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Ruthenium-Catalyzed Self-Coupling of Secondary Alcohols J. Org. Chem. (IF 3.6) Pub Date : 2023-12-01 Nitin Kumar, Raman Vijaya Sankar, Chidambaram Gunanathan
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Cobalt(II)-Catalyzed Selective Three-Component Oxyalkylation of N-Aryl Glycinates: A Route to CF3-Labeled Threonine Analogues J. Org. Chem. (IF 3.6) Pub Date : 2023-11-30 Yadong Li, Dengfu Lu, Yuefa Gong
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P(III)-Chirogenic Phosphinite Building Blocks by Stereospecific N→O Phosphinyl Migration J. Org. Chem. (IF 3.6) Pub Date : 2023-12-02 Antonin Jaillet, Jérôme Bayardon, Yoann Rousselin, Sylvain Jugé
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TMSCF3-Mediated Conversion of Salicylates into α,α-Difluoro-3-coumaranones: Chain Kinetics, Anion-Speciation, and Mechanism J. Org. Chem. (IF 3.6) Pub Date : 2023-12-02 Hannah B. Minshull, Guy C. Lloyd-Jones
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Calcium-Catalyzed Synthesis of Fused Furo[2,3-b]furans and Substituted Furans from 2-Oxo Aldehydes and Cyclic Enols J. Org. Chem. (IF 3.6) Pub Date : 2023-12-01 Srinivasarao Yaragorla, Sanyasi Rao Ithu, Doma Arun, Valmuri Srivardhan
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Green Synthesis of Electrophilic Alkenes Using a Magnesium Catalyst under Aqueous Conditions and Mechanistic Insights by Density Functional Theory J. Org. Chem. (IF 3.6) Pub Date : 2023-12-01 Pankaj Lal Kalar, Kavita Jain, Swatantra Agrawal, Siddique Khan, Rampal Vishwakarma, Ayush Shivhare, Milind M. Deshmukh, Kalpataru Das
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Chemodivergent Synthesis of Benzothiadiazin-3-one 1-Oxides and Benzisothiazol-3-ones via Visible Light-Promoted Intramolecular N–S Bond Formation J. Org. Chem. (IF 3.6) Pub Date : 2023-12-01 Huimin Li, Zhiqiang Xiong, Shouri Sheng, Junmin Chen
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Potassium tert-Butoxide-Mediated Cascade Synthesis of Rutaecarpine Alkaloid Analogues: Access to Molecular Complexity on Multigram Scales J. Org. Chem. (IF 3.6) Pub Date : 2023-12-01 Soumya Jyoti Basak, Jyotirmayee Dash
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Oxidation/Alkylation of Amino Acids with α-Bromo Carbonyls Catalyzed by Copper and Quick Access to HDAC Inhibitor J. Org. Chem. (IF 3.6) Pub Date : 2023-12-01 Yuqiong Tan, Huan Xiang, Jiayan Jin, Xingrui He, Shijun Li, Yang Ye
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Divergent Synthesis of 3-(Indol-2-yl)quinoxalin-2-ones and 4-(Benzimidazol-2-yl)-3-methyl(aryl)cinnolines via Polyphosphoric Acid (PPA)-Mediated Intramolecular Rearrangements of 3-(Methyl/aryl(2-phenylhydrazono)methyl)quinoxalin-2-ones J. Org. Chem. (IF 3.6) Pub Date : 2023-11-30 Vakhid A. Mamedov, Liliya V. Mustakimova, Zheng-Wang Qu, Hui Zhu, Victor V. Syakaev, Venera R. Galimullina, Leisan R. Shamsutdinova, Il’dar Kh. Rizvanov, Aidar T. Gubaidullin, Oleg G. Sinyashin, Stefan Grimme
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Iodine-Catalyzed Regioselective Synthesis of Diphenyl-Substituted Carbazoles via [4 + 2] Annulation of β-Formyl Ketones with Indoles J. Org. Chem. (IF 3.6) Pub Date : 2023-11-30 Sundaram Suresh, Hung-Sheng Chien, Chao-Hua Chen, Hao-Yu Tsai, Dai-Ru Chung, Veerababurao Kavala, Ching-Fa Yao
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Theoretical Analysis of a Three-Component Reaction between Two Diazo Compounds and a Hydroxylamine Derivative: Mechanism, Enantioselectivity, and Effect of Cooperative Catalysis J. Org. Chem. (IF 3.6) Pub Date : 2023-11-30 Simeng Qi, Ji Ma, Guowei Yan, Alexander M. Kirillov, Lizi Yang, Ran Fang
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Arene Ruthenium(II)-Catalyzed Sustainable Synthesis of 2,4-Disubstituted Quinazolines via Acceptorless Dual Dehydrogenative Coupling of Alcohols J. Org. Chem. (IF 3.6) Pub Date : 2023-11-29 Saranya Sundar, Tamilthendral Veerappan, Anandaraj Pennamuthiriyan, Ramesh Rengan
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Cobalt-Catalyzed Chemodivergent Synthesis of Cyclic Amines and Lactams from Ketoacids and Anilines Using Hydrosilylation J. Org. Chem. (IF 3.6) Pub Date : 2023-11-29 Surajit Panda, Amareshwar Nanda, Ratnakar Saha, Rahul Ghosh, Bidraha Bagh
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Photocatalytic Thiol–Yne Reactions of Alkynyl Sulfides J. Org. Chem. (IF 3.6) Pub Date : 2023-11-29 Oliver Bleton, Noémie Beaucage, Javier Guerrero-Morales, Shawn K. Collins
Thiol–yne reactions typically employ thiols and terminal alkynes as the reaction partners. The thiol–yne reaction of alkynyl sulfides and thiols is possible when employing a nonmetal photocatalyst eosin Y, green LED irradiation, under an air atmosphere. Alkynyl sulfides were transformed in good overall yields (58–90% total yields, 11 examples) favoring the cis isomer. No addition to the α-position
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Thiolation of Terminal Alkynes with Thiuram Disulfide Reagents Using Water as the Hydrogen Source: Stereoselective Synthesis of (Z)-Vinyl Sulfides J. Org. Chem. (IF 3.6) Pub Date : 2023-11-29 Dan Wang, Jing Du, Wan-Li Lin, Yue-Sheng Li, Zhi-Bing Dong
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Electrochemical N-Acylation of Sulfoximine with Hydroxamic Acid J. Org. Chem. (IF 3.6) Pub Date : 2023-11-29 Wenxiu Huang, Shoucai Wang, Mingzhe Li, Longqiang Zhao, Mengyu Peng, Chen Kang, Guangbin Jiang, Fanghua Ji
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Photocatalytic Radical Cascade Dehalogenation/Carbo-cyclization/Sulfonylation Leading to Indole- and Benzofuran-Based Benzylic Sulfones J. Org. Chem. (IF 3.6) Pub Date : 2023-11-29 Qing-Quan Liu, Jia-Zhuo Li, Yan-Jing Wang, Yan-Ning Leng, Yu-Wen Huang, Xin-Chao Meng, Bo-Rong Leng, De-Cai Wang, Yi-Long Zhu
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Rapid and General Access to α-Haloketones Using Quaternary Ammonium Salts as Halogen Sources J. Org. Chem. (IF 3.6) Pub Date : 2023-11-29 Nan Wu, Mengfei Jiang, Ashley Cao, Lei Huang, Xiumei Bo, Zhou Xu
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1,6-Dioxo-2-azaspiro[3.4]oct-2-enes and Related Spirocycles: Heterocycles from [3 + 2] Nitrile Oxide Cycloadditions with 2-Methyleneoxetanes, -Thietanes, and -Azetidines J. Org. Chem. (IF 3.6) Pub Date : 2023-11-28 Jose Intano, Jr., Louis P. Riel, Jacky Lim, Jerome R. Robinson, Amy R. Howell
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Equipping 1,4,7-Triazacyclononane with Substituents via Solid-Phase Synthesis J. Org. Chem. (IF 3.6) Pub Date : 2023-11-28 Daniel Ossadnik, Jona Voss, Adelheid Godt
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Oxygen Dependent Switchable Selectivity during Ruthenium Catalyzed Selective Synthesis of C3-Alkylated Indoles and Bis(indolyl)methanes J. Org. Chem. (IF 3.6) Pub Date : 2023-11-28 Amit Kumar Guin, Subhasree Pal, Subhajit Chakraborty, Santana Chakraborty, Nanda D. Paul
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Organocatalytic Asymmetric Vinylogous Michael Addition of Electron-Deficient Aryl Alkane Nucleophiles to Enals J. Org. Chem. (IF 3.6) Pub Date : 2023-11-28 Zhiguang Zhang, Ao Sui, Xiaomin Zhang, Xu Wang, Xinyi He, Bingzhu Zhang, Haixia Wu
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Selectfluor-Mediated Electrophilic Annulation of 2-Alkynyl Biaryls with Diorganyl Diselenides J. Org. Chem. (IF 3.6) Pub Date : 2023-11-28 Qing-Xia Luo, Hong-Tao Ji, Yu-Han Lu, Ke-Li Wang, Li-Juan Ou, Wei-Min He
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Relay Copper-Catalyzed Synthesis of Imidazo[1,5-a]pyridine Scaffolds from Phenylalanine and Halohydrocarbon J. Org. Chem. (IF 3.6) Pub Date : 2023-11-28 Jian Tang, Fengjie Lu, Yi Sun, Zhiyu Yang, Ensheng Zhang, Jingwei Lv
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Synthesis of 3-Aminoquinazolinones via a SnCl2-Mediated ANRORC-like Reductive Rearrangement of 1,3,4-Oxadiazoles J. Org. Chem. (IF 3.6) Pub Date : 2023-11-28 Mohamed Elagawany, Lingaiah Maram, Bahaa Elgendy
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Concise Stereoselective Total Synthesis of (−)-Hedycoropyran A J. Org. Chem. (IF 3.6) Pub Date : 2023-11-28 Byeongyeon Ahn, Ryangha Lee, Hyoungsu Kim, Dongjoo Lee
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Regioselective and Diastereoselective Construction of Diverse Dispiro-Indanone-Fluorenone-Oxindole Motifs J. Org. Chem. (IF 3.6) Pub Date : 2023-11-28 Dan Liu, Jing Sun, Ying Han, Chao-Guo Yan
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Phosphonium Ion-Tethered Secondary Amines for Chemospecific 5-Enolexo Aldol Condensations of 6-Ketoaldehydes J. Org. Chem. (IF 3.6) Pub Date : 2023-11-28 Akash Sugunan, V. M. Aparna, Goreti Rajendar
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Regioselective Synthesis of Benzannulated [5,6]-Oxaspirolactones via Cu(II)-Catalyzed Cycloisomerization of 2-(5-Hydroxyalkynyl)benzoates J. Org. Chem. (IF 3.6) Pub Date : 2023-11-27 Sagar S. Thorat, Sagar P. Shimpi, Pooja I. Sambherao, Gamidi Rama Krishna, Ravindar Kontham
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Rapid Lewis Acid Screening and Reaction Optimization Using 3D-Printed Catalyst-Impregnated Stirrer Devices in the Synthesis of Heterocycles J. Org. Chem. (IF 3.6) Pub Date : 2023-11-27 Rumintha Thavarajah, Matthew R. Penny, Ryo Torii, Stephen T. Hilton
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Copper-Catalyzed Synthesis of N-Fused Quinolines via C(sp3)–H Activation-Radical Addition–Cyclization Cascade J. Org. Chem. (IF 3.6) Pub Date : 2023-11-27 Yangang Wu, Wen Zhang, Shiyu Ma, Chuanjun Song, Junbiao Chang
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A Comprehensive Study of the Radical Scavenging Activity of Rosmarinic Acid J. Org. Chem. (IF 3.6) Pub Date : 2023-11-27 Quan V. Vo, Nguyen Thi Hoa, Matthew Flavel, Nguyen Minh Thong, Houssem Boulebd, Pham Cam Nam, Duong Tuan Quang, Adam Mechler
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Chiral Pool Meets Chiral Catalysis: Eight-Step Convergent Total Synthesis of Anticancer Natural Lipid Mycalol J. Org. Chem. (IF 3.6) Pub Date : 2023-11-26 Rodney A. Fernandes, Priyanka Choudhary, Gulenur N. Khatun
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Stereoselective Synthesis of Tri- and Tetrasubstituted Allylsilanes via Copper-Catalyzed Decarboxylative Silylation of Vinylethylene Carbonates J. Org. Chem. (IF 3.6) Pub Date : 2023-11-27 Wenzhu Ren, Yifei Yan, Yinhua Huang
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CS2/KOH System-Promoted Stereoselective Synthesis of (E)-Alkenes from Diarylalkynes and a “Hidden” Zinin-Type Reduction of Nitroarenes into Arylamines J. Org. Chem. (IF 3.6) Pub Date : 2023-11-27 Douglas B. Paixão, Eduardo G. O. Soares, Caren D. G. Silva, Thiago J. Peglow, Daniel S. Rampon, Paulo H. Schneider
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TFE-Facilitated Synthesis of Tetrahydropyridino[2,3-d]pyrimidine via Cascade [1,5]-Hydride Transfer/Cyclization J. Org. Chem. (IF 3.6) Pub Date : 2023-11-27 Cong Wei, Yan Li, Xin Yao, Kui Zhang, Lingchao Cai
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Glutathione Peroxidase-like Antioxidant Activity of 1,3-Benzoselenazoles: Synthesis and In Silico Molecular Docking Studies as Pancreatic Lipase Inhibitors J. Org. Chem. (IF 3.6) Pub Date : 2023-11-26 Manisha Yadav, Vijay P. Singh
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Highly Enantioselective Chiral Diol-Catalyzed Conjugate Addition of Boronic Acids to α,β-Unsaturated Trifluoromethyl Ketones J. Org. Chem. (IF 3.6) Pub Date : 2023-11-25 Ya-Jing Hou, Lu Zhao, Guo-Li Chai, Kangbao Zhong, Junbiao Chang
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Toward N-peri-Annulated Planar Blatter Radical through aza-Pschorr and Photocyclization J. Org. Chem. (IF 3.6) Pub Date : 2023-11-24 Patrycja Szamweber, Anna Pietrzak, Georgia A. Zissimou, Piotr Kaszyński
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Sequential Nitrile Amidination–Reduction as a Straightforward Procedure to Selective Linear Polyamine Preparation J. Org. Chem. (IF 3.6) Pub Date : 2023-11-25 Antonio Peñas-Sanjuán, Jose J. Chica-Armenteros, Rubén Cruz-Sánchez, Celeste García-Gallarín, Manuel Melguizo
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Synthesis of Asymmetric Urea Derivatives from COS and Amines: Substrate Selection, Scope Studies, and Mechanism Investigation J. Org. Chem. (IF 3.6) Pub Date : 2023-11-23 Siliu Cheng, Jiakai Wu, Huijie Jia, Ruijun Xie, Ning Zhu
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Syntheses of Substituted α,β-Unsaturated δ-Lactams from N-Boc-2,4-dioxopiperidine J. Org. Chem. (IF 3.6) Pub Date : 2023-11-22 Saiya Liu, Chenchen Zhang, Qihua Xiong, Yuexin Liu, Lu Li, Yongqiang Sun, Bichu Cheng, Fener Chen
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Pd-Catalyzed Regioselective Deuteration of Indole’s C4-Position with Transient Directing Groups J. Org. Chem. (IF 3.6) Pub Date : 2023-11-22 Chenxu Zheng, Zhi-Jiang Jiang, Ke Jin, Qian Wang, Jian-Fei Bai, Gang Xu, Zhanghua Gao
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Investigating Substituent Interactions with Cationic Catalysts J. Org. Chem. (IF 3.6) Pub Date : 2023-11-22 Ziyuan Gong, Alberto Smith, Abdikani Omar Farah, Shelby D. Dickerson, Gisela A. González-Montiel, Jacqueline M. Laddusaw, Paul Ha-Yeon Cheong, Sheryl L. Wiskur
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Cp2Fe-Mediated Electrochemical Synthesis of Phosphorylated Oxindoles and Indolo[2,1-a]isoquinolin-6(5H)-ones J. Org. Chem. (IF 3.6) Pub Date : 2023-11-22 Xiaocong Zhou, Jian Wang, Yirui Shen, Dumei Ma, Yufen Zhao, Ju Wu
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Two-Chamber-Enabled Hydrogenation Reactions Using Al-H2O/NaOH: Access to Pharmaceuticals J. Org. Chem. (IF 3.6) Pub Date : 2023-11-21 Ashif Iqubal, Pallabi Halder, Parthasarathi Das
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Unusual Kinetics Induced by Ligands in Rhodium(III)-Catalyzed Dehydrogenative Olefination Reactions J. Org. Chem. (IF 3.6) Pub Date : 2023-11-21 Dandan Lu, Kongchuan Wu, Ting-Bin Wen, Wei Hao, Hui-Jun Zhang
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Enantioenriched 1,4-Benzoxazepines via Chiral Brønsted Acid-Catalyzed Enantioselective Desymmetrization of 3-Substituted Oxetanes J. Org. Chem. (IF 3.6) Pub Date : 2023-11-21 Martin Nigríni, Viraj A. Bhosale, Ivana Císařová, Jan Veselý
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Fluorescent Rotary Switches: Four- vs Three-Substituted Phthalimide Boron Difluoride Schiff Base Complexes J. Org. Chem. (IF 3.6) Pub Date : 2023-11-21 Dancho Yordanov, Rastislav Smolka, Kosuke Nakashima, Shin-ichi Hirashima, Yasuyuki Matsushima, Martin Vala, Jozef Krajčovič, Martin Weiter, Tsuyoshi Miura, Anton Georgiev
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Organophotocatalyzed Mono- and Bis-Alkyl/Difluoroalkylative Thio/Selenocyanation of Alkenes J. Org. Chem. (IF 3.6) Pub Date : 2023-11-21 Koustav Pal, Palasetty Chandu, Debabrata Das, Aliya V. Jinilkumar, Manasi Mallick, Devarajulu Sureshkumar
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Origin of Ligand and Acid Effects on the Pd-Catalyzed Regiodivergent Coupling Reaction of Indazoles and Isoprene: A DFT Study J. Org. Chem. (IF 3.6) Pub Date : 2023-11-21 Manzhu Zhao, Haiyan Yuan, Jingping Zhang
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Visible Light Promoted [3+2]-Cycloaddition for the Synthesis of Cyclopenta[b]chromenocarbonitrile Derivatives J. Org. Chem. (IF 3.6) Pub Date : 2023-11-21 Ewelina Kowalska, Mateusz Dyguda, Angelika Artelska, Anna Albrecht
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Copper-Catalyzed Aerobic S-Amination of Sulfenamides for the Synthesis of Sulfinamidines J. Org. Chem. (IF 3.6) Pub Date : 2023-11-20 Guoling Huang, Jianlin Ye, Minxi Tan, Yuetong Chen, Xunbo Lu
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Brønsted Acid-Mediated Multicomponent One-Pot Approach to Direct Construction of 4-Aryl-hydrocoumarin Derivatives J. Org. Chem. (IF 3.6) Pub Date : 2023-11-20 Pragya Sharma, Sanjay Singh, Chinmoy Kumar Hazra
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Kumada–Tamao–Corriu Type Reaction of Aromatic Bromo- and Iodoamines with Grignard Reagents J. Org. Chem. (IF 3.6) Pub Date : 2023-11-20 Alicja A. Zielińska, Piotr Trzaska, Marcin Budny, Mariusz J. Bosiak
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POCl3/Sulfoxide-Promoted Synthesis of Indolizino[8,7-b]indoles J. Org. Chem. (IF 3.6) Pub Date : 2023-11-20 Xiao-Hui Chen, Yun-Meng Li, Xiang Huang, Hai-Lei Cui
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Photochemically Induced Hydrogen Atom Transfer and Intramolecular Radical Cyclization Reactions with Oxazolones J. Org. Chem. (IF 3.6) Pub Date : 2023-11-20 Mohammed Latrache, Corentin Lefebvre, Manabu Abe, Norbert Hoffmann
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Ru(II)-Catalyzed Enantioselective Transfer Hydrogenation of α-Ketophosphonates: Straightforward Access to Valuable Chiral α-Hydroxy Phosphonates J. Org. Chem. (IF 3.6) Pub Date : 2023-11-20 Pierre Plouard, Ulysse Elmerich, Mina Hariri, Severine Loiseau, Ludovic Clarion, Jean Luc Pirat, Pierre-Georges Echeverria, Tahar Ayad, David Virieux
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Organocatalytic Diastereoselective (4 + 1) Cycloaddition of o-Hydroxyphenyl-Substituted Secondary Phosphine Oxides J. Org. Chem. (IF 3.6) Pub Date : 2023-11-20 Shu-Fang Wu, Guo-Ke Zhang, Xue Wang, Zhuo-Jing He, Yu-Chen Zhang, Feng Shi