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Competing formation of α and δ-FAPbI3 in perovskite ink using 2-methoxyethanol as the solvent J. Solid State Chem. (IF 3.3) Pub Date : 2024-03-14 Yin Xie, Zhuozheng Wang, Yan Cui, Liang Qiao, Kebin Chi, Dejun Shi, Yang Bai, Zhijie Wu, Shengbao He
2-Methoxyethanol (2-Me) is a promising solvent for large-area perovskite film preparation. Understanding the competing processes of α and δ-FAPbI in 2-Me is crucial for advancing the application of 2-Me in FAPbI film coating. In this study, FAPbI microcrystals are fabricated by inverse temperature crystallization method at 100 °C, and are used as a platform to investigate the competing formation of
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Complexity of the KNa2ZrF7, KNa2HfF7, and KNa2(Hf,Zr)F7 compounds J. Solid State Chem. (IF 3.3) Pub Date : 2024-03-12 Oksana Matselko, Morgane Poupon, Erika Samolova, Zuzana Vasková, Blanka Kubíková, Zuzana Netriová, Matej Mičušík, Miroslav Boča
New mixed-cation fluorides KNaHfF (2, = 8.213 (2) Å, = 6.126 (2) Å, = 5.979 (2) (1) Å, = 2) and KNa(Hf,Zr)F (refined composition KNaHfZrF; 2, = 8.2210 (8) Å, = 6.1288 (6) Å, = 5.979 (1) Å, = 2) together with isostructural KNaZrF (2, = 8.221 (2) Å, = 6.118 (2) Å, = 5.994 (2) Å, = 2) have been synthesised in aqueous solutions and structurally characterised at room temperature by powder and single-crystal
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An ultra-photosensitive viologen-based hybrid crystalline material with unconventional transfer pathways J. Solid State Chem. (IF 3.3) Pub Date : 2024-03-12 Yuan Shen, Xiao-Nan Li, Li Huang, Yang Hua, Xiao-Yang Yu, Run-Hong Song, Kun Huang, Wen-Bo Cui, Hong Zhang
Viologen units are widely used in UV/X-ray detection, photoelectric detection, intelligent anti-counterfeiting, and inkless printing owing to their excellent photo-induced electron transfer (PET). In the previous research, the traditional electron transfer channel types of highly photosensitive viologen-based PET materials were mostly O/X … N (X=Cl, Br, I). In this work, we synthesized a photochromic
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Covalently construction of C-GSH-AuNCs@UiO-66-NH2 composites as an efficient turn-on fluorescence sensor for UO22+ J. Solid State Chem. (IF 3.3) Pub Date : 2024-03-12 Hong-Bo Peng, Hua-Rui Nan, Shi-Qi Li, You-Qun Wang, Zhi-Min Dong, Zhi-Bin Zhang, Xiao-Hong Cao, Yun-Hai Liu
Due to the continuous expansion of the nuclear power industry, the exploitation of uranium resources has led to the discharge of large quantities of uranium-rich wastewater into the environment, which poses a major threat to the environment and human health. Rapid detection of uranium in water bodies is of great significance for early warning of uranium contamination in the environment, safe discharge
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Synthesis of cubic lutetium hydride at HPHT conditions and its implications J. Solid State Chem. (IF 3.3) Pub Date : 2024-03-10 Nishant N. Patel, Ajay K. Mishra
Binary rare earth hydrides are ideal hydrogen rich materials for the search of room temperature superconductivity. Even though there are plethora of such theoretical predictions, only a few binary hydrides show high T experimentally. The recent progress in the search for new ternary hydrides have led to the controversial discovery of room temperature superconductivity in the nitrogen doped lutetium
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Concentration and reaction duration effects on synthesizing ZIF67 derivatives with NH4BF4 and NH4HF2 as efficient active material of energy storage device J. Solid State Chem. (IF 3.3) Pub Date : 2024-03-09 Pin-Yan Lee, Yu-En Wang, Su-Ching Wang, Sadang Husain, Chutima Kongvarhodom, Sibidou Yougbaré, Hung-Ming Chen, Kuo-Chuan Ho, Yung-Fu Wu, Lu-Yin Lin
Zeolitic imidazolate framework-67 (ZIF67) with large surface area and tunable pore structure is intensively applied as a tailoring target for design active materials. An in-situ tailoring technique is proposed to design ZIF67 derivatives by using structure directing agents (SDA) to induce favorable morphology and composition. Ammonium fluoride is a common SDA for modifying surface properties of active
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Experimental studies on noncentrosymmetric Nd3Se4: Strongly correlated noncollinear ferromagnet J. Solid State Chem. (IF 3.3) Pub Date : 2024-03-08 Prabuddha Kant Mishra, Ashok Kumar Ganguli
We have synthesized polycrystalline NdSe by the solid state sealed tube reaction route followed by structural characterization and magnetic property measurements. The temperature-dependent magnetization studies reveal the existence of competing magnetic interactions below the ferromagnetic ordering ( ≈ 48.4 K). The observation of hysteresis in the isothermal magnetization data with the coercive field
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EY@UiO-67-CDC-(CH3)2 as an ultra-sensitive ratiometric fluorescence sensor for visible and selective detecting of nitrite J. Solid State Chem. (IF 3.3) Pub Date : 2024-03-08 Xin Zou, Wen-yi Chen, Xu-shan Li, Qian Sun, En-qing Gao
Nitrite is widely used in production and daily life, and detecting this substance has always been crucial for human health or environment monitoring. Here, a dual-emitting dye@MOF composite, EY@UiO-67-CDC-(CH), has been constructed and demonstrated that this material could detect nitrite ions with highly selective and anti-interference properties. By incorporating an organic anionic dye (Eosin Y) within
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Enhancing OER and overall water splitting performance of amorphous NiFe LDH grown on Ni foam with the needle-like NiCoP transition layer J. Solid State Chem. (IF 3.3) Pub Date : 2024-03-04 Xiaoyu Chen, Xiaoshuai Yu, Chuncheng Yang, Guoyong Wang
The oxygen evolution reaction is more challenging than the hydrogen evolution reaction in overall water splitting, not only because the four-electron reaction is more complex but also because the oxidizing environment of the anode reaction is more destructive to the electrode material. Generally, such destruction results in the formation of an oxide film that hinders the transition of electrons and
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Synthesis, structure and electrochemical properties of Co-MOF containing pyridine polycarboxylic acid J. Solid State Chem. (IF 3.3) Pub Date : 2024-03-04 Mengyao Ma, Liwen Wang, Jia Jiang, Hao Yu, Wenqian Sun, Jinyan Wang, Fengdi Zhou, Xiuling Xu, Yulan Bai
Metal-organic frameworks (MOFs) have been widely used in filed of electrochemistry. Compared with traditional inorganic porous materials, the polyvalent pyridinecarboxylic acid ligands have many advantages which contains more active sites, flexible coordination mode, adjustable structure. Therefore, it becomes good choice for constructing MOFs materials with excellent performance. In this paper, a
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Unlocking the potential of Cu3SbSe3: Ultralow thermal conductivity and enhanced thermoelectric performance J. Solid State Chem. (IF 3.3) Pub Date : 2024-03-04 Kivanc Saglik, Jinfeng Dong, Danwei Zhang, Thiri Zaw Hsu, Solco Samantha Faye Duran, Jing Cao, Qiang Zhu, Rong Ji, Seng Kai Wong, Siew Lang Teo, Feng Xia Wei, Qingyu Yan, Ady Suwardi
CuSbSe, with its ultralow thermal conductivity and Earth-abundant elements, has emerged as a promising thermoelectric material. However, synthesizing its pure phase and achieving effective doping have proven to be challenging. In this study, we present our findings on the investigation of thermoelectric properties of stoichiometric and off-stoichiometric CuSbSe compositions along with various doping
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CuInSe2 nanoplatelets decorated CdS nanosheets as 2D-2D S-scheme photocatalyst for photocatalytic H2 generation coupled with benzyl alcohol oxidation and microplastic degradation J. Solid State Chem. (IF 3.3) Pub Date : 2024-03-02 Yimin Liu, Qingru Zeng, Shunyan Ning, Yufeng Gan, Toyohisa Fujita, Yuezhou Wei, Xinpeng Wang, Deqian Zeng
In this work, a novel 2D layered heterojunction for various photocatalytic reactions is constructed by hybridizing CdS nanosheets and CuInSe nanoplatelets. By adjusting CuInSe content, the CdS-16% CuInSe sample displays a visible-light-induced H production rate of 4382 μmol g h, approximately 7.5 times higher than pristine CdS. Furthermore, CdS-16% CuInSe demonstrates exceptional photocatalytic activity
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Improvement of Cu2ZnSnS4 films properties using sulfurized precursor films with Cu-poor/Zn-rich ratio J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-29 Xinzhi Wu, Yanyan Yuan, Yaping Duan, Yang Chen, Xiaoyi Liu
The precursor films with Cu-poor/Zn-rich composition ratio prepared by spin coating were sulfurized at different temperatures. Effect of sulfur powder amount, annealing temperature and time on the properties of films were comprehensively investigated. The results show that 0.5 g sulfur powder atmosphere can effectively avoid the loss of S in CZTS precursor and secondary phase formation during sulfurization
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Structure directing factors and photophysical properties of five Cu(I)-iodide materials with N-donor heteroaromatic ligands J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-28 Francisco Sánchez-Férez, Xavier Solans-Monfort, Luis Rodríguez-Santiago, Teresa Calvet, Mercè Font-Bardia, Josefina Pons
In this work, two families of Cu(I)-iodide complexes with -heterocyclic donors ligands bearing amide, phenyl, chloro, and methyl substituents have been synthesized to combine two structural directing factors: attractive interactions and steric bulkiness. To this aim, we synthesized five Cu(I)-iodide based complexes: two 1D coordination polymers [CuI(isn)] () and {[CuI(nic)]·ACN} (), one tetrameric
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Fluorescence turn off-on continuous response of dual lanthanide metal organic frameworks for selective detecting fluoroquinolone antibiotics J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-28 Wang Donghan, Kang Han, Wang Xinrui, Zhou Wei
Eu and Tb as central ions and 1,4-phthalic acid (HBDC) as ligand, a dual lanthanide metal-organic framework, Eu-Tb(BDC), was synthesized by co-precipitation method. The products performed stable crystal structure and adjustable fluorescence color. EuTb (BDC) was selected as an optimized probe to detect norfloxacin (NFX) in urine, and the fluorescence color was found to transfer from bright yellow to
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Synthesis, characterization, and structural analysis of (1-x) Eu2Ti2O7 – x ZnO solid solution with a pyrochlore structure: Insights for potential applications in hydrogen storage systems J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-28 Brahim Arfoy, Mohamed Douma, El Hossain Chtoun, Oualid El Haddade, Ibrahim Allaoui, Mohammad Elmourabit, Soukaina El Abbadi, Hajar El Moustansiri, Leila Loubbidi
This study focuses on the synthesis and characterization of a (1-x) EuTiO – x ZnO solid solution with a pyrochlore structure using a solid-state method. The structural investigations of the prepared materials were carried out using powder X-ray diffraction (PXRD), field emission scanning electron microscopy (FE-SEM), Fourier transform infrared (FT-IR), and Raman spectroscopy. These techniques confirmed
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Low-temperature synthesis of transparent conducting La-doped BaSnO3 via rejuvenation of the dried peroxo-precursor J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-28 Sushobhita Chawla, Garima Aggarwal, Akash Kumar, Akhilender Jeet Singh, Patrick M. Woodward, K.R. Balasubramaniam
In this article, we develop a low-temperature route for the synthesis of the high figure-of-merit transparent conductor, La-doped BaSnO. Towards this, we first study the evolution of the cubic perovskite phase of the undoped BaSnO during solution combustion synthesis. A peroxo/superoxo precursor synthesized HO assisted co-precipitation is employed as the oxidizing agent. Typically, precursor drying
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Lead-free (K0.5Na0.5)NbO3 co-substituted with Ta5+ and Er3+: Structural, optical, dielectric and electrical properties J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-27 Najwa Gouitaa, Taj-dine Lamcharfi, Farid Abdi, Omar Bajjou
The lead-free KNaNbO (KNN) ceramics co-substituted with 0.05 mol Ta and x mol Er ions (K, Na) ErNbTaO, with x = 0.00 to 0.05, have been successfully manufactured by using the solid-state reaction. The XRD results showed that the ceramics crystalize in pure perovskite with a trace of secondary phase, for low Er levels (x ≤ 0.02). Above this rate, the presence of secondary phases became more significant
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Green and facile synthesis of OH-functionalized UiO-66 with controlled particle sizes to improve the selective separation of CO2/N2 J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-27 Na Yang, Tao Zhao, Xue Wang, Junkuo Gao
The escalating levels of carbon dioxide in flue gas and the resultant greenhouse effect have heightened the need for adsorbents with high CO sorption and separation capabilities. However, Traditional heated synthesis methods are energy-intensive and often involve toxic solvents, which are not viable for widespread industrial use. This study introduces a room-temperature, eco-friendly synthesis technique
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Construction of photoactive MOF for photocatalytic oxidative organic transformation J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-27 Weijun Dai, Ci Kong, Xiang Li, Baomin Fan, Chixian He, Jian-Jun Liu
The incorporation of photoresponsive component into metal-organic frameworks (MOFs) is intriguing because they can confer additional properties such as photomagnetic behavior, light-controlled electrical conductivity, and photocatalysis. Naphthalene diimide (NDI) is organic dye that absorbs visible light and have π-electron-deficient planes and photochemical characteristics. NDIs are ideal for creating
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Facile synthesis of BiOI/BaNbO3 composite for rapid sonocatalytic degradation of tetracycline hydrochloride J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-27 Yaqi Wang, Feng Li, Taohai Li
Sonocatalysis, a vibration-induced chemical reaction, has shown great potential for catalytic applications. This study used a water bath method to prepare BiOI/BaNbO composites with various mass ratios. Under the influence of sonocatalysis, the BI/B-0.5 catalyst could degrade tetracycline hydrochloride up to 96.5 % after 20 min, and the stability was good. In comparison to pure BiOI and BaNbO, the
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One-pot synthesis of BiSCl–Bi6.88S8·64Cl3.36 nanorods for rhodamine B photodegradation in water J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-27 Zehao Li, Wangzhe Xia, Rui Qin, Fangping Wu, Zhihan Cai, Jianhong Wu
In the domain of water treatment, photocatalytic degradation presents a compelling approach. However, the quest for photocatalysts that exhibit superior solar energy absorption and conversion remains a challenge. We explore rod-shaped bismuth-rich chalcohalide photocatalyst BiSCl–BiSCl by simple temperature control and demonstrate the proficiency in degrading organic pollution under visible light.
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Experimental investigation on hydrophilic functionalized CaCl2@UIO-66 composites for water adsorption and heat storage J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-24 Bo Lou, Daheng Zhou, Jiaxin Ding, Qiongyi Huang
Porous materials with high adsorption capacity can enhance the efficiency of water-based adsorption heat transformation systems. The composites salt in porous matrix (CSPM) are considered to be very promising materials. In this paper, the UIO-66-NH and UIO-66-NO metal-organic framework were used as the porous matrix to synthesize composites with CaCl as the hygroscopic salt. The water adsorption and
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Synthesis and properties of the NdSF compound, phase diagram of the NdF3–Nd2S3 system J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-24 V.M. Grigorchenko, M.S. Molokeev, A.S. Oreshonkov, A.S. Aleksandrovsky, A.V. Kertman, M.U. Abulkhaev, A.S. Mereshchenko, I.O. Yurev, N.А. Shulaev, D.N. Kamaev, A.V. Elyshev, O.V. Andreev
The NdF–NdS system attracts attention of researchers due to the possibility of using LnSF compounds (Ln = rare earth element) as possible new - and -type materials. The samples of this system were synthesized from NdF and NdS. The NdSF compound belongs to the PbFCl structural type, 4/ space group, unit cell parameters: = 3.9331(20) Å, = 6.9081(38) Å. The experimentally determined direct and indirect
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Influence of Hf doping on structural, morphological, optical and electrochemical properties of NiO thin films: Electrochromic application J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-23 B. Brioual, A. El-Habib, Z. Rossi, A. Aouni, M. Addou, M. Diani, M. Jbilou
In this study, the authors investigated the influence of hafnium doping on the properties of NiO thin films using the spray pyrolysis (SP) method. A comprehensive analysis was conducted to evaluate the structural, morphological, optical, and electrochemical characteristics of the deposited films. Techniques such as X-ray diffraction analysis (XRD), Raman spectroscopy, scanning electron microscopy (FESEM)
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Study of structural, X-ray photoelectron spectroscopy, Raman and temperature-dependent magnetic studies of NiFe2O4/CoCr2O4 nanocomposites J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-23 K. Manjunatha, Hsin-Hao Chiu, Ming-Kang Ho, Tsu-En Hsu, A. Bajorek, Sheng Yun Wu, Manish Gupta, Abdullah A. Al-Kahtani, Mohd Ubaidullah, S.O. Manjunatha, Nagaraj Basavegowda, Jagadeesha Angadi V
In recent years, cobalt chromites/nickel ferrites have been attractive candidates for significant applications as nanomagnets. In the present work, structural, electronic, vibrational and low-temperature magnetic properties of NiFeO CoCrO, and NiFeO/CoCrO nanocomposites were investigated. Refined XRD patterns and the Raman spectra confirm the formation of the pure crystalline spinel cubic phase. The
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Anharmonic lattice dynamics dominated ion diffusion in γ-Li3PO4 J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-23 Qiwei Hu, Boyu Lin, Yang Yang, Aning Wu, Yuxin Zhao, Xianpei Ren, Fang Ling, Qiang Li, Jing Yang, Chao Li, Yuquan Yuan
Understanding the influences of lattice dynamics on ionic transport holds the potential to shed light on advanced strategies for designing ionic conductors. However, their utilization remains infrequent due to a limited grasp of anharmonic lattice dynamics within ionic conductors. Herein, we focused on the anharmonic lattice dynamics of γ-LiPO, a prototype material for lithium superionic conductor
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AC conductivity and dielectric relaxation behavior of lamellar benzyltrimethylammonium/V2O5 nanocomposite J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-22 H. Nefzi, M.K. Chine, F. Sediri
Lamellar benzyltrimethylammonium/VO nanocomposite has been prepared hydrothermally. Electrical and dielectric properties as a function of temperature and frequency of the nanocomposite were reported. The decrease in Z′ with increasing temperatures indicates the existence of a negative temperature resistance coefficient (NTCR) characteristic of the semiconductor material. For T > 432 K, the values of
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Phosphotungstic acid-coated glass fibre with thin Pd-sputtered films enhances fuel cell performance and durability in proton exchange membrane fuel cells (PEMFCs) J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-21 Md Shahjahan Kabir Chowdury, Ye Ji Park, Sung Bum Park, Yong-il Park
This study investigated the potential utilization of glass microfiber filters (GMFs) reinforced with hetero polyacid (12-phosphotungstic acid, HPWO; PWA) in hydrogen fuel cells. Nano-sized PWA powders were confirmed through XRD and Raman spectra. Several analytical techniques confirmed the preservation of the Keggin structure of PWA following the absorption (interfacial contact) procedure using the
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Competition between chiral anomaly and weak antilocalization in Cd3As2 nanoplates J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-20 Hongwei Zhang, Min Wu, Yuyan Han, Xiangde Zhu, Jianhui Zhou, Wei Ning
Negative longitudinal magnetoresistivity (nLMR) induced by the chiral anomaly together with the weak antilocalization (WAL) due to the quantum interference can be regarded as remarkable magnetotransport signatures for three-dimension (3D) topological semimetals. Here, we report the observation of high-temperature competition between the chiral anomaly and WAL by magnetotransport measurements on high-quality
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A graft-modified sponge with COFs for wastewater treatment and iodine adsorption J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-19 Renjie Li, Yaning Xu, Yong Li, Ying Qiao, Dan Tian
Azo dyes, used in large quantities in drinks, have become a threat to human health. In the treatment of dyes, the method of chemical adsorption is often used due to its simple and efficient features. Covalent organic frameworks (COFs) material with the characteristics of stability and porosity has great potential for the adsorption of azo dyes. However, the application of COFs is severely limited by
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Adsorptive separation of Xe/Kr mixtures by microporous lanthanide metal-organic frameworks with high thermal stability J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-19 Rong Tan, Biquan Su, Peng Wang, Nong Wang
Efficient separation of Xenon (Xe) and Krypton (Kr) is a significant process for their wide industrial applications and potential environmental concerns. Owing to the inert atomic gases (Xe and Kr) nature with similar physical and chemical properties, it is a great challenge to achieve efficient separation of the Xe/Kr mixture. Herein, we report a series of microporous Lanthanide based metal-organic
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Effects of Al3+ doping on the structure and electrical properties of La0.9Sr0.1CrO3 ceramics J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-17 Yunfei Wang, Hao Sun, Yafei Liu, Lili Zhi, Aimin Chang, Bo Zhang
Perovskite lanthanum chromate (LaCrO) has been widely investigated for applications as functional material, its properties can be finely tuned through doping. This study explores the effect of Al doping on the structure and electrical properties of LaSrCrAlO ceramics. Our findings reveal that Al doping significantly influences the consistency of grain size and electrical transport properties of these
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Synthesis of isotype heterojunction by series calcination of multicomponent for high efficiency photocatalytic reduction of uranium J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-17 Ye'an Zhu, Zhiwen Wu, Yidan Nie, Bo Wang, Jialin Qiu, Zongbo Xie, Zhanggao Le
Photocatalytic reduction of soluble U(VI) to insoluble U(IV) is considered to be one of the most effective strategies for uranium contaminant removal. Graphite carbon nitride (g-CN) was widely used in the photocatalytic reduction of uranium due to its adjustable band structure and excellent chemical stability. Herein, through supramolecular self-assembly method, using thiourea as precursors, a carbon
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Progress in the study of binary chalcogenide-based thermoelectric compounds J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-16 Jifang Zheng, Mengjie Ma, Guangsai Yang, Yuandong Wu, Dajiang Mei
As a novel and environmentally friendly energy source, thermoelectric (TE) materials are receiving more and more attention because of their unique capability to directly convert heat into electricity. Chalcogenide-based materials have been extensively explored as promising TE candidates in the past years, primarily attributed to their unique properties in accommodating diverse compositions and structures
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Preparation of the 2,2′-biimidazole-based hypercrosslinked polymers by bottom-up synthetic strategy and their application for adsorping and fluorescence sensing 2,4-dinitrophenol J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-15 Qi Peng, Yu-Xia Zhang
The 2,2′-biimidazole-based hypercrosslinked polymers (2,2′-biimidazole-based HCPs, BIMM-3 and BIMM-4) were prepared by the synthetic strategy of one-pot bottom-up with nitrogen-rich 2,2′-biimidazole and triiodomethane or tetra-iodine methane for the first time. This new strategy offers the resulting HCPs presented nitrogen-rich and electron-rich. The as-synthesized 2,2′-biimidazole-based HCPs exhibit
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The study of electronic structure and magnetic properties of ferromagnetic Kondo-lattice CePd2 P2 from the first-principles J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-15 M. Sahakyan, V.H. Tran
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The use of simple structural parameters of energetic metal-organic frameworks to assess their density J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-13 Zeinab Dalirandeh, Mohammad Jafari, Ali Mousaviazar
A new method is presented for accurately estimating the density (D) of energetic material-organic frameworks (EMOFs), which has vital role in determining their performance. The experimental density data for 124 EMOFs, which are composed of five or six-membered heterocyclic rings, has been used to develop and analyze the model. The model is constructed based on simple structural parameters and can be
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First-principles investigation on molecular adsorption on 2D perovskite toward optoelectronic application J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-13 Lei Zhang, Yiru Huang
Halide perovskite materials have received attention for optoelectronic applications, and it is promising to further engineer the perovskite systems via surface molecular adsorption to improve optoelectronic properties. In this study, we comprehensively investigate atomic structures and properties of surface molecule-modified low-dimensional halide perovskite systems represented by CsPbBr via first-principles
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Detailed studies on characterization and photocatalytic hydrogen production of ammonium tetrathiomolybdate and tetrathiotungstate pyrolysis products J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-13 Dehang Ma, Mingcai Yin, Miaomiao Xue, Yaoting Fan
MoS and WS are two promising candidates for photocatalytic hydrogen production, and pyrolysis is one of the conventional and useful methods for their preparations. However, systematic investigations about the influences of pyrolysis conditions on their photocatalytic hydrogen production performances are still unreported. Then in this paper, a series of pyrolysis products of ammonium tetrathiomolybdate
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High dielectric permittivity and relaxation-induced dielectric pulsing effect-like in [1,3-bis(1-methylimidazolium)propane][Pb2I6] crystal J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-12 Shao-Xian Liu, Zhi-Xing Han, Yuan-Bo Tong, Xiao-Ming Ren
Herein, a new hybrid, [1,3-bis(1-methylimidazolium)propane][PbI] (), was synthesized and thoroughly characterized using microanalysis, thermogravimetric analysis (TG), differential scanning calorimetry (DSC), and powdered X-ray diffraction (PXRD) techniques. The crystal structure of reveals one-dimensional face-sharing PbI octahedral chains composed of Pb and I ions, with the disordered 1,3-bis(1-
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Rapid and scalable synthesis of porous organic cages with solvent recyclability J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-11 Liangxiao Tan, Siyu Ren, Jian-Ke Sun
Herein, we report the feasible synthesis of a series of porous organic cages (POCs, e.g., CC1, CC2, CC4, and CC3–OH) through a straightforward and effective dynamic solvent-mediated strategy. Notably, the preparation of POC nanocrystals can be significantly shortened from days/weeks (by traditional methods) to just 4 h, even at a large scale (around 2 g), due to the accelerated imine-bond formation
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Water splitting of nickel foam-supported CuCo2S4@CoFe-LDH efficient bifunctional catalysts J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-11 Weiguo Zhang, Dexuan Zheng, Hongzhi Wang, Suwei Yao
The development of highly efficient and low-cost bifunctional electrocatalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is the key to the industrialization of large-scale hydrogen production, while the development of non-precious-metal catalysts that can be substituted for precious-metal materials is the current trend of research. In this paper, nickel foam (NF) self-supported
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Phase diagram study of Na2O–ThO2–P2O5 system and investigation of thermo physical properties of quaternary compounds J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-10 Geeta Patkare, Muhammed Shafeeq, Meera Keskar, Rohan Phatak
The subsolidus phase relations in NaO–ThO–PO pseudo ternary system were determined at 1223 K. Synthesis of all the phases, used for drawing phase diagram, was carried out by solid state route. Formation of ternary and quaternary compounds in NaO–ThO, NaO–PO, ThO–PO and NaO–ThO–PO systems was confirmed at 1223 K. With the help of these compounds and phase analysis of number of synthetic mixtures, prepared
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The photocatalytic degradation performance and mechanism of rod-like hollow derivatives from Co-doped MIL-68(In) under visible light J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-10 Xiaolan Guo, Xiaoman Li, Yuxin Huang, Yongjun Peng, Tongke Hu, Yazhen Chen, Jianhua Cheng
In this study, we synthesized a convenient and efficient composite photocatalyst, InO/CoO from the pyrolysis of Co-doped MIL-68(In). Structural characterization indicates that the composite material exhibited a rod-like hollow structure, thus increasing the specific surface area. Meanwhile, InO/CoO forms a PN heterojunction, which reduces the recombination rate of photogenerated hole-electron pairs
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Unconventional critical behavior in room temperature magnetocaloric material: Fe30Cr45V25 all d-metal Heusler alloy J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-09 Kowsalya Murugan, M. Karunakaran, Srikanti Kavita, S. Paulraj, Rudra Banerjee, Kathirvel Venugopal
Comprehensive study on the critical behavior and magnetocaloric properties of FeCrV is carried out. The ferromagnetic alloy undergoes a second-order magnetic phase transition at = 300 K. The critical exponents of FeCrV are = 0.380, = 1.293, and = 4.389. Although the obtained exponents do not fall into any conventional universal classes (slightly relatable with 3D Heisenberg type), they get renormalized
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Divalent doping of the EuPd3S4 mixed valence system J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-09 Emma A. Pappas, D.H. Ryan
We investigate the solubility of divalent alkaline earths calcium and strontium in where Eu and Eu ions are present in equal amounts on distinct sublattices. Contrary to a recent yttrium and lanthanum substitution study where complete europium replacement is possible, and there are significant changes in the europium valence, here we observe severely limited solubility (x≲0.1 (Ca) and x≲0.25 (Sr))
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High intrinsic proton conduction in cerium(IV) metal-organic framework constructed by bromine-grafted terephthalic acid J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-09 Li-Li Gao, Jun-Yang Feng, Hui-Min Ren, Gang Li
Organic linkage functionalization has been demonstrated to be an efficient approach for improving the proton conductivity of metal-organic frameworks (MOFs). Herein, we successfully synthesized a functionalized MOF, , employing cerium(IV) ion and 2, 5-dibromoterephthalic acid (HBDC-Br) ligand. Since high electronegativity and hydrophilicity bromine may play a major role in boosting the proton conduction
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Wide-range temperature sensing regulated by the excited-state intramolecular proton transfer in main-group metal-organic frameworks J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-08 Dan Li, Xin Yan, Chen-Chen Xing, Peng Zhang, Quan-Guo Zhai
The luminescent properties of main-group metal-organic frameworks (MOFs) can usually be modulated by organic ligands, and thus realizing temperature sensing over a wide range. Herein, a step-by-step decoration of hydroxyl groups on terephthalic acid (BDC) ligand was involved to regulate the excited-state intramolecular proton transfer (ESIPT) process of the ligands and thus the temperature sensing
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Effect of different preparation technologies of CuCo2O4 on electrocatalytic activity for oxidation of alcohols J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-06 Zhiyang Zhong, Jinyang Yan, Bowen Chen, Qinghui Zhang, Yingying Zhu, Siyan Xu, Aijuan Xie, Shiping Luo
CuCoO for electrocatalytic oxidation of alcohols (methanol, ethanol, ethylene glycol, glycerol) were successfully prepared by coprecipitation method (C-CuCoO), solvothermal method (S-CuCoO) and bimetallic MOF template method (B-CuCoO), respectively. The effect of different preparation technologies on the structure, morphology of CuCoO were studied by X-ray diffraction (XRD), scanning electron microscope
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Enhanced microwave dielectric properties in LiAlO2 ceramics by Li+ substitution for Al3,+ J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-06 Zezhen Yin, Yun Zhang, Shihua Ding, Tianxiu Song, Xiaoning Li, Jiaying Dan
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Synthesis of thiophene Schiff base functionalized UiO-66 for enhanced Cu(II) ion adsorption capacity and selectivity J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-06 Ying Yang, Yan Wang, Qiongxin Gou, Yuanyuan Zhang, Yuqi Wu, Yuhui Luo
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Dual-emission Mn-doped CsPbCl3 QDs in collaboration with CsPbBr3 QDs applied in excitation-sensitive flexible anti-counterfeiting technologies J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-05 Zhen Yang, Chang-Qing Lin, Mao-Lin Liu, Han Wang, Chun-Yang Pan
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How to build a homologous series from parent compounds: Synthesis, crystal, and electronic structures of La2Ni2Al·n(LaNi2Al) J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-03 Anna I. Tursina, Sergey N. Nesterenko, Ilja V. Chernyshev, Alexey N. Kuznetsov
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Understanding copper sulfide formation from layered template and their use as power electrode materials in aqueous electrolyte J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-03 Julien Sarmet, Fabrice Leroux, Christine Taviot Gueho, Patrick Gerlach, Camille Douard, Thierry Brousse, Gwenaëlle Toussaint, Philippe Stevens
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Synthesis and characterization of the rare-earth chloride complexes with N,N,N′,N′-tetramethylmalonamide J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-03 Dmytro V. Kravchuk, Richard E. Wilson
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Short-time X-ray irradiation induced long afterglow and photostimulated luminescence from Sr2GeO4: Pr3+ J. Solid State Chem. (IF 3.3) Pub Date : 2024-01-30 Zewen Liu, Jiaxu Zhang, Runyao Liu, Mingliang Zhang, Xiaoyan Fu, Tongyan Lin, Naihui Chen, Hongwu Zhang
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Preparation and photocatalytic properties of Zr–BiOI/GO composites J. Solid State Chem. (IF 3.3) Pub Date : 2024-02-02 Lifang Wang, Ruqin Gao, Jianling He, Jianping Huang, Hongye Chen, Wenzhi Yao, Xin Cai