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End group cross‐linked membranes based on highly sulfonated poly(arylene ether sulfone) with vinyl functionalized graphene oxide as a cross‐linker and a filler for proton exchange membrane fuel cell application J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2020-11-11 Junghwan Kim, Kihyun Kim, Jusung Han, Hyunhee Lee, Hyejin Kim, Sungjun Kim, Yung‐Eun Sung, Jong‐Chan Lee
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Optimization of anionic conductivity through the coexistence of ionomer cluster and backbone‐backbone morphologies in anion exchange membranes J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2020-11-07 Chinomso Nwosu, Tara P. Pandey, Andrew M. Herring, Soenke Seifert, E. Bryan Coughlin
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Thermoset modified with polyethersulfone: Characterization and control of the morphology J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2020-03-07 Eléonore Mathis, Marie‐Laure Michon, Claude Billaud, Pauline Grau, Anthony Bocahut, Caroll Vergelati, Didier R. Long
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Dual Stimuli‐Responsive Self‐Assembly Behavior of a Tailor‐Made ABC‐Type Amphiphilic Tri‐Block Copolymer J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2020-02-03 Sanjay Pal, Michael Kather, Sovan Lal Banerjee, Pabitra Saha, Andrij Pich, Nikhil K. Singha
This investigation describes the synthesis of a dual stimuli‐responsive, amphiphilic ABC tri‐block copolymer (BCP) based on the functional monomers via RAFT polymerization. In this case, ABC‐type BCP was prepared based on N‐isopropylacrylamide, n‐butyl acrylate, and 4‐vinylpyridine in DMF solvent using cyanomethyl dodecyl trithiocarbonate as the RAFT agent and azobisisobutyronitrile as a thermal initiator
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Synthesis of well-defined block copolymer composed of flexible amphiphilic poly(ethylene glycol) and hydrophobic liquid crystalline segments by living coordination polymerization of allene derivatives and its application to thin film with perpendicularly oriented cylindrical nanostructure J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2020-01-22 Koyuki Sakai, Hiroki Nishiyama, Shinsuke Inagi, Ikuyoshi Tomita, Yusuke Hibi, Motonori Komura, Keiji Nose, Tomokazu Iyoda
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A Novel Conjugated Polymer Consists of Benzimidazole and Benzothiadiazole: Synthesis, Photophysics Properties, and Sensing Properties for Pd2+ J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2020-01-20 Kuan Liu, Zijun Hu
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Preparation of Liquid Crystal Film Capable of Shielding Visible Light Band by Two‐Phase Coexistence J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2020-01-20 Erli Li, Dongdong Zhang, Hui Cao, Yinjie Chen, Limin Zhao, Ping Gan, Zhou Yang, Dong Wang, Wanli He
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Confined crystallization, melting behavior and morphology in PEG‐b‐PLA diblock copolymers: Amorphous versus crystalline PLA J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2020-01-13 Jianna Bao, Xiaolei Dong, Shichang Chen, Wangyang Lu, Xianming Zhang, Wenxing Chen
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Special Issue in honor of Professor Takeshi Endo J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-12-13 Toshikazu Takata, Ikuyoshi Tomita, Yusuf Yagci, Tsutomu Yokozawa
It is our great pleasure to realize this special issue celebrating the 80th birthday of Professor Takeshi Endo, who has just started his new full professor position at Kyushu Institute of Technology following successive positions at Tokyo Institute of Technology, Yamagata University, and Kindai University. Included in this special issue are 32 papers by some of the distinguished international polymer
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Investigation of segmental reorganization within amphiphilic block polymer nanoparticles derived from shell crosslinked micelle templates: Shell crosslinked knedel‐like inversion J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-12-03 Qi Zhang,Karen L. Wooley
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Cover Image, Volume 57, Issue 23 J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-12-01
In their work reported on page 2295, Hiroyuki Matsukizono, Kozo Matsumoto, and Takeshi Endo synthesized hyperbranched polyacetals (HBPAs) bearing cyclic carbonate (CC) terminals. The left image on the cover shows the HBPA molecule, while the right image shows the HBPA molecule bearing the CC terminals. The authors discuss the facile synthetic route to obtain these molecules and discuss their potential
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Acyl guanidine functional poly(2-oxazoline)s as reactive intermediates and stimuli-responsive materials J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-25 Joachim F. R. Van Guyse, Xiaowen Xu, Richard Hoogenboom
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Isothiourea‐based lewis pairs for homopolymerization and copolymerization of 2,2‐dimethyltrimethylene carbonate with ε‐caprolactone and ω‐pentadecalactone J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-20 Jun‐Hua Bai, Jin‐Hua Wang, Li‐Fang Zhang
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Chain‐growth polymerization of azide–alkyne difunctional monomer: Synthesis of star polymer with linear polytriazole arms from a core J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-07-19 Weiping Gan,Xiaosong Cao,Yi Shi,Haifeng Gao
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Surface‐initiated PET‐RAFT polymerization under metal‐free and ambient conditions using enzyme degassing J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-07-16 Soyoung E. Seo,Emre H. Discekici,Yuanyi Zhang,Christopher M. Bates,Craig J. Hawker
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Polymerization‐induced self‐assembly of metallo‐polyelectrolyte block copolymers J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-07-10 Md Anisur Rahman,Yujin Cha,Liang Yuan,Parasmani Pageni,Tianyu Zhu,Moumita Sharmin Jui,Chuanbing Tang
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Macroscopic and microscopic shape memory effects of block copolymers prepared via ATRP J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-07-01 Qihua Wang,Liming Tao,Zenghui Yang,Wojciech Raj,Yaoming Zhang,Tingmei Wang,Joanna Pietrasik
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Complex macromolecular structures from stable radical containing block copolymers J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-04-19 Azra Kocaarslan,Gorkem Yilmaz,Clemens Liedel,Yusuf Yagci
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Isotactic Regulation in the Radical Polymerization of Calcium Methacrylate: Is Multiple Chelation the Key to Stereocontrol? J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-01-30 Benjamin B. Noble,Michelle L. Coote
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Effect of surface modification of colloidal silica nanoparticles on the rigid amorphous fraction and mechanical properties of amorphous polyurethane–urea–silica nanocomposites J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-18 Oguzhan Oguz, Nicolas Candau, Stéphane H. F. Bernhard, Cagla Kosak Soz, Ozge Heinz, Grégory Stochlet, Christopher J. G. Plummer, Emel Yilgor, Iskender Yilgor, Yusuf Z. Menceloglu
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Synthesis and characterization of 9,9-bis(4-hydroxyphenyl and 4-aminophenyl)dibenzofluorenes: Novel fluorene-based monomers J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-18 Surasak Seesukphronrarak, Shinichi Kawasaki, Shigeki Kuwata, Toshikazu Takata
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Cover Image, Volume 57, Issue 22 J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-15
In their work presented on page 2214, Irfan and colleagues report a series of pH‐sensitive hydrogels synthesized via frontal polymerization. The authors utilized several methods, including FTIR, DSC, SEM, dynamic mechanical analysis, and swelling measurements to characterize the synthesized hydrogels. The cover image shows several SEM images of the compact and uniform porous microstructures of the
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Synthesis, electrochemistry, and electrochromic properties of branched thiophene polymers with different conjugation lengths J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-15 Weijun Li, Feifei Luo, Ling Zhang, Shuanma Yan, Ruiyang Zhao, Ning Ren, Yizhao Wu, Yuliang Chen, Yujie Dong, Mi Ouyang, Cheng Zhang
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Synthesis and properties of sulfur‐contained poly(silylene arylacetylene)s J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-15 Chuan Li, Jiawei Luo, Manping Ma, Junkun Tang, Qiaolong Yuan, Farong Huang
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Synthesis and cationic ring-opening polymerization of oxetane monomer containing five-membered cyclic carbonate moiety via highly chemoselective addition of CO2 J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-15 Naoto Aoyagi, Takeshi Endo
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Imine-based dynamic polymer networks as photoprogrammable amine sensing devices J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-14 Michael Kathan, Christoph Jurissek, Petr Kovaříček, Stefan Hecht
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Preparation of carboxyl-functionalized polyhedral oligomeric silsesquioxane by a structural transformation reaction from soluble rod-like polysilsesquioxane J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-14 Tomoya Kozuma, Yoshiro Kaneko
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Selective capture of Pd2+ by graft copolymer bearing LCST graft chain and metal adsorbing stem chain J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-14 Bungo Ochiai, Kazuyuki Tsuda
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Double-crosslinked reversible redox-responsive hydrogels based on disulfide–thiol interchange J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-14 Yunjiao Che, Stefan Zschoche, Franziska Obst, Dietmar Appelhans, Brigitte Voit
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Fabrication of a Novel Polymeric Scaffold for Amperometric Laccase Biosensor J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-14 Saniye Soylemez, Siddika Aybuke Bekmezci, Seza Goker, Levent Toppare
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Synthesis and Properties of Novel Side‐Chain Sulfonated Poly(Arylene Ether Sulfone)s for Proton Exchange Membranes J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-11 Lei Xiao, Xing Chen, Jingjing Xu, Kangcheng Chen, Jianhua Fang
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Tetraarylphosphonium perfluorocyclobutyl polyelectrolyte with low critical surface energy, high thermal stability, and high alkaline resistance J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-04 Wang Wan, Monte S. Bedford, Rhett C. Smith
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RAFT polymerization of 2‐hydroxyethyl methacrylate in a deep eutectic solvent J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-04 Arunjunai Raja Shankar Santha Kumar, Nikhil Kumar Singha
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Synthesis and crosslinking reaction of a novel polymer containing benzoxazine and phenyleneethynylene moieties in the main chain J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-04 Takumi Kobayashi, Masahide Goto, Masaki Minami, Fumio Sanda
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Synthesis and Hierarchical Self-Assembly of Diphenylalanine-Based Homopolymer and Copolymers By RAFT Polymerization J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-04 Ryo Yonenuma, Ai Ishizuki, Kazuhiro Nakabayashi, Hideharu Mori
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Cover Image, Volume 57, Issue 21 J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-11-01
In their work reported on page 2181, Tsai and colleagues prepared a novel polyhedral oligomeric silsesquioxane (POSS)‐containing block polymer, designated as st‐PMMA‐b‐PMAPOSS, with well‐controlled stereoregularity and the ability to recognize functional molecules using a living anionic polymerization method in the presence of Lewis acid. The St‐PMMA segment in st‐PMMA‐b‐PMAPOSS formed a helical structure
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Use of N-methyliminodiacetic acid boronate esters in suzuki-miyaura cross-coupling polymerizations of triarylamine and fluorene monomers. J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2017-07-03 Andrew B Foster,Viktor Bagutski,Josue I Ayuso-Carrillo,Martin J Humphries,Michael J Ingleson,Michael L Turner
Polytriarylamine copolymers can be prepared by Suzuki-Miyaura cross-coupling reactions of bis N-methyliminodiacetic acid (MIDA) boronate ester substituted arylamines with dibromo arenes. The roles of solvent composition, temperature, reaction time, and co-monomer structure were examined and (co)polymers prepared containing 9, 9-dioctylfluorene (F8), 4-sec-butyl or 4-octylphenyl diphenyl amine (TFB)
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Supramolecular polymerization of a ureidopyrimidinone-based [2]catenane prepared via ring-closing metathesis. J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2017-07-03 Abraham J P Teunissen,José Augusto Berrocal,Christiaan H W A Corbet,E W Meijer
The synthesis and supramolecular polymerization of a ureidopyrimidinone-based Sauvage-type [2]catenane is reported. The monomer synthesis explores many routes using the elegant metathesis catalysts of Bob Grubbs, yielding a catenane with one ureidopyrimidinone in each cycle. The supramolecular polymer obtained features both mechanical bonds and quadruple hydrogen bonding connections.
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Toward a versatile toolbox for cucurbit[n]uril-based supramolecular hydrogel networks through in situ polymerization. J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2017-06-22 Ji Liu,Cindy Soo Yun Tan,Yang Lan,Oren A Scherman
The success of exploiting cucurbit[n]uril (CB[n])-based molecular recognition in self-assembled systems has sparked a tremendous interest in polymer and materials chemistry. In this study, polymerization in the presence of host-guest complexes is applied as a modular synthetic approach toward a diverse set of CB[8]-based supramolecular hydrogels with desirable properties, such as mechanical strength
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Pyrene-cored covalent organic polymers by thiophene-based isomers, their gas adsorption, and photophysical properties. J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2017-05-07 Changfeng Li,Peixian Li,Linjiang Chen,Michael E Briggs,Ming Liu,Kai Chen,Xiaoxiao Shi,Deman Han,Shibin Ren
Two new pyrene-cored covalent organic polymers (COPs), CK-COP-1 and CK-COP-2, were synthesized via the one-step polymerization of two thiophene-based isomers, 1,3,6,8-tetra(thiophene-2-yl) pyrene (L1 ) and 1,3,6,8-tetra(thiophene-3-yl) pyrene (L2 ). The resulting pyrene-cored COPs exhibit rather different surface areas of 54 m2 g-1 and 615 m2g-1 for CK-COP-1 and CK-COP-2, respectively. The CO2 uptake
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Degradation of poly(β-amino ester) gels in alcohols through transesterification: A method to conjugate drugs to polymer matrices. J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2017-03-25 Prachi Gupta,Caroline Lacerda,Vinod Patil,Dipti Biswal,Paritosh Wattamwar,J Zach Hilt,Thomas D Dziubla
Poly(β amino ester) polymers have received growing attention in the literature, owing to their ease of synthesis, versatile co-monomer selection, and highly tunable degradation kinetics. As such, they have shown extensive potential in many biomedical applications as well. In this work, it is demonstrated for the first time that PβAE polymers containing primary and secondary amine groups can undergo
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Oxygen-mediated Polymerization Initiated by Oltipraz-derived Thiones. J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2017-02-11 Scott R Zavada,Joseph C Furgal,Nathan D Wood,Timothy F Scott
A pyrrolopyrazine-thione derived from oltipraz, a compound that has been investigated as a chemopreventive agent, affords radicals in the presence of thiols and oxygen via a redox cycle, an attribute that suggests its suitability as an initiator for oxygen-mediated polymerization. Here, we explore the utilization of this pyrrolopyrazine-thione, generated in situ from a precursor, as an initiator for
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Direct Access to Functional (Meth)acrylate Copolymers through Transesterification with Lithium Alkoxides. J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2017-02-10 Carolin Fleischmann,Athina Anastasaki,Will R Gutekunst,Alaina J McGrath,Phillip D Hustad,Paul G Clark,David S Laitar,Craig J Hawker
A straightforward and efficient synthetic method that transforms poly(methyl methacrylate) (PMMA) into value-added materials is presented. Specifically, PMMA is modified by transesterification to produce a variety of functional copolymers from a single starting material. Key to the reaction is the use of lithium alkoxides, prepared by treatment of primary alcohols with LDA, to displace the methyl esters
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Fluorene-containing tetraphenylethylene molecules as lasing materials. J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2016-11-21 C Orofino,C Foucher,F Farrell,N J Findlay,B Breig,A L Kanibolotsky,B Guilhabert,F Vilela,N Laurand,M D Dawson,P J Skabara
A series of star-shaped oligofluorene molecules, each containing a TPE core, have been specifically designed and produced to show effective aggregation-induced emission (AIE). Each molecule differs either in the number of fluorene units within the arms (e.g., 1 or 4, compounds 4 and 5), or the terminal group positioned at the end of each arm (e.g., H, TMS, or TPA, compounds 4, 6, and 7). Although they
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Properties of acyl modified poly(glycerol-adipate) comb-like polymers and their self-assembly into nanoparticles. J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2016-07-08 Vincenzo Taresco,Jiraphong Suksiriworapong,Rhiannon Creasey,Jonathan C Burley,Giuseppe Mantovani,Cameron Alexander,Kevin Treacher,Jonathan Booth,Martin C Garnett
There is an increasing need to develop bio-compatible polymers with an increased range of different physicochemical properties. Poly(glycerol-adipate) (PGA) is a biocompatible, biodegradable amphiphilic polyester routinely produced from divinyl adipate and unprotected glycerol by an enzymatic route, bearing a hydroxyl group that can be further functionalized. Polymers with an average Mn of ∼13 kDa
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Synthesis and Properties of Polycarbosilanes Having Lactose-Derived Structures J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-30 Kozo Matsumoto, Tatsuya Miyano, Yojiro Kotake
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Synthesis, thermal, rheological characteristics, and enzymatic degradation of aliphatic polyesters with lignin‐based aromatic pendant groups J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-30 Carlos R. Arza, Ping Wang, Javier Linares‐Pastén, Baozhong Zhang
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Acceleration effects of 1,5,7-triazabicyclo[4.4.0]dec-5-ene with 2-methylimidazole-intercalated α-zirconium phosphate as a latent thermal initiator in the reaction of glycidyl phenyl ether and hexahydro-4-methylphthalic anhydride J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-26 Osamu Shimomura, Suguru Sasaki, Kaori Kume, Atsushi Ohtaka, Ryôki Nomura
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Surface modification for nano-lignocellulose fiber through vapor-phase-assisted surface polymerization J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-26 Kubra Eksiler, Yoshito Andou, Hidayah Ariffin, Yoshihito Shirai
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Tapered copolymers of styrene and 4‐vinylbenzocyclobutene via carbanionic polymerization for crosslinkable polymer films J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-24 Daniel Leibig,Margarita Messerle,Tobias Johann,Christian Moers,Farzaneh Kaveh,Hans‐Jürgen Butt,Doris Vollmer,Axel H. E. Müller,Holger Frey
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Glass‐transition temperature governs the thermal decrosslinking behavior of Diels–Alder crosslinked polymethacrylate networks J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-23 Daniel J. Dobbins,Georg M. Scheutz,Hao Sun,Christopher A. Crouse,Brent S. Sumerlin
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Functionalization of cis‐1,4‐polyisoprene using hypervalent iodine compounds with tetrazole ligands J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-22 Rajesh Kumar,Kapil Dev Sayala,Yakun Cao,Nicolay V. Tsarevsky
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Supramolecular assembly of poly(ionic liquid) nanogel driven by host‐stabilized charge transfer interaction J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-23 Yuntao Tang, Ke Wang, Yong Zuo, Xi Chen, Yubing Xiong, Yumin Yuan
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Synthesis of metallosupramolecular polymers incorporating cage silsesquioxanes in the main chains J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-23 Mari Hashimoto, Shunichi Fujii, Hiroaki Imoto, Kensuke Naka
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Synthesis of molecular-weight-controlled polyfluorene with boronate at one end J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-18 Yu Tokita, Kotaro Sugawara, Riho Awayama, Yoshihiro Ohta, Tsutomu Yokozawa
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Synthesis, characterization, and CO2 uptake of mellitic triimide-based covalent organic frameworks J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-18 Hugo Veldhuizen, Alexandros Vasileiadis, Marnix Wagemaker, Tadhg Mahon, Durga P. Mainali, Lishuai Zong, Sybrand van der Zwaag, Atsushi Nagai
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Cover Image, Volume 57, Issue 20 J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-16
In their work reported on page 2104, Praban and colleagues prepared a series of tin(II) complexes supported by N2O2 bis(phenol)‐amine ligands from the reactions of Sn[N(SiMe3)2]2 with the corresponding ligands having different substituents on the aryl rings and N‐containing side arm. All complexes were active for solvent‐free polymerization of L‐lactide at 120 °C, giving poly(L‐lactide) with narrow
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Synthesis of π-conjugated polymer containing both thiophene and phosphole sulfide in the main chain by simultaneous post-element transformation of organotitanium polymer J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-16 Yoshimasa Matsumura, Hiroki Nishiyama, Shinsuke Inagi, Ikuyoshi Tomita
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Synthesis of Poly(Arylene Alkenylene)s by Pd-Catalyzed Three-Component Coupling Polycondensation of Diiodoarenes, Non-Conjugated Dienes, and Nucleophiles that Involves Chain Walking Isomerization J. Polym. Sci. A Polym. Chem. (IF 2.869) Pub Date : 2019-10-16 Liyi Tan, Daisuke Takeuchi, Kohtaro Osakada