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Organolead Halide-Based Coordination Polymers: Intrinsic Stability and Photophysical Applications Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-31 Chen Sun, Ruonan Xi, Honghan Fei
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Early Microjet Experimentation with Liquid Water in Vacuum Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-31 Manfred Faubel
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Unique Properties and Emerging Applications of Carbolong Metallaaromatics Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-30 Ming Luo, Dafa Chen, Qian Li, Haiping Xia
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Benzo-Fused-Ring Toolbox Based on Palladium/Norbornene Cooperative Catalysis: Methodology Development and Applications in Natural Product Synthesis Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-30 Hong-Gang Cheng, Shihu Jia, Qianghui Zhou
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Chelating Bis-silylenes As Powerful Ligands To Enable Unusual Low-Valent Main-Group Element Functions. Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-31 Shenglai Yao,Artemis Saddington,Yun Xiong,Matthias Driess
ConspectusSilylenes are divalent silicon species with an unoccupied 3p orbital and one lone pair of electrons at the SiII center. Owing to the excellent σ-donating ability of amidinato-based silylenes, which stems from the intramolecular imino-N donor interaction with the vacant 3p orbital of the silicon atom, N-heterocyclic amidinato bis(silylenes) [bis(NHSi)s] can serve as versatile strong donating
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Molecular Machine Learning for Chemical Catalysis: Prospects and Challenges Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-30 Sukriti Singh, Raghavan B. Sunoj
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Porous Single Crystals at the Macroscale: From Growth to Application Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-27 Wenting Li, Kui Xie
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Sulfoxide-Directed or 3d-Metal Catalyzed C–H Activation and Hypervalent Iodines as Tools for Atroposelective Synthesis Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-27 Sabine Choppin, Joanna Wencel-Delord
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Discipline-Based Diversity Research in Chemistry Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-27 Rigoberto Hernandez
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Multiple Stepwise Synthetic Pathways toward Complex Plasmonic 2D and 3D Nanoframes for Generation of Electromagnetic Hot Zones in a Single Entity Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-24 Insub Jung, Jeongwon Kim, Sungwoo Lee, Woocheol Park, Sungho Park
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Element Distributions in Bimetallic Aerogels Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-26 Cui Wang, Juan Herranz, René Hübner, Thomas J. Schmidt, Alexander Eychmüller
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Helical Synthetic Nanographenes with Atomic Precision Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-26 Yanpeng Zhu, Jiaobing Wang
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Chalcones: Potential Chemotherapeutic Compounds and Educational Tools for Closing the Loop in STEM Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-25 Albert E. Russell, Brandon R. Gines
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Layered Oxide Cathodes for Sodium-Ion Batteries: Storage Mechanism, Electrochemistry, and Techno-economics Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-25 Wenhua Zuo, Alessandro Innocenti, Maider Zarrabeitia, Dominic Bresser, Yong Yang, Stefano Passerini
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Core-Level Photoelectron Angular Distributions at the Liquid–Vapor Interface Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-25 Rémi Dupuy, Stephan Thürmer, Clemens Richter, Tillmann Buttersack, Florian Trinter, Bernd Winter, Hendrik Bluhm
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Signatures of Room-Temperature Quantum Interference in Molecular Junctions Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-24 Shi-Xia Liu, Ali K. Ismael, Alaa Al-Jobory, Colin J. Lambert
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Real-Time Visualizing Nucleation and Growth of Electrodes for Post-Lithium-Ion Batteries Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-23 Ji Hyun Um, Seong-Jun Kim, Jae-Hwan Hyun, Mihyun Kim, Si-Hwan Lee, Seung-Ho Yu
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Highly Efficient Asymmetric Hydrogenation Catalyzed by Iridium Complexes with Tridentate Chiral Spiro Aminophosphine Ligands Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-23 Fan Yang, Jian-Hua Xie, Qi-Lin Zhou
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Nickel-Catalyzed Ligand-Controlled Selective Reductive Cyclization/Cross-Couplings Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-23 Qi Pan, Yuanyuan Ping, Wangqing Kong
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Demystifying the Chemical Ordering of Multimetallic Nanoparticles Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-21 Dennis Johan Loevlie, Brenno Ferreira, Giannis Mpourmpakis
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Template-Assembled Synthetic G-Quartets (TASQs): multiTASQing Molecular Tools for Investigating DNA and RNA G-Quadruplex Biology Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-20 David Monchaud
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Photochemical Methods Applied to DNA Encoded Library (DEL) Synthesis Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-19 Bianca Matsuo, Albert Granados, Guillaume Levitre, Gary A. Molander
DNA-encoded library technology (DELT) is a new screening modality that allows efficient, cost-effective, and rapid identification of small molecules with potential biological activity. This emerging technique represents an enormous advancement that, in combination with other technologies such as high-throughput screening (HTS), fragment-based lead generation, and structure-based drug design, has the
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Fluorescent Probes for Biological Species and Microenvironments: from Rational Design to Bioimaging Applications Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-18 Hongbao Fang, Yuncong Chen, Zhiyong Jiang, Weijiang He, Zijian Guo
Some important biological species and microenvironments maintain a complex and delicate dynamic balance in life systems, participating in the regulation of various physiological processes and playing indispensable roles in maintaining the healthy development of living bodies. Disruption of their homeostasis in living organisms can cause various diseases and even death. Therefore, real time monitoring
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Advancements in Liquid Jet Technology and X-ray Spectroscopy for Understanding Energy Conversion Materials during Operation Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-13 Torben Reuss, Sreeju Sreekantan Nair Lalithambika, Christian David, Florian Döring, Christian Jooss, Marcel Risch, Simone Techert
Water splitting is intensively studied for sustainable and effective energy storage in green/alternative energy harvesting–storage–release cycles. In this work, we present our recent developments for combining liquid jet microtechnology with different types of soft X-ray spectroscopy at high-flux X-ray sources, in particular developed for studying the oxygen evolution reaction (OER). We are particularly
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Addressing Short-Chain PFAS Contamination in Water with Nanofibrous Adsorbent/Filter Material from Electrospinning Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-12 Shobha Mantripragada, Sherine O. Obare, Lifeng Zhang
Per- and polyfluoroalkyl substances (PFAS) stand for thousands of fully/highly fluorinated aliphatic chemicals, which have been widely manufactured and used in consumer products. Due to easy deprotonation of headgroups and high strength of C–F bonds in their molecules, PFAS are water-soluble and extremely stable in our environment. Significant accumulation of PFAS in water bodies started as early as
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Coordination Assistance: A Powerful Strategy for Metal-Catalyzed Regio- and Enantioselective Hydroalkynylation of Internal Alkenes Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-11 Wei Zhao, Hou-Xiang Lu, Wen-Wen Zhang, Bi-Jie Li
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Membranized Coacervate Microdroplets: from Versatile Protocell Models to Cytomimetic Materials Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-10 Ning Gao, Stephen Mann
Although complex coacervate microdroplets derived from associative phase separation of counter-charged electrolytes have emerged as a broad platform for the bottom-up construction of membraneless, molecularly crowded protocells, the absence of an enclosing membrane limits the construction of more sophisticated artificial cells and their use as functional cytomimetic materials. To address this problem
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Overcoming Pharmaceutical Bottlenecks for Nucleic Acid Drug Development Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-09 Mei Lu, Haonan Xing, Aiping Zheng, Yuanyu Huang, Xing-Jie Liang
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Poly(Glycerol)-Based Biomedical Nanodevices Constructed by Functional Programming on Inorganic Nanoparticles for Cancer Nanomedicine Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-05 Naoki Komatsu
Nanomedicine is promising to improve conventional cancer medicine by making diagnosis and therapy more accurate and more effective in a more personalized manner. A key of the cancer nanomedicine is construction of medical nanodevices by programming various requisite functions to nanoparticles (NPs). As compared to that of soft NPs, including organic micelles and polymers, fabrication of an inorganic
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Absolute Electronic Energetics and Quantitative Work Functions of Liquids from Photoelectron Spectroscopy Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-04 Bernd Winter, Stephan Thürmer, Iain Wilkinson
Liquid-jet photoelectron spectroscopy (LJ-PES) enabled a breakthrough in the experimental study of the electronic structure of liquid water, aqueous solutions, and volatile liquids more generally. The novelty of this technique, dating back over 25 years, lies in stabilizing a continuous, micron-diameter LJ in a vacuum environment to enable PES studies. A key quantity in PES is the most probable energy
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Aryne Atropisomers: Chiral Arynes for the Enantiospecific Synthesis of Atropisomers and Nanographene Atropisomers Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-03 Yoann Coquerel
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Synthesis of High-Order and High-Oxidation State Securinega Alkaloids Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-03 Gyumin Kang, Sangbin Park, Sunkyu Han
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Nanothermometry with Enhanced Sensitivity and Enlarged Working Range Using Diamond Sensors Acc. Chem. Res. (IF 24.466) Pub Date : 2023-01-03 Gang-Qin Liu, Ren-Bao Liu, Quan Li
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Rational Design of Diamond Electrodes Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-30 Nianjun Yang, Xin Jiang
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SARS-CoV-2 Main Protease Drug Design, Assay Development, and Drug Resistance Studies Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-29 Bin Tan, Ryan Joyce, Haozhou Tan, Yanmei Hu, Jun Wang
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Lewis Base–Boryl Radicals Enabled Borylation Reactions and Selective Activation of Carbon–Heteroatom Bonds Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-26 Tian-Yu Peng, Feng-Lian Zhang, Yi-Feng Wang
The past decades have witnessed tremendous progress on radical reactions. However, in comparison with carbon, nitrogen, oxygen, and other main group element centered radicals, the synthetic chemistry of boron centered radicals was less studied, mainly due to the high electron-deficiency and instability of such 3-center–5-electron species. In the 1980s, Roberts and co-workers found that the coordination
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Multifunctional Photo-Cross-Linking Probes: From Target Protein Searching to Imaging Applications Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-19 Kostiantyn Kozoriz, Olha Shkel, Kyung Tae Hong, Dong Hoon Kim, Yun Kyung Kim, Jun-Seok Lee
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Advancing X-ray Luminescence for Imaging, Biosensing, and Theragnostics Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-19 Zhongzhu Hong, Zhaowei Chen, Qiushui Chen, Huanghao Yang
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Fluorescent Probes for Lipid Membranes: From the Cell Surface to Organelles Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-19 Andrey S. Klymchenko
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Collective Diffraction Effects in Perovskite Nanocrystal Superlattices Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-19 Stefano Toso, Dmitry Baranov, Umberto Filippi, Cinzia Giannini, Liberato Manna
For almost a decade now, lead halide perovskite nanocrystals have been the subject of a steadily growing number of publications, most of them regarding CsPbBr3 nanocubes. Many of these works report X-ray diffraction patterns where the first Bragg peak has an unusual shape, as if it was composed of two or more overlapping peaks. However, these peaks are too narrow to stem from a nanoparticle, and the
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Knowledge Engineering in Chemistry: From Expert Systems to Agents of Creation Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-14 Aleksandar Kondinski, Jiaru Bai, Sebastian Mosbach, Jethro Akroyd, Markus Kraft
Passing knowledge from human to human is a natural process that has continued since the beginning of humankind. Over the past few decades, we have witnessed that knowledge is no longer passed only between humans but also from humans to machines. The latter form of knowledge transfer represents a cornerstone in artificial intelligence (AI) and lays the foundation for knowledge engineering (KE). In order
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Chemical Preintercalation Synthesis of Versatile Electrode Materials for Electrochemical Energy Storage Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-13 Ekaterina Pomerantseva
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Bifunctional Lipid-Derived Affinity-Based Probes (AfBPs) for Analysis of Lipid–Protein Interactome Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-09 Jingyan Ge, Shubo Du, Shao Q. Yao
Although lipids are not genetically encoded, they are fundamental building blocks of cell membranes and essential components of cell metabolites. Lipids regulate various biological processes, including energy storage, membrane trafficking, signal transduction, and protein secretion; therefore, their metabolic imbalances cause many diseases. Approximately 47 000 lipid species with diverse structures
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Advances in Polyynes to Model Carbyne Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-09 Yueze Gao, Rik R. Tykwinski
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Nonadiabatic Dynamics Studied by Liquid-Jet Time-Resolved Photoelectron Spectroscopy Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-08 Zachary N. Heim, Daniel M. Neumark
The development of the liquid microjet technique by Faubel and co-workers has enabled the investigation of high vapor pressure liquids and solutions utilizing high-vacuum methods. One such method is photoelectron spectroscopy (PES), which allows one to probe the electronic properties of a sample through ionization in a state-specific manner. Liquid microjets consisting of pure solvents and solute–solvent
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Role of Cinchona Alkaloids in the Enantio- and Diastereoselective Synthesis of Axially Chiral Compounds Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-07 Chiara Portolani, Giovanni Centonze, Paolo Righi, Giorgio Bencivenni
Asymmetric synthesis using organic catalysts has evolved since it was first realized and defined. Nowadays, it can be considered a valid alternative to transition metal catalysis for synthesizing chiral molecules. According to the literature, the number of asymmetric organocatalytic processes associated with atropisomer synthesis has rapidly increased over the past 10 years because organocatalysis
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Relaxometry with Nitrogen Vacancy (NV) Centers in Diamond Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-07 Aldona Mzyk, Alina Sigaeva, Romana Schirhagl
Relaxometry is a technique which makes use of a specific crystal lattice defect in diamond, the so-called NV center. This defect consists of a nitrogen atom, which replaces a carbon atom in the diamond lattice, and an adjacent vacancy. NV centers allow converting magnetic noise into optical signals, which dramatically increases the sensitivity of the readout, allowing for nanoscale resolution. Analogously
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Two-Dimensional Nanomaterial-Templated Composites Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-07 Zhenyu Shi, Yiyao Ge, Qinbai Yun, Hua Zhang
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Boron-Doped Diamond Electrodes: Fundamentals for Electrochemical Applications Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-07 Yasuaki Einaga
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Surface Plasmon-Induced Hot Carriers: Generation, Detection, and Applications Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-06 Hyunhwa Lee, Yujin Park, Kyoungjae Song, Jeong Young Park
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Facile Assembly of Modular-Type Phosphines for Tackling Modern Arylation Processes Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-06 Man Ho Tse, Pui Ying Choy, Fuk Yee Kwong
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Solvation, Surface Propensity, and Chemical Reactions of Solutes at Atmospheric Liquid–Vapor Interfaces Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-06 Markus Ammann, Luca Artiglia
Liquids are of overarching importance for the atmosphere, as 72% of the Earth’s surface is covered by oceans, a large number of liquid aerosol particles fill the air, and clouds hold a tiny but critical fraction of Earth’s water in the air to influence our climate and hydrology, enabling the lives of humans and ecosystems. The surfaces of these liquids provide the interface for the transfer of gases
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Predicting the Second-Order Nonlinear Optical Responses of Organic Materials: The Role of Dynamics Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-05 Frédéric Castet, Claire Tonnelé, Luca Muccioli, Benoît Champagne
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Smart Hydrogen Atoms in Heterocyclic Cations of 1,2,4-Triazolium-Type Poly(ionic liquid)s Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-05 Si-hua Liu, Hong Wang, Jian-ke Sun, Markus Antonietti, Jiayin Yuan
Discovering and constructing molecular functionality platforms for materials chemistry innovation has been a persistent target in the fields of chemistry, materials, and engineering. Around this task, basic scientific questions can be asked, novel functional materials can be synthesized, and efficient system functionality can be established. Poly(ionic liquid)s (PILs) have attracted growing interest
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Exploring Multifunctional Hydrogen-Bonded Organic Framework Materials Acc. Chem. Res. (IF 24.466) Pub Date : 2022-12-01 Zhangjing Zhang, Yingxiang Ye, Shengchang Xiang, Banglin Chen
Hydrogen-bonded organic framework (HOF) materials have provided a new dimension and bright promise as a new platform for developing multifunctional materials. They can be readily self-assembled from their corresponding organic molecules with diverse functional sites such as carboxylic acid and amine groups for their hydrogen bonding and aromatic ones for their weak π···π interactions to stabilize the
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Phenanthroline Catalysis in Stereoselective 1,2-cis Glycosylations Acc. Chem. Res. (IF 24.466) Pub Date : 2022-11-30 Jiayi Li, Hien M. Nguyen
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Surface Control of Nanodiamond: From Homogeneous Termination to Complex Functional Architectures for Biomedical Applications Acc. Chem. Res. (IF 24.466) Pub Date : 2022-11-29 Elisabeth Mayerhoefer, Anke Krueger
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UV Photoelectron Spectroscopy of Aqueous Solutions Acc. Chem. Res. (IF 24.466) Pub Date : 2022-11-28 William G. Fortune, Michael S. Scholz, Helen H. Fielding
Knowledge of the electronic structure of an aqueous solution is a prerequisite to understanding its chemical and biological reactivity and its response to light. One of the most direct ways of determining electronic structure is to use photoelectron spectroscopy to measure electron binding energies. Initially, photoelectron spectroscopy was restricted to the gas or solid phases due to the requirement
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Single Metal Atoms on Oxide Surfaces: Assessing the Chemical Bond through 17O Electron Paramagnetic Resonance Acc. Chem. Res. (IF 24.466) Pub Date : 2022-11-28 Enrico Salvadori, Paolo Cleto Bruzzese, Elio Giamello, Mario Chiesa
Even in the gas phase single atoms possess catalytic properties, which can be crucially enhanced and modulated by the chemical interaction with a solid support. This effect, known as electronic metal–support interaction, encompasses charge transfer, orbital overlap, coordination structure, etc., in other words, all the crucial features of the chemical bond. These very features are the object of this
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Synthesis Processes, Photoluminescence Mechanism, and the Toxicity of Amorphous or Polymeric Carbon Dots Acc. Chem. Res. (IF 24.466) Pub Date : 2022-11-23 Xiaoxiao Yao, Riley E. Lewis, Christy L. Haynes