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Silicone Resin Applications for Heat-Resistant Coatings: A Review Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-12-21 Hanqi Qian, Bo Jiang
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Evolution of Organometallasiloxanes Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-11-15 A. A. Anisimov, E. O. Minyaylo, A. R. Shakirova, O. I. Shchegolikhina
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Practical Application of Selected Functional Organosilicone Polymers Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-10-10 V. I. Nedel’kin, A. V. Nedel’kin, B. A. Izmailov, A. B. Zachernyuk, E. N. Solov’eva, B. A. Zachernyuk
Abstract The available information concerning the preparation and properties of modifying siloxane coatings on the surface of fibrous materials, as well as a number of other functional silicone polymers for hydrophobization of fibers, textiles, leather, building materials, creation of adhesive compositions, and other practically valuable silicone products has been generalized.
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Non-Isocyanate Poly(Siloxane-Urethanes) Based on Oligodimethylsiloxanes Containing Aminopropyl and Ethoxy Substituents Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-10-10 E. S. Trankina, A. Yu. Kazantseva, D. A. Khanin, S. E. Lyubimov, E. G. Kononova, U. S. Andropova, A. M. Muzafarov
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Modern Approaches to Obtaining Organofunctional Silsesquioxanes Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-10-10 N. S. Bredov, V. V. Kireev, V. A. Polyakov, I. B. Sokol’skaya, A. S. Esin
Abstract Modern research in the field of synthesis of organofunctional oligosilsesquioxanes is considered. Relationships between the composition and structure of oligomeric organosilsesquioxanes and the conditions for their formation during the hydrolytic and acidohydrolytic polycondensation of organotrialkoxysilanes containing various functionalities, such as methacrylic, aminopropyl, carboxyl, and
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New Fluorescent Materials Based on Polysiloxanes and Boron Bis(β-diketonates) Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-09-30 E. E. Kim, T. M. Il’ina, Yu. N. Kononevich, D. S. Ionov, D. A. Khanin, G. G. Nikiforova, A. M. Muzafarov
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Mechanochemical Interaction of Phenylboronic Acid with Polyphenylsilsesquioxane and a Hydroxy(phenyl)siloxane Oligomer Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-09-30 V. V. Libanov, A. A. Kapustina, N. P. Shapkin
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Functionalized Oligoaryloxycyclotriphosphazenes and Noncombustible Binders Based on Them Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-09-30 Yu. V. Bilichenko, Pham Van Thuan, R. S. Borisov, A. A. Kolenchenko, V. V. Kireev
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Study of the Effect of Nonselective Organic Solvent Nature on the Self-Organization of Amphiphilic Block Copolymers of D,L-Lactide and Ethylene Oxide in Aqueous Solution Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-09-26 E. V. Kuznetsova, E. M. Shirokova, Yu. A. Puchkova, E. V. Yastremsky, S. N. Chvalun
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Stimuli-Responsive Systems Based on Polymer-like Wormlike Micelles of Ionic Surfactants and Their Modern Applications Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-09-26 V. S. Molchanov, O. E. Philippova
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Dielectric Mismatch Effects on Polyelectrolyte Solutions in Electrified Nanopores: Insights from Mean-Field Theory Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-08-31 Yu. A. Budkov, N. N. Kalikin
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Polytope 240-Based Rod Structures Made of Tetrahedral Atoms: Comparison with Structures Obtained Using a Modular Design Method Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-08-31 E. A. Zheligovskaya
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Adsorption of Random Copolymer on a Chemically Heterogeneous Periodic Stripe-Patterned Surface Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-08-31 A. S. Ivanova, A. A. Polotsky
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History and Perspectives of Atomistic Simulation of Polysaccharides Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-08-18 V. I. Deshchenya, N. D. Kondratyuk
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Effect of Characteristics of Polymer Microgel Catalysts on the Efficiency of Interfacial Catalysis Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-08-18 M. V. Anakhov, R. A. Gumerov, I. I. Potemkin
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Geometric Features of Structuring of Amphiphilic Macromolecules on the Surface of a Spherical Nanoparticle Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-08-18 D. A. Mitkovskiy, A. A. Lazutin, A. S. Ushakova, A. L. Talis, V. V. Vasilevskaya
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The Rheological Behavior of Polymer Solution Threads Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-08-09 A. V. Subbotin, I. A. Nyrkova, A. N. Semenov
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One-Step Synthesis of Monosilicon-Substituted Norbornenes with Siloxane and Aryl Fragments and Their Polymerization Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-08-09 M. A. Guseva, P. P. Lezhnin, D. A. Alentiev, K. V. Zaitsev, M. V. Bermeshev
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Polymetalorganosiloxanes as a Reflection of the Milestones in the Development of Advanced Technologies in the Chemistry of Silicones Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-08-09 O. A. Serenko
Abstract This review analyzes the areas of practical application of oligomeric and polymeric organometal siloxanes as reduced fire risk coatings, antifriction and heat-resistant coatings, materials with high refractive index, and protective coatings for space equipment as well as functional branched oligomers as the most universal organometal siloxane synthons for diverse use.
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Novel Approach to the Synthesis of Bithiophenesilane Dendrimers with Efficient Intramolecular Energy Transfer Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-08-09 M. S. Skorotetskii, O. V. Borshchev, E. A. Kleimyuk, E. A. Svidchenko, N. M. Surin, S. A. Ponomarenko
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Diblock Copolymer Melt in an Electric Field: Stability of the Homogeneous State in the Random Phase Approximation Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-08-09 Yu. A. Kriksin, Y. V. Kudryavtsev
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Elasticity of Highly Entangled Polymer Networks and Gels: Review of Models and Theory of Nonaffine Deformations Polym. Sci. Ser. C (IF 2.2) Pub Date : 2023-08-09 S. V. Panyukov
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Bending Rigidity of Branched Polymer Brushes with Finite Membrane Thickness Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-09-21 I. V. Mikhailov, A. A. Darinskii, T. M. Birshtein
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Ionic Ring-Opening Polymerization for the Synthesis of Star-Shaped Polymers Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-09-21 A. N. Blokhin, M. M. Dudkina, A. V. Tenkovtsev
Abstract Features of ionic ring-opening polymerization for preparing star-shaped polymers are considered. The possibilities of controlled synthesis of star-shaped structures using cyclic monomers of various classes are demonstrated. Data on the preparation of star polymers using the approaches of “grafting from” a multifunctional initiator, “grafting through” a macromonomer, and “grafting to” a multifunctional
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Amino- and Sulfo-Containing Molecular Brushes Based on Oligo(ethylene glycol) (Meth)Acrylates: Synthesis and Properties in Solutions Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-09-13 A. S. Simagin, M. V. Savinova, D. M. Kamorin, O. A. Kazantsev, D. V. Orekhov, M. A. Simonova, S. V. Orekhov
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Comb-Like Polyelectrolytes with Quinolinium and Trimethylammonium Cations in Micellar Catalysis Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-09-13 P. A. Fetin, V. I. Fetina, M. V. Kadnikov, A. A. Lezov, I. M. Zorin
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Recent Advances in the Field of Polycarboranesiloxanes Synthesis Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-09-13 V. A. Vasnev, G. D. Markova
Abstract The reports on the synthesis and study of polycarboranesiloxanes published after 2000 have been reviewed. The data on the C- and B-substitution at the carborane core are presented. Major parameters of the synthesized polymers, including thermal, mechanical, and others) have been estimated.
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Effect of the Structure of Arms and Way of Their Attachment to Calix[4]arene on Self-Assembly Processes in Aqueous Solutions of Thermoresponsive Star-Shaped Poly(2-alkyl-2-oxazolines) and Poly(2-alkyl-2-oxazines) Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-08-31 T. Yu. Kirila, A. B. Razina, A. V. Ten’kovtsev, A. P. Filippov
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Molecular Switch Based on a Linear Macromolecule Inserted in a Second-Generation Dendron Brush Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-08-31 A. A. Polotsky, T. M. Birshtein
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Amphiphilic Copolymers of Different Structure Based on Poly(ethylene glycol): Synthesis, Physico-Chemical Properties, and Cytotoxicity Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-08-31 M. Yu. Zaremski, N. S. Melik-Nubarov, I. D. Grozdova, E. E. Aliev, S. A. Rumyantsev
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Self-assembly of Polyfluorene Molecular Brushes with Poly(methacrylic acid) Side Chains in Ethanol and Water Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-08-31 M. A. Simonova, D. M. Ilgach, K. I. Kaskevich, M. I. Nepomnyashaya, L. S. Litvinova, A. P. Filippov, A. V. Yakimansky
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Ferrocenyl-Containing Oligosiloxanes and Polysiloxanes: Synthesis, Properties, and Application Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-08-31 K. V. Deriabin, R. M. Islamova
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Polyvinylidene Fluoride Copolymers with Grafted Polyethyl Methacrylate Chains: Synthesis and Thermal and Dielectric Properties Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-08-31 E. A. Kleimyuk, A.I. Kosyakova, A. I. Buzin, V. G. Shevchenko, Yu. N. Luponosov, S. A. Ponomarenko
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Polymerization of Micelle-Forming Monomers Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-07-08 I. M. Zorin, N. A. Zorina, P. A. Fetin
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Synthesis and Properties of Polymer Photonic Crystals Based on Core–Shell Particles Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-07-08 N. N. Shevchenko, B. M. Shabsel’s, D. I. Iurasova, Yu. O. Skurkis
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Effect of Annealing at High Temperatures on the Morphology of Aqueous Solutions of Star-Shaped Poly(2-Isopropyl-2-Oxazoline) and Linear Poly(2-Ethyl-5,6-Dihydrooxazine) Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-07-08 A. V. Smirnova, A. V. Tenkovtsev, A. P. Filippov
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New Approaches to Atom Transfer Radical Polymerization and Their Realization in the Synthesis of Functional Polymers and Hybrid Macromolecular Structures Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-06-29 I. D. Grishin
Abstract Recent advances in controlled atom transfer radical polymerization are reviewed. Polymerization techniques carried out in the presence of small catalyst amounts, as well as air oxygen traces, are addressed. Particular attention is given to processes occurring under the action of light and near UV radiation. Latest achievements of Atom Transfer Radical Polymerization in the modification of
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Attempts to Optimizing the Synthesis of Hypercrosslinked Polystyrene. 1. Crosslinking with Monochlorodimethyl Ether Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-06-29 M. P. Tsyurupa, Z. K. Blinnikova, Yu. A. Davidovich, M. M. Ilyin, V. A. Davankov
Abstract This contribution was focused on the developing of an improved method for preparing hypercrosslinked polystyrene by bridging styrene-0.5% DVB copolymer with monochlorodimethyl ether (MCDE) up to 100, 150, 200 and 300% via Fidel–Crafts reaction. The modification comprises both the reduction in the consumption of the catalyst, SnCl4, and the complete substitution of SnCl4 with the more active
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Amphiphilic ABA-Type Block–Graft Molecular Brushes Based on Polyimide Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-06-29 I. V. Ivanov, A. V. Kashina, N. V. Kukarkina, A. V. Yakimansky
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Reversible Deactivation Radical Copolymerization: Synthesis of Copolymers with Controlled Unit Sequence Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-04-29 E. V. Chernikova, K. O. Mineeva
Abstract The review addresses the synthesis of copolymers with the controlled distribution of monomer units (random, gradient, block-random, block-gradient, multiblock copolymers) by reversible deactivation radical polymerization and the ways of purposeful variation in the sequence of units in macromolecules during the synthesis. The effect of chain microstructure on the properties of these copolymers
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New Approaches to the Design of Double Polymer Networks: a Review Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-04-13 A. V. Shibaev, O. E. Philippova
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Polymer Composites with Graphene and Its Derivatives as Functional Materials of the Future Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-03-21 M. V. Gudkov, D. Yu. Stolyarova, K. A. Shiyanova, V. P. Mel’nikov
Abstract Approaches to the synthesis of polymer composite materials filled with graphene and its derivatives, methods of introducing graphene and its functionalized forms into polymer matrices, and effect of fillers on the electrophysical, mechanical, and electrorheological properties and the structure of the materials are considered. Research trends that can promote the integration of polymer composites
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Synthesis, Properties, and Biological Activity of Poly(1-vinyl-1,2,4-triazole) and Silver Nanocomposites Based on It Polym. Sci. Ser. C (IF 2.2) Pub Date : 2022-03-02 G. F. Prozorova, A. S. Pozdnyakov
Abstract The review summarizes the data on the synthesis, physicochemical properties, and biological activity of poly(1-vinyl-1,2,4-triazole) and its nanocomposites with silver nanoparticles. The results of studying the antibacterial and antitumor activity of the polymers and nanocomposites and their immunomodulatory ability, toxicity, and interaction with body cells, as well as the prospects for their
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Erratum to: Modern Porous Polymer Implants: Synthesis, Properties, and Application Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-11-17 Kovylin, R. S., Aleynik, D. Ya., Fedushkin, I. L.
An Erratum to this paper has been published: https://doi.org/10.1134/S1811238221330018
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Polymer Rheology in the Petroleum Industry Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-11-17 Malkin, A. Ya.
Abstract The possibilities of using special rheological properties of polymers in the petrochemical industry, in particular, at the stage of oil production in the modification of drilling fluids and oil displacement, the transportation of oil in pipeline systems, and the modification of properties of main hydrocarbon products are considered. In all the cases, polymers with different compositions and
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Reversible Deactivation Radical Polymerization Mediated by Nitroxides and Green Chemistry Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-11-17 Zaremski, M. Yu., Melik-Nubarov, N. S.
Abstract This review is the first attempt to consider application of some principles of green chemistry to reversible-deactivation radical polymerization mediated by nitroxides. The results of controlled synthesis of easily degradable polymers and polymers synthesized under conditions of green chemistry by photopolymerization, polymerization in supercritical carbon dioxide, and polymerization of monomers
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Mechanisms of Reactions of Green Chemistry of Polyurethanes and Problems of Using Renewable Vegetable Raw Materials Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-11-17 Tiger, R. P., Zabalov, M. V., Levina, M. A.
Abstract A brief overview of works in the field of mechanisms of reactions underlying the green chemistry of polyurethanes is presented. The main attention is paid to the processes of the formation of nonisocyanate urethanes from cyclocarbonates and amines and the thermal decomposition of acyl azides as a phosgene-free method for the preparation of isocyanates in statu nascendi. The results of the
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Networks of Micellar Chains with Nanoplates Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-11-17 Molchanov, V. S., Kuklin, A. I., Orekhov, A. S., Arkharova, N. A., Khudoleeva, E. S., Philippova, O. E.
Abstract Nanocomposite networks of surfactant micellar chains and natural bentonite clay nanoplates are studied by rheometry, small-angle neutron scattering, and cryogenic transmission electron microscopy. It is shown that, in an aqueous medium in the presence of a small part of an anionic surfactant, sodium dodecyl sulfate, the molecules of a biodegradable zwitterionic surfactant, oleyl amidopropyl
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Polymer Materials for Membrane Separation of Gas Mixtures Containing CO2 Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-11-17 Alentiev, A. Yu., Ryzhikh, V. E., Belov, N. A.
Abstract In recent decades, the need to capture carbon dioxide from industrial gas streams, its storage, and utilization has been justified as a rule by environmental problems. However, the capture of CO2 from industrial gas mixtures is an independent important issue of chemical technology. The review addresses consideration and analysis of polymer materials for the membrane separation of CO2-containing
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Polycomplex Formulations for the Protection of Soils against Degradation Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-11-17 Panova, I. G., Ilyasov, L. O., Yaroslavov, A. A.
Abstract The review discusses the application of polymers for the control of soil degradation caused by wind and water erosion. The background of the problem, current situation with the soil erosion in the world and Russian Federation, traditional methods for controlling erosion processes, and natural and synthetic soil amendments (soil conditioners) are described. Particular attention is paid to t
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Polylactide-Based Porous Materials: Synthesis, Hydrolytic Degradation Features, and Application Areas Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-11-17 Trofimchuk, E. S., Potseleev, V. V., Khavpachev, M. A., Moskvina, M. A., Nikonorova, N. I.
Abstract Polylactide-based materials are often considered an alternative to materials produced from traditionally hardly degradable polymers. Porous polylactide membranes, matrices, and scaffolds are especially attractive for use in biomedicine. The review concerns the physicochemical basis and structural and morphological opportunities of various methods for the manufacture of porous polylactide,
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Polymer Municipal Solid Waste in the Environment and Methods for Their Processing Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-11-17 Petrosyan, V. S., Shipelov, A. E., Shuvalova, E. A.
Abstract In recent years, the problem of polymer processing has become quite urgent owing to the accumulation of huge amounts of unprocessed polymer municipal solid waste in the environment. The authors discuss the main environmental problems associated with environmental pollution with polymer waste, as well as modern methods of separation, processing (including processing into secondary material
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Polyelectrolytes for the Construction of Artificial Soils Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-11-17 O. S. Yakimenko, D. A. Gruzdenko, A. A. Stepanov, M. A. Butylkina, A. A. Kiushov, I. G. Panova
Abstract The effect of cationic polyelectrolyte poly(diallyldimethylammonium chloride), anionic polyelectrolyte potassium lignohumate, and their interpolyelectrolyte complex on the aggregate composition and phytotoxicity of constructozem, an artificially constructed soil, is investigated. The original constructozem is characterized by a wide range of structural aggregates with a high proportion of
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Combined Use of Atomic Force Microscopy and Molecular Dynamics in the Study of Biopolymer Systems Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-11-17 M. A. Smirnov, D. A. Tolmachev, A. D. Glova, M. P. Sokolova, P. V. Geydt, N. V. Lukasheva, S. V. Lyulin
Abstract Publications showing the prospects of combining computer simulation with atomic force microscopy in the study of polymer biological objects and materials for various purposes are analyzed. The problems that arise when these methods are used together are described. Three main directions are presented in which atomic force microscopy is used in conjunction with computer simulation: study of
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Morphological Transformations in the Process of Coagulation of Cellulose Solution in N-Methylmorpholine N-Oxide with Isobutanol Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-11-17 I. S. Makarov, L. K. Golova, M. I. Vinogradov, M. V. Mironova, N. A. Arkharova, V. V. Klechkovskaya, V. G. Kulichikhin
Abstract Evolution of the morphology of cellulose solutions in N-methylmorpholine-N-oxide during coagulation with a “soft” coagulant, isobutyl alcohol, at different temperatures is considered. Using optical interferometry and transmitted and scanning electron microscopy the mechanism of phase separation of the system to form a polymer phase is studied depending on the temperature of alcohol. It is
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Materials Based on Chitosan and Polylactide: From Biodegradable Plastics to Tissue Engineering Constructions Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-11-17 T. S. Demina, T. A. Akopova, A. N. Zelenetsky
Abstract The transition to green chemistry and biodegradable polymers is a logical stage in the development of modern chemical science and technology. In the framework of this review, the advantages, disadvantages, and potential of biodegradable polymers of synthetic and natural origin are compared using the example of polylactide and chitosan as traditional representatives of these classes of polymers
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Bisphthalonitrile-based Thermosets as Heat-resistant Matrices for Fiber Reinforced Plastics Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-06-30 B. A. Bulgakov, O. S. Morozov, I. A. Timoshkin, A. V. Babkin, A. V. Kepman
Abstract This review focuses on the processes involved in producing heat-resistant matrices for fiber reinforced plastics (FRP) by polymerization of the resins consisting of phthalonitrile monomers and comonomers, and the specifics of fiber reinforced plastics fabrication technologies. Polymerization behaviors observed in the presence of various types of initiators and in different temperature modes
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Modern Porous Polymer Implants: Synthesis, Properties, and Application Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-06-30 R. S. Kovylin, D. Ya. Aleynik, I. L. Fedushkin
Abstract The needs of modern surgery triggered the intensive development of transplantology, medical materials science, and tissue engineering. These directions require the use of innovative materials, among which porous polymers occupy one of the leading positions. The use of natural and synthetic polymers makes it possible to adjust the structure and combination of properties of a material to its
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Polymer Mysteries of Chemical Physics Polym. Sci. Ser. C (IF 2.2) Pub Date : 2021-06-30 Al. Al. Berlin
Abstract The problems that have arisen in the process of research work when solving various applied and scientific problems are considered. Basically, this concerns the synthesis and various properties of polymers. Special attention is paid to phenomena, at first glance, mysterious, requiring a nontrivial approach to explain them. Only understanding the essence of the phenomenon itself makes it possible