Organoboron/Palladium Cocatalyzed Dehydrative Couplings of Azoles with Allylic Alcohols: A Combined Experimental and Computational Mechanistic Investigation ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Matthew T. Zambri, Teh Ren Hou, Sofia Jdanova, Mark S. Taylor
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Construction of Diazo Compounds via Catalytic [3 + 2] Annulation of Vinyldiazoacetates and Their Synthetic Applications ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Ming Bao, Diana Victoria Navarrete Carriola, Daniel Wherritt, Michael P. Doyle
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Steric Effects on the Oxygen Reduction Reaction with Cobalt Porphyrin Atropisomers ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Tao Liu, Haonan Qin, Yuhan Xu, Xinyang Peng, Wei Zhang, Rui Cao
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Enantioselective Synthesis of Axially Chiral Diaryl Ethers through Chiral Phosphoric Acid-Catalyzed Desymmetric Acylation with Azlactones ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Jiawei Xu, Wei Lin, Hanliang Zheng, Xin Li
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CsPbBr3 Perovskite Polyhedral Nanocrystal Photocatalysts for Decarboxylative Alkylation via Csp3–H Bond Activation of Unactivated Ethers ACS Catal. (IF 12.9) Pub Date : 2024-04-16 Soumya Mondal, Souvik Banerjee, Suman Bera, Subal Mondal, Siba P. Midya, Rajkumar Jana, Rakesh Kumar Behera, Ayan Datta, Narayan Pradhan, Pradyut Ghosh
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Sensitized and Self-Sensitized Photocatalytic CO2 Reduction to HCO2– and CO under Visible Light with Ni(II) CNC-Pincer Catalysts ACS Catal. (IF 12.9) Pub Date : 2024-04-15 Sonya Y. Manafe, Nghia Le, Ethan C. Lambert, Christine Curiac, Dinesh Nugegoda, Sanjit Das, Leigh Anna Hunt, Fengrui Qu, Logan M. Whitt, Igor Fedin, Nathan I. Hammer, Charles Edwin Webster, Jared H. Delcamp, Elizabeth T. Papish
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Stereoselective access to β‐gem‐difluorinated alcohols through enzymatic reduction Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-17 Lucas Bacheley, Julien Boutet, Gérard Guillamot, Pierre Gilles, Juliette Martin, Phannarath Phansavath, Virginie Ratovelomanana-Vidal
We report here a mild and efficient process to access diversely functionalized enantioenriched b‐gemdifluorinated (S)‐alcohols by using biocatalytic reduction in > 99% yield and enantiomeric excesses ranging from 96% to >99%. This novel approach involves enzymatic reduction of α‐gem‐difluorinated heterocyclic and carbocyclic ketone derivatives as well as an acyclic gem‐difluorinated β‐ketosulfone and
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Manganese‐Mediated Electrooxidative Ring‐Opening Azidation of Cyclobutanol Derivatives with TMSN3 Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-17 Wenchao Gao, Jie Yang, Yong Teng, Wendian Li, Wenguang Li, Ting Li
A Mn‐electrocatalytic ring‐opening azidation of tert‐cyclobutanols has been developed. The regioselective method is applicable for the azidation of a diverse array of cyclobutanols to provide γ‐azido ketones in 23‐91% yields under chemical oxidants‐free reaction conditions. Detailed mechanistic studies suggest the process of Mn‐mediated alkoxy radical generation followed by β‐scission to form carbon‐centered
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Dinuclear Cu(I) molecular electrocatalyst for CO2-to-C3 product conversion Nat. Catal. (IF 37.8) Pub Date : 2024-04-15 Naonari Sakamoto, Keita Sekizawa, Soichi Shirai, Takamasa Nonaka, Takeo Arai, Shunsuke Sato, Takeshi Morikawa
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Visualizing the structural evolution of individual active sites in MoS2 during electrocatalytic hydrogen evolution reaction Nat. Catal. (IF 37.8) Pub Date : 2024-04-15 Teng-Xiang Huang, Xin Cong, Si-Si Wu, Jiang-Bin Wu, Yi-Fan Bao, Mao-Feng Cao, Liwen Wu, Miao-Ling Lin, Xiang Wang, Ping-Heng Tan, Bin Ren
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Catalytic Dinitrogen Reduction to Silylamines by Molybdenum Nitride Complexes Bearing a Diphenolate N-Heterocyclic Carbene Ligand ACS Catal. (IF 12.9) Pub Date : 2024-04-15 Zhaoxin Li, Chenrui Liu, Jingyi An, Xi Wang, Shaowei Hu
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Structural and Functional Analysis of Heparosan Synthase 2 from Pasteurella multocida to Improve the Synthesis of Heparin ACS Catal. (IF 12.9) Pub Date : 2024-04-15 Eduardo Stancanelli, Juno A. Krahn, Elizabeth Viverette, Robert Dutcher, Vijayakanth Pagadala, Mario J. Borgnia, Jian Liu, Lars C. Pedersen
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Nitrogen, Sulfur Co-doped Hollow Carbon-Encapsulated Cu/Co2P for Selective Oxidation Esterification of Furfurals ACS Catal. (IF 12.9) Pub Date : 2024-04-15 Yangyang Dong, Gaofeng Chen, Xiongxiong Zuo, Jiaran Li, Jia Yu, Ge Zhang, Junhua Kuang, Isil Akpinar, Li Peng, Xing Tang, Jin-Chao Dong, Lu Lin, Pengbo Lyu, Shuliang Yang, Jian-Feng Li
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Synthesis of highly heterogeneous Pt-Ag nanocrystals for catalytic and photocatalytic applications J. Catal. (IF 7.3) Pub Date : 2024-04-16 Ming-Shiuan Huang, Su-Wen Hsu
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Site-Selective Bimetallic Heterogeneous Nanostructures for Plasmon-Enhanced Photocatalysis of Nitrobenzene Hydrogenation ACS Catal. (IF 12.9) Pub Date : 2024-04-15 Ya-Qin Wang, Jun-Rong Zheng, Qi Liu, Yu-Qiang Shi, Hui-Jie Liu, Zheng Huang, Jun Yi, Ye Yang, Qin Kuang
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Palladium-Catalyzed Annulations via Sequential C–H Activations of C(sp2)–H/C(sp3)–H or C(sp3)–H/C(sp3)–H Bonds ACS Catal. (IF 12.9) Pub Date : 2024-04-15 Wan-Xu Wei, Mateusz Czajkowski, Yangjin Kuang, Tu-Anh V. Nguyen, Bo Qin, Martin Tomanik
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Hydrogen Peroxide as an Ideal Electron Donor for Long-Lasting Fenton Chemistry: Strong Enhancement of Fe(III) Activity by Heteroatom-Doped Nanocarbons ACS Catal. (IF 12.9) Pub Date : 2024-04-14 Yiming Sun, Peng Zhou, Minglu Sun, Yuchen Zhang, Xiao Wang, Chenying Zhou, Yang Liu, Chuanshu He, Bo Lai
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Direct characterization of interface sites in Au/TiO2 catalysts prepared using atomic layer deposition Chem Catal. Pub Date : 2024-04-15 Wang Ke, Xiangdong Qin, Yovanny Vazquez, Ilkeun Lee, Francisco Zaera
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Synthesis of C5-boryl indoles via a borane-catalyzed borylation/hydride transfer cascade Chem Catal. Pub Date : 2024-04-15 Baoquan Zhan, Jianxing Lv, Jiangyue Wu, Hua Zhang
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Stable Operation of Paired CO2 Reduction/Glycerol Oxidation at High Current Density ACS Catal. (IF 12.9) Pub Date : 2024-04-13 Attila Kormányos, Adrienn Szirmai, Balázs Endrődi, Csaba Janáky
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Generation of Sulfamoyl Radical for the Modular Synthesis of Sulfonamides ACS Catal. (IF 12.9) Pub Date : 2024-04-13 Haiping Lv, Xinzhou Chen, Xuemei Zhang, Søren Kramer, Zhong Lian
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Solar Gas-Phase CO2 Hydrogenation by Multifunctional UiO-66 Photocatalysts ACS Catal. (IF 12.9) Pub Date : 2024-04-12 Celia M. Rueda-Navarro, Zahraa Abou Khalil, Arianna Melillo, Belén Ferrer, Raúl Montero, Asier Longarte, Marco Daturi, Ignacio Vayá, Mohamad El-Roz, Virginia Martínez-Martínez, Herme G. Baldoví, Sergio Navalón
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Theoretical Insights into the Reaction Mechanism of Direct Hydrogenation of Maleic Anhydride to Produce 1,4-Butanediol on the Cu–ZnO Surface ACS Catal. (IF 12.9) Pub Date : 2024-04-12 Xinyue Guan, Yingzhe Yu, Minhua Zhang
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Practical Machine Learning-Assisted Design Protocol for Protein Engineering: Transaminase Engineering for the Conversion of Bulky Substrates ACS Catal. (IF 12.9) Pub Date : 2024-04-12 Marian J. Menke, Yu-Fei Ao, Uwe T. Bornscheuer
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Nickel-Catalyzed Deoxygenative Disulfuration of Alcohols to Access Unsymmetrical Disulfides ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Xiyao Chen, Wen Shao, Guo-Jun Deng
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Catalytic mechanisms of methylcyclohexane cracking and light olefins production over zeolites J. Catal. (IF 7.3) Pub Date : 2024-04-13 Yuyue Gao, Linxian Liao, Quan Zhu, Haisheng Ren
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Cobalt Catalyzed Annulation of Benzimidates or NH‐Benzaldimines with Ynamides : Synthesis of 1‐Alkoxy‐ and 1‐Alkyl‐3‐Aminoisoquinolines Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-13 Isabelle Gillaizeau, Cyril NICOLAS, Elsa Anselmi, pascal retailleau, Liliane Mimoun, Hamdi Sanaa
Inexpensive cobalt‐catalyzed, pivalic acid‐assisted oxidative C‐H functionalization of benzimidates or NH‐benzaldimines with ynamides is presented, providing an access to 3‐aminoisoquinoline derivatives. The procedure is compatible with various substrates featuring alkyl, alkoxy, acyl or halogen as substituents, heteroaryl structures, and diverse ynamides. The reaction has been scaled up, with subsequent
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Organocatalyzed, Three‐Component Construction of Cyanopyrazoles Using Diazoacetonitrile Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-13 Anamika Dhami, Anuj Kumar, Kalathingal Hisana, KISHOR MOHANAN
An organocatalyzed three‐component protocol using diazoacetonitrile to access a wide range of cyanopyrazole derivatives has been reported herein. This strategy, which proceeds through a piperidine‐catalyzed Knoevenagel condensation/formal [3+2] cycloaddition/dehydrocyanation sequence, provides an efficient route to construct dicyanopyrazoles from aldehydes, malononitrile, and diazoacetonitrile regioselectively
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Copper‐Catalyzed α‐Indolmethylation of 2‐Pyridylacetates with 3‐Indoleacetic Acids via Alkylideneindolenine Intermediates Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-13 Xiaodong Tang, Chen Chen, Yongjun Chen, Jianxin Pang, Weiya Kong
This study reports the copper‐catalyzed α‐indolmethylation of 2‐pyridylacetates with 3‐indoleacetic acids. This reaction offers a approach to generating alkylideneindolenine electrophiles via the oxidative decarboxylation of 3‐indoleacetic acids. The developed reaction system demonstrates good versatility, extending beyond the indolmethylation of 2‐ pyridylacetates to include activated esters and nitroalkanes
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Stabilization of layered lithium-rich manganese oxide for anion exchange membrane fuel cells and water electrolysers Nat. Catal. (IF 37.8) Pub Date : 2024-04-12 Xuepeng Zhong, Lijun Sui, Menghao Yang, Toshinari Koketsu, Malte Klingenhof, Sören Selve, Kyle G. Reeves, Chuangxin Ge, Lin Zhuang, Wang Hay Kan, Maxim Avdeev, Miao Shu, Nicolas Alonso-Vante, Jin-Ming Chen, Shu-Chih Haw, Chih-Wen Pao, Yu-Chung Chang, Yunhui Huang, Zhiwei Hu, Peter Strasser, Jiwei Ma
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Diastereo- and Enantioselective Dearomative Reductive Aryl-Fluoroalkenylation of Indoles by Nickel Catalysis ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Xinmiao Huang, Min Ou, Lixin Hong, Wenjie Qin, Yuanhong Ma
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Nickel-Based Catalysts for the Selective Monoarylation of Dichloropyridines: Ligand Effects and Mechanistic Insights ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Geraldo Duran-Camacho, Douglas C. Bland, Fangzheng Li, Sharon R. Neufeldt, Melanie S. Sanford
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Double Catalytic Activity Unveiled: Synthesis, Characterization, and Catalytic Applications of Iridium Complexes in Transfer Hydrogenation and Photomediated Transformations ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Laura Blanco, Andrea Uroz, Kevin Gutiérrez, Silvia Cabrera, Alba Collado, José Alemán
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Supported Catalytically Active Liquid Metal Solutions: Liquid Metal Catalysis with Ternary Alloys, Enhancing Activity in Propane Dehydrogenation ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Michael Moritz, Sven Maisel, Narayanan Raman, Haiko Wittkämper, Christoph Wichmann, Mathias Grabau, Deniz Kahraman, Julien Steffen, Nicola Taccardi, Andreas Görling, Marco Haumann, Peter Wasserscheid, Hans-Peter Steinrück, Christian Papp
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Rhodium(II)-Catalyzed Asymmetric Cyclopropanation and Desymmetrization of [2.2]Paracyclophanes ACS Catal. (IF 12.9) Pub Date : 2024-04-11 Duc Ly, John Bacsa, Huw M. L. Davies
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Synthesis of Alkynylsilanes: A Review of the State of the Art Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-12 Krzysztof Kuciński
This contribution offers a comprehensive overview of methods for forging sp C–Si bonds. Over time, alkynylsilanes (silylacetylenes), once considered mere byproducts of hydrosilylation processes, have become essential building blocks in organic synthesis. This literature review traces the evolution of their synthesis, from traditional methodologies relying on organolithium and organomagnesium compounds
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Enantioselective Si‐H Insertion of Arylvinyldiazoesters Promoted by Rhodium(I)/Diene Complexes Adv. Synth. Catal. (IF 5.4) Pub Date : 2024-04-12 Ziyan Li, Jian-Guo Liu, Wen-Ping Zhang, Ming-Hua Xu
An enantioselective Si‐H insertion between α‐arylvinyldiazoesters and silanes has been developed by employing rhodium(I)/chiral diene complex as the catalyst. This protocol offers a catalytic asymmetric approach to various chiral silanes containing α‐arylvinyl functionality at room temperature with good enantiocontrol (89‐99% ee). Transformation of the resulting enantiomerically enriched α‐arylvinyl‐α‐silyl