Article Frontmatter was published on June 1, 2021 in the journal Corrosion Reviews (volume 39, issue 3).

Article In this issue was published on June 1, 2021 in the journal Corrosion Reviews (volume 39, issue 3).

Mechanisms for materials degradation are usually inferred from electrochemical measurements and characterization performed before, during, and after exposure testing and/or failure analysis of service materials. Predicting corrosion and other materials degradation modes, such as hydrogen-assisted cracking, from first-principles has generally been limited to thermodynamic predictions from Pourbaix or

Silica is a chemically inert molecule with an ability of adsorption on the metal to form a layer of barrier for preventing it from the atmospheric damage. However, a larger amount of silica is required for producing the impactful anticorrosive activity, leading to toxic and carcinogenic effects in the environment, and thus limiting the applications of silica. Application of nanotechnology in the synthesis

Carbon capture and storage (CCS) technology is considered to be one of the key technologies to reduce CO 2 emissions. This paper reviews the industry corrosion accidents of CCS transportation system, in which the pipeline corrosion risk is analyzed, and the pipeline corrosion theory is summarized. Also, the effect of impurities on gas phase properties is discussed. We analyze the corrosion mechanism

In coal fired power plants, the metallic surfaces such as boiler tubes, walls of combustion chambers and other parts degrade by corrosion, erosion and abrasion. It happens due to the hot gaseous environment, steam oxidation and presence of hard minerals and impurities in the coal. It is very important to protect these surfaces from material loss, otherwise it would lead to increased repair and maintenance

Gas boriding was used to produce the borided layer containing a mixture of chromium and nickel borides on the Inconel ® 600-alloy. The borided sample was characterized by a higher corrosion potential (−0.953 V) than the non-borided sample (−1.005 V). The corrosion current density was significantly lower for the borided sample. The oxidation at 1000 °C for 24 h caused the formation of different oxides

To reduce the use of synthetic compounds as wear-corrosion inhibitors, and substitute them with new ecological compounds, we are interested in evaluating the effect of the essential oils against the tribocorrosion. The present paper describes the effect of adding Thymus zygis subsp. gracilis (TZ) essential oil (3 g·L −1 ) on AISI 304L tribocorrosion behavior in 0.5 M H 2 SO 4 . As a result, the addition

Article Frontmatter was published on April 1, 2021 in the journal Corrosion Reviews (volume 39, issue 2).

There are collective data about the scope of various corrosion inhibitors viz., polymers, plant extracts, inorganic compounds, ionic liquids, organic molecules with hetero atoms, and π-electron clouds have been reported so far on the corrosion prevention of various metals in various corrosive media. Many reviews of literature related to organic inhibitors have been accounted for their classification

As two-dimensional (2D) materials, graphene and hexagonal-boron nitride ( h -BN) are famous for protective coatings, because of their excellent chemical resistance, barrier property, impermeability along with thermal stability, and a large number of these properties are particularly suitable for protective coatings. However, the applications of graphene for metal protection have been limited by galvanic

This paper investigated optimization of corrosion inhibitory attributes of mixed cocoa pod- Ficus exasperata (CP-FE) extracts towards mild steel in 1.5 M HCl using central composite design. Potentiodynamic polarization, linear polarization resistance and electrochemical impedance spectroscopy measurements were used for the electrochemical study. The result revealed maximum inhibition efficiency of

Coatings based on a graphene oxide–boron nitride/epoxy (GO–BN/EP) system were fabricated and applied for corrosion protection of metal substrates. GO–BN hybrid sheet synthesized by using a modified Hummers’ method had a higher lipophilicity than GO and BN. Then, GO–BN hybrid was incorporated into an epoxy coating to investigate the compactness and the corrosion protection ability of GO–BN hybrid/epoxy

The inhibition effectiveness of Punica granatum ( also called Pomegranate) extract and the synergistic effect of potassium iodide (KI) against the degradation of mild steel in 1 M HCl was studied. Potentiodynamic polarization measurement (PDP) was used in order to investigate the performance of this compound. The presence of a mixture of iodide ions (KI) and inhibitor (PG) increased the degree of surface

To investigate the effect of interaction between two single-Si 3 N 4 particle-impingements on the repassivation of 304 stainless steel in a simulated groundwater, the corrosion current peaks of the samples during the impingement were recorded, and the micro-hardness of the substrate around the crater was tested. The results indicated that significant interactions between the two impingements were observed

This paper results from mutual discussions on the review ‘When do small fatigue cracks propagate and when are they arrested?’ in Corrosion Reviews, 2019; 37(5): 397–418. These discussions have arisen from the two engineering paradigms characterizing our fatigue research: (i) an aerospace research and technology remit for metallic airframes, and (ii) a materials science research programme supporting

Article Frontmatter was published on February 1, 2021 in the journal Corrosion Reviews (volume 39, issue 1).

Rapid development of railway industry makes safety increasingly important. Wear, contact-impact, fatigue and corrosion are important factors initiating rail track degradation from the beginning, while corrosion attracts far less attention than other issues. Direct corrosion cost due to railway corrosion in China was 18.88 billion RMB, so corrosion definitely deserves more attention. This work has reviewed

Zinc is an important coating material for corrosion protection of carbon steel because of its sacrificial behavior. Continuous efforts have therefore been made over the years to perform required microstructural engineering to further enhance the corrosion resistance behavior of Zn based coatings. This review is focused on a new class of recently developed coatings in which carbonaceous materials like

Corrosion is a spontaneous process that adversely affects strength and quality of economically vital materials including steel. Plant extracts are emerging as renewable, low cost and eco-friendly alternate to existing toxic chemical corrosion inhibitors. Physisorption, Chemisorption and retrodonation are the main mechanism of corrosion inhibition by plant extracts. Different functional groups of phytochemicals

The corrosion behavior of 15CrMo used for water-wall tubes was studied in various urea-containing solution to determine the corrosion problem of water-wall tubes caused by urea in a coal-fired power plant. Urea decomposition tests, together with corrosion experiments, were carried out. The temperature was 320 °C, and the concentrations of urea were 70, 140, 280, 560 and 840 mg/L. Weight loss experiments

AA7075 high-strength aluminum alloy, which has many applications in the aircraft, marine and automobile industries, happens to be susceptible to stress corrosion cracking (SCC) when exposed to corrosive environments, resulting in reduced service life of the components. Inappropriate fabrication processes may augment this behavior. The fabrication of AA7075 components using conventional fusion welding

Metal matrix composites are expanding their range every day due to their various industrial applications in manufacturing sectors, to attain high performance and favorable characteristics such as light weight, more excellent corrosion as well as wear resistance, high specific strength and high temperature-resistance than conventional materials. This study deals with analysis on erosion wear characteristic

Article Reviewer acknowledgement Corrosion Reviews volume 38 (2020) was published on February 1, 2021 in the journal Corrosion Reviews (volume 39, issue 1).

Journal Name: Corrosion Reviews Volume: 38 Issue: 6 Pages: i-iii

Abstract The relatively limited data for the corrosion and pitting of high nickel alloys are reviewed herein and time-dependent trends developed for exposures in marine and atmospheric environments. Data sets for average or ‘uniform’ corrosion losses that are sufficiently extensive show topological consistency with the bimodal functional model previously observed for steels and various copper-nickel

Abstract This study reports a facile method to prepare silica-coated graphene oxide nanoflakes (SiO2–GO). Results of X-ray diffraction analysis, Raman spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy and atomic force microscopy reveal that silica was successfully coated on the GO flakes. The effect of SiO2–GO nanosheets on the corrosion

Abstract The effect of small amounts of chalcogen alloying elements (S, Se and Te) on the oxidation resistance (OR) of Cu has been investigated at 300–800 °C in 0.1 MPa oxygen atmospheres. Compared to pure copper, the addition of S, Se and Te could effectively improve the OR below 600 °C mainly owing to the chalcogen-element inclusions which hinder the diffusion of Cu. However, it becomes weak above

Abstract The state of art in alternating current (AC)-induced corrosion in pipelines is reviewed. Growing pipeline networks and their co-location with high-voltage (HV) transmission networks have brought into focus the issue of induced AC corrosion on the pipeline networks. Induced AC corrosion may quickly and severely affect the integrity of pipeline networks, especially considering that a number

Abstract In this paper, the principle and application of atomic force microscopy (AFM) are reviewed and discussed in detail. Several scientific papers are used to find out data about AFM. The obtained scientific results are summarized to get a better understanding of the method and its application. The application of AFM for corrosion study is discussed in detail, and the possible conclusion is made

Abstract The proposed work aims to improve the comprehensive properties of the composite coating by adding different content of graphene into the coating solution. Firstly, the formulation of the coating solution was determined by the L16(45) orthogonal test. Secondly, the conventional properties of the coating were tested using the optical microscope and micro-vickers hardness tester. Thirdly, the

Abstract Biofilms cause huge economic loss to the industry through corrosion. A deeper understanding of how biofilms form, develop and interact will help to decipher their roles in promoting and inhibiting corrosion, thus in controlling it. The present review explores most mechanisms of biofilm development and maintenance with particular emphasis on the roles of the biomolecules characteristic of biofilms

Abstract Biomaterials play a significant role in revolutionizing human life in terms of implants and medical devices. These materials essentially need to be highly biocompatible and inert to the human physiological conditions. This paper provides an in-depth, critical and analytical review on the previous research work and studies conducted in the field of metals and alloys used as implant materials

Abstract The work introduces a numerical external damage prediction method for buried pipelines. The external pitting initiation and corrosion rate of oil or gas pipelines are affected by pipeline age, physicochemical properties of soils and cathodic protection performance as well as coating conditions. Before developing the damage prediction model, the influencing factors were weighed by grey relational

Abstract One of the promising applications of magnesium and magnesium alloys is their use as biodegradable implants in biomedical applications. The pH around an orthopedic implant greatly affects the degradation kinetics of biodegradable Mg–Ca alloys. At the location of a fracture, local pH changes, and this has to be considered in the optimization of implant materials. In this study, the effect of

Abstract Twinning-induced plasticity (TWIP) steels are increasingly receiving wide attention for automotive applications due to their outstanding combination of ductility and strength, which can largely be attributed to the strain hardening effect, formation of mechanical twins during straining, and the presence of manganese (Mn) as an alloying element. However, the premature cracking and sudden failure

Journal Name: Corrosion Reviews Volume: 38 Issue: 5 Pages: i-iii

Abstract In this work, results on the causes that could promote the abnormal spallation of the oxides formed on the surface of high-strength low-alloy (HSLA) steels are presented. By means of Rietveld refining of X-ray diffraction spectra, scanning electron microscopy analyses and calculations, it was found that the value of the thermal stress experienced by the oxide scale reached a maximum when the

Abstract The damage caused by marine fouling organisms to ships and underwater artificial equipment is becoming increasingly serious issue, and the prevention and control of marine biofouling has always been a research hotspot in marine coatings. Aiming at the problems of poor adhesion, long curing time and high curing temperature of low-surface energy marine antifouling coatings of organosilicon,

Abstract In order to evaluate the seawater corrosivity of typical sea areas in China and provide guidance for the seawater corrosion protection on marine equipment and facilities, field exposure test was carried out. These typical sea areas under various climatic zones in China included Qingdao, Zhoushan, Sanya and a South China Sea reef, and Q235, copper, 5083 aluminum alloy and 304 stainless steel

Abstract In a primer coating system used in aerospace applications to protect aluminum alloy substrate, praseodymium is added as corrosion inhibitors while CaSO4 is primarily added as filler materials. The interaction of Pr and CaSO4 is unknown. The goal of this study is to characterize any cooperative or synergistic inhibition between these two. Cooperative inhibition can be defined when one inhibitor

Journal Name: Corrosion Reviews Volume: 38 Issue: 4 Pages: i-iii

Abstract Stainless steel has proved to be an important material to be used in a wide range of applications. For this reason, ensuring the durability of this alloy is essential. In this work, pitting corrosion behaviour of EN 1.4404 stainless steel is evaluated in marine environment in order to develop a model capable of predicting its pitting corrosion status by an automatic way. Although electrochemical

Abstract The atmospheric corrosion of metallic materials causes great economic loss every year worldwide. Thus, it is meaningful to predict the corrosion loss in different field environments. Generally, the corrosion prediction method includes three parts of work: the modelling of the corrosive environment, the calibration of the corrosion effects, and the establishment of the corrosion kinetics. This

Journal Name: Corrosion Reviews Volume: 38 Issue: 3 Pages: i-iii

Abstract Nuclear steam generators (NSGs) are key components of nuclear power plants (NPPs) since their reliability affects the overall plant performance. Corrosion control of steam generators under operation and during plant outages is attained by proper design, adequate material selection and control of water chemistry in the entire secondary cooling circuit. This article reviews the types of steam

Abstract Buried pipelines are essential for the delivery of potable water around the world. A key cause of leaks and bursts in these pipelines, particularly those fabricated from carbon steel, is the accelerated localized corrosion due to the influence of microbes in soil. Here, studies conducted on soil corrosion of pipelines' external surface both in the field and the laboratory are reviewed with

Abstract A nickel-rich conductive anti-corrosive coating (CACC) was fabricated to improve the corrosion resistance of the carbon steel grounding materials. The coating was tested using surface contact resistance measurement, electrochemical impedance spectroscopy (EIS) and surface characterization. The results indicate that the increase of the nickel powder content in the coating induces its electrical

Abstract The wastewater of petroleum refineries consists of various corrosive pollutants that are harmful not only for human and living organisms but also for the equipment and materials exposed to it. The galvanic corrosion of carbon steel in MgCl2 solution as a pollutant in petroleum refinery wastewater was studied under concentration cell formation. The influence of different operating parameters

Abstract Microstructural changes that result in relevant improvements in mechanical properties and electrochemical behavior can be induced using different sintering conditions of ASTM F75 cobalt alloys during their processing using powder metallurgy technique. It has been observed that the increase in carbon and nitrogen content improves corrosion resistance and mechanical properties as long as the

Abstract In order to advance material development for future nuclear systems, an insight into the cracking conditions of T91 ferritic-martensitic steel in heavy liquid metals (HLM) is provided. The paper critically reviews previous experimental data and summarizes them with new results. The new testing of T91 steel was performed in contact with slow flow and static HLM to study crack initiation, especially

Abstract High-temperature oxidation of E110 (Zr-1%Nb) zirconium alloy in steam at Т = 1100°C to various degrees has been carried out. Based on the studies of morphology and microstructure of the oxide film and metal, as well as on review of previously published results, the mechanism of alloy oxidation has been proposed, which includes oxide thickening close to the oxide/metal interface, growth of

Abstract Gel capsules of calcium alginate as a matrix stuffed with a non-ionic surfactant, namely 2-(2-(3,4-bis(2-methoxyethoxy)tetrahydrofuran-2-yl)-2-(2-methoxyethoxy)ethoxy)ethyl stearate, Tween-60, as an inhibitor was prepared by a piercing-solidifying method for corrosion protection of carbon steel tubes from produced water in acidizing oil wells. The Fourier transform infrared and thermal gravimetric

Abstract The inhibition effect of Thymus zygis subsp. gracilis (TZ) on mild steel corrosion in 1 m hydrochloric acid has been investigated by weight loss measurements, surface analysis [scanning electron microscopy (SEM)-energy-dispersive X-ray (EDX), three-dimensional (3D) profilometry, and Fourier transform infrared analysis], potentiodynamic polarization, and electrochemical impedance spectroscopy

Abstract This paper describes the study of electrodeposition process by cyclic voltammetry for Zn-Ni bimetallic coating on the X52 carbon steel substrate. Prior to the deposition at the bath temperatures of 25°C, 40°C, and 60°C, investigations were carried out to find the optimum potential range for zinc-nickel coatings with respect to the Ag/AgCl reference electrode. Scanning electron microscopy (SEM)

Abstract Corrosion products formed on the surface of two silver brazing alloys after the potentiostatic polarization in 3.5% sodium chloride solution were characterized by the standard methods such as, the X-ray diffraction, micro-Raman spectroscopy, and scanning electron microscopy with energy-dispersive spectroscopy. This paper presents the results of a laser desorption/ionization mass spectrometry

Abstract The corrosion mechanism of copper and copper alloy is reviewed. A number of scientific papers have been investigated to determine the corrosion mechanism and protection techniques of copper and copper alloy corrosion. Results have shown that copper can be corroded in an acidic or an alkaline environment, and oxide formation is the corrosion initiation process. The use of corrosion inhibitors

Journal Name: Corrosion Reviews Volume: 38 Issue: 2 Pages: i-iii

Abstract Various methodologies are practically used to control corrosion. Coatings are the most widely used to protect metals against corrosion. However, due to the weak resistance of polymer coating against the penetration of corrosive solution to the metal/coating interface, the long-term corrosion resistance of the polymer coating is reduced gradually. Recently, nanoparticles have been added to

Abstract This paper presents an overview of the corrosion behavior of titanium (Ti) alloys in both acidic and saline solutions. The solutions covered in this review are essentially the typical electrolytes encountered by Ti alloys when applied under service conditions. Although Ti alloys are generally known to be corrosion resistant, this review identifies strong reducing acids and fluoride-containing