A new poly (vinyl chloride) (PVC) membrane electrode using 2-benzoylpyridine semicarbazone as membrane carrier with dioctylphthalate as plasticizer and sodium tetraphenylborate (NaTBP) as anion excluder has been fabricated and investigated as Zn(II)-selective electrode. Best potential response is observed for the composition PVC 30%, plasticizer 58%, NaTBP 8% and ionophore 4% (w/w). The sensor showed

The main objective of this study was to assess the effectiveness of TiO2-Al2O3 nano-mixture used as filler in improving packaging films performance. Polylactic acid/titanium dioxide (PLA/TiO2), polylactic acid/alumina (PLA/Al2O3) and polylactic acid/TiO2-Al2O3 (PLA/TiO2-Al2O3) nanocomposite films were successfully prepared via melt mixing process and thoroughly characterized by FTIR spectroscopy, X-ray

Laser direct joining of carbon fiber reinforced thermoplastic (CFRTP) composite plate and titanium alloy plate with a thickness of 2 mm was performed with swing laser. Numerous air bubble of submillimeter size were observed inside the fusion zone of CFRTP and titanium alloy at the cross section of the joints. The air bubble characteristics were analyzed based on the morphology and size, while the formation

Glycidyl azide polymer (GAP) is well known as an energetic prepolymer, but its application as a binder in propellants is limited due to its relatively high glass transition temperature and relatively poor mechanical properties. Copolymerization of GAP with polypropylene glycol (PPG) has been shown to improve GAPs properties because of the good thermal and mechanical properties of PPG. In this research

Quality consistency is essential in maximizing the productivity rate of the injection molding process and minimizing the production cost. The quality consistency problem is particularly acute in the case of injection molding processes performed using regrind resin, for which the rheological properties are less uniform and more unpredictable than those of virgin material. Accordingly, the present study

This article describes the development of a mathematical model of forward roll coating of a thin film of a non-Newtonian material when it passes through a small gap between the two counter-rotating rolls. The conservation equations of mass, momentum, and energy in the light of LAT (lubrication approximation theory) are non-dimensionalized and solutions for the velocity profile, flow rate, pressure

This work focuses on the potential use of cellulose fibers extracted from Mediterranean saltbush (Atriplex halimus) as a filler in the polymeric matrix. The fully biodegradable composites were prepared from polylactic acid (PLA) as matrix and microcellulose fibers ranging from 0 to 15 wt.%. The influence of the fiber content on the structure, mechanical, thermal, and water absorption properties was

Porous implants play a crucial role in allowing ingrowth of host connective tissue and thereby help in keeping the implant in its place. With the aim of mimicking the microstructure of natural extracellular matrix, ultrahigh-molecular-weight polyethylene (UHMWPE) porous samples with a desirable pore size distribution were developed by combining thermally induced phase separation and salt leaching techniques

Star-shaped arylacetylene resins, tris(3-ethynyl-phenylethynyl)methylsilane, tris(3-ethynyl-phenylethynyl) phenylsilane, and tris (3-ethynyl-phenylethynyl) silane (TEPHS), were synthesized through Grignard reaction between 1,3-diethynylbenzene and three types of trichlorinated silanes. The chemical structures and properties of the resins were characterized by means of nuclear magnetic resonance, fourier-transform

Glass ceramics from the CaO–P2O5–SiO2 system were synthesized. They were characterized by XRD, SEM and EDX methods. It was found that they contain two crystalline [Whitlockite, Ca3 (PO4)2 and Hydroxylapatite, Ca5 (PO4)3 (OH)] and one residual amorphous phase. The ceramics are composed of porous aggregates of fine particles with predominant macro- and mesopores in it. The ceramics were used as a functional

A novel optical probe consistinsg of Ag@PANI (silver-polyaniline) nanocomposites was developed for detection of mercury ions (Hg2+). The poly-dispersed Ag@PANI nanocomposites were synthesized by complexation reaction method. We studied structural and functional properties of polymer nanocomposites thoroughly. Ag@PANI nanocomposites consist of fibrous morphology with a mean particle size of 31.39 nm

In this study, retinoic acid loaded-PLGA-gelatin matrixes were prepared with both freeze-casting and freeze-drying techniques. Herein, the effect of unidirectional microstructure with tunable pores on release profile, cellular adhesion, migration, and differentiation was compared. Morphological observation determined that highly interconnected porous structure can be formed, but lamellar pore channels

In this work, polypropylene (PP) filled with different proportions of CoSt were prepared in a twin-screw extruder by compounding technique. Eight films of these compounds were prepared using compression moulding. The modified PP films were characterized for chemical, physical, thermal, and morphological properties (before and after biodegradation). The biodegradation of the CoSt filled PP films was

Polymer blends have been widely used as tribological materials for replacements of traditional metals and ceramics. Polymer blends consist of the reinforced phase, the matrix phase and interfaces between reinforced and matrix phase. Although the interface structure of polymer blends is usually small in size, it is one of the key factors for deciding the physical and tribological properties of polymer

Journal Name: Journal of Polymer Engineering Volume: 40 Issue: 8 Pages: i-iii

Journal Name: Journal of Polymer Engineering Volume: -1 Issue: ahead-of-print

Non-small cell lung cancer (NSCLC) contributes to about 85% of lung cancer. By 2040, lung cancer cases estimated to rise to 3.6 million globally. Brigatinib (BG) acts as tyrosine kinase inhibitors that target the epidermal growth factor receptor of the epithelial lung cancer cells. BG loaded nanosponges (NSs) were prepared by the emulsion solvent evaporation technique using ethylcellulose (EC) and

Composite-nanofiltration membranes based on polysulfone (PSU) and functionalized graphene oxide (f-GO) were prepared for dye removal from aqueous media. Graphene oxide (GO) was introduced to enhance the performance of these membranes. GO was functionalized using an aminated heterocyclic compound, namely 6-amino-4-(4-nitrophenyl)-3-methyl-4-phenyl-4,7-dihydro-1H-pyrazolo-[3,4-b]pyridine-5carbonitrile

Hexagonal boron nitride (h-BN) nanoplatelets (0.6 μm in diameter and 100 nm in thickness) are introduced into epoxy resin to improve the polymer’s thermal conducting ability. As expected, the thermal conductivities (TCs) of the composites, especially the in-plane TCs, are significantly increased. The in-plane TC of the epoxy composites can reach 1.67 W/mK at only 0.53 wt% loading, indicating h-BN nanopletelets

In this study, thermoplastic polyurethanes (TPUs) containing trisilanol isooctyl polyhedral oligomeric silsesquioxane (POSS), a reactive nanofiller, were synthesized and characterized rheologically and morphologically, and the effects of POSS content on the melt thermal stability of the TPUs are investigated. Samples containing 0, 0.23, 0.57, 1.14, and 2.23% (w/w) POSS were synthesized by reactive

The digital photoelastic technique is used to characterise the necking behaviour of isotactic polypropylene (iPP) fibres. The effect of stretching rate on necking initiation is studied. The birth of necking is observed using photoelastic patterns of the stretched fibres to understand how the localised difference between the principle stresses grows to form a necking region. Finally, the formation of

Pultrusion is considered to be a cost efficient method for developing composite structures. It facilitates the fabrication of uniform cross-section products with improved fiber alignment, mechanical properties, good surface characteristics, etc. In order to ascertain the crashworthiness, the pultruded composites shall be able to resist impact loads, and in this concern, the energy absorption capacity

In order to investigate the effect of the slot ends of the melt-blowing die on the three-dimensional airflow field distribution and the fiber draft, the numerical calculation was carried out. The computational domain of the slot die was established with Gambit, and the flow field was calculated using FLUENT. Compared with the experimental data collected by a hot-wire anemometer, the numerical calculation

Taking into account the fact that since the 1970s frontal polymerization (FP) reactors in flow have been the subject of our study, the work gives a brief chronology of the development of FP reactors for the synthesis of high molecular polymers, polymeric hydrogels with cross-linked structure, their advantages and drawbacks. The reasons for the impossibility of the practical implementation of tubular

The citrate-based thermoset elastomer is a promising candidate for bone scaffold material, but the harsh curing condition made it difficult to fabricate porous structure. Recently, poly (1, 8-octanediol-co-Pluronic F127 citrate) (POFC) porous scaffold was creatively fabricated by chitin nanofibrils (ChiNFs) supported emulsion-freeze-casting. Thanks to the supporting role of ChiNFs, the lamellar pore

The recent technology of geopolymer concrete is a substitute material for ordinary portland cement concrete which is produced from the polycondensation reaction of aluminosilicate materials with alkaline activator solutions. The cost of river sand is high since the demand for the same is also high. Manufactured sand is used as a replacement material for river sand in geopolymer concrete. This paper

Polymer dispersed liquid crystalline (PDLC) membrane with intrinsic thermal conductivity was prepared by dispersing liquid crystalline polysiloxane containing crosslinked structure (liquid crystalline polysiloxane elastomer (LCPE)) into polyvinyl alcohol (PVA). Chemical structures were characterized by Fourier transform infrared (FT-IR) and 1H-NMR, and microscopic structures were analyzed by polarizing

The bead foaming behavior of ether- and an ester-based Tensor Processing Unit (TPU) resins were investigated in a lab-scale reactor using supercritical CO2 as the blowing agent. The samples were saturated at various saturation temperatures and the effects of hard segment crystallization during the saturation on the foaming behavior of the TPU samples were explored. The results revealed that the different

In this research, three modified chitosan-based hydrogels are synthesized, i.e., a crosslinked chitosan hydrogel and semi- and fully-interpenetrating polymer network (IPN) chitosan hydrogels fabricated using poly(N-vinyl-pyrrolidone). A non-modified chitosan hydrogel was also synthesized as a control. These samples were compared regarding their swelling behavior and mechanical properties. The hydrogels

In this study, silicone rubber foam (SF) was prepared through cross-linking and foaming. The effects of ethanol content on the SF were investigated in terms of the physical properties, static cushioning properties, dynamic thermomechanical properties, and dynamic fatigue properties. The cell structure was characterized using scanning electron microscopy and its relationship with the SF properties was

Journal Name: Journal of Polymer Engineering Volume: 40 Issue: 7 Pages: i-iii

Mixed matrix membranes were prepared by blending polyethersulfone with zirconium oxychloride octahydrate (ZOH) solution, and coating by polyvinyl alcohol layer. Different analyses were applied in the prepared membranes. Membranes performances were examined using different salty solutions concentrations (5000, 10,000 and 20,000 mg/L) and a real sample from highly concentrated seawater (brine) of 1,30

Many herbal/botanical medicines from plant sources are being used for therapeutic purpose. Alternanthera sessilis sp. plant leaves are known for their phytochemical constituents, which have potent antibacterial activity. In the present study, the properties of the A. sessilis sp. extract and the biocomposite membrane of A. sessilis sp. with sodium alginate were studied for their biomedical applications

Blending different molecular weight polyacrylonitrile (PAN) was adopted to solve the shrinkage problem of high molecular weight PAN hollow fiber membrane, to enhance the application performance of low molecular weight PAN membrane, and to adjust the porosity, pore size distribution, and hydrophilicity of the end product. The structurally-optimized membrane was chosen as a substrate to support Fe/Mn

Journal Name: Journal of Polymer Engineering Volume: 40 Issue: 6 Pages: 449-449

Journal Name: Journal of Polymer Engineering Volume: 40 Issue: 6 Pages: i-iii

In this paper, the β-cyclodextrin (β-CD) and biotin (Bi) were successfully grafted onto carboxymethyl chitosan (CMCS). And then the β-CD-Bi-CMCS nanoparticles (NPs) were prepared as oral nano-delivery carrier of protein drugs by ionic gelation method. The morphological feature of fabricated drug carrier was determined by dynamic light scattering and transmission electron microscopy. The result showed

Induction welding is an important joining technique with potentially significant application in the connection of the Poly Ether Ether Ketone (PEEK). The present research employs the metal mesh as induction components into the induction welding of PEEK plate to PEEK plate at low power successfully. Besides, the examinations and analyses of macro/micro-structures, energy dispersive spectroscopy (EDS)

This work reports the fabrication and characterizations of porous scaffold made up of polylactic acid (PLA) with the inclusion of pectin (1, 3, 5, 7, 9, 11 wt%) for potential tissue engineering material. The composite scaffold was prepared using a facile method of freeze extraction. Based on the physical evaluations, the scaffold was suggested to be optimum at 5 wt% of pectin loading. Water contact

The interfacial interaction between the fiber and matrix is the most important factor which influences the performance of the carbon fiber-epoxy composites. In this study, the graphitic surface of the carbon fibers was modified with graphene oxide nanomaterials by using a spray coating technique which is an easy, cheap, and quick method. The carbon fiber-reinforced epoxy matrix composites were prepared

Poly (butylene succinate-co-butylene-3-hydroxyphenylphosphinyl-propionate) (PBSH) was synthesized through polycondensation. Then, 4,4′-methylene diphenyl diisocyanate (MDI) was introduced into PBSH matrix by reactive blending. The chemical structure and properties of the blending products were investigated using Fourier Transform Infrared Spectroscopy (FT-IR), differential scanning calorimetry (DSC)

The flax and equivalent proportion of poly(L-lactic acid)/poly(d-lactic acid) (PLLA/PDLA) were melt compounded and injection molded to prepare flax reinforced polylactide stereocomplex (sc-PLA) bio-composite, and two different coupling agents, hexamethylene diisocyanate (HMDI) and maleic anhydride grafted polypropylene (MAPP), were used to modify the interface of composite, then the influence of different

For hindered phenol (HP)/polymer-based hybrid damping materials, the damping properties are greatly affected by the structure variation of HPs. However, the unclear relationship between them limits the exploitation of such promising materials. Therefore, three HPs with different chain polarity were synthesized to explore the relationship in this paper. The structures of the HPs were firstly confirmed

Redox-active polymers among the energy storage materials (ESMs) are very attractive due to their exceptional advantages such as high stability and processability as well as their simple manufacturing. Their applications are found to useful in electric vehicle, ultraright computers, intelligent electric gadgets, mobile sensor systems, and portable intelligent clothing. They are found to be more efficient

Journal Name: Journal of Polymer Engineering Volume: 40 Issue: 5 Pages: i-iii

Journal Name: Journal of Polymer Engineering Volume: 40 Issue: 4 Pages: i-iii

The qualities of injection-molded parts are affected by process parameters. Warpage and volume shrinkage are two typical defects. Moreover, insufficient or excessively large clamping force also affects the quality of parts and the cost of the process. An experiment based on the orthogonal design was conducted to minimize the above defects. Moldflow software was used to simulate the injection process

The adhesive properties of a self-prepared bio-based epoxy resin with native cellulose nanocrystals (CNCs) are evaluated in this article. The porosity of actual CNCs is high. The most promising finding is the acquisition of high tensile modulus. The addition of CNC composites significantly increased the tensile modulus at lower wt.%, and the maximum crystallinity of CNCs was obtained. Bearing in mind

To obtain uniform and controllable material removal on hard and brittle materials, a novel processing technology with functionally graded lapping and polishing plate (FG-LPP) was proposed. Taking application of particles/rubber composites and adjustable contact stress of workpiece as key point, the abrasive particles and rubber were mixed with different mass ratios; then the FG-LPP was formed with

In this study we report on the preparation and characterization of biocomposites based on a sodium montmorillonite-ibuprofen (MtIb) hybrid and neat poly(ethylene glycol), neat sodium carboxymethylcellulose or poly(ethylene glycol)-carboxymethylcellulose blend 50/50 biocomposites as drug carriers. Ib, a poorly soluble drug, was first intercalated into sodium Mt and then the resulting hybrid was compounded

Cobalt ferrite functionalized chitosan graphene oxide (CoFe2O4@CS@GO) was inserted successfully in polyvinylpyrrolidone (PVP), and its distribution was distinguished through scanning electron microscope (SEM) analysis. Furthermore, the thermal and structural characterizations of the CoFe2O4@CS@GO-PVP nanocomposite were accomplished via the TGA, DSC, FT-IR, and XRD methods. The magnetic characterization

Polymer composites offer a great advantage in biomedical field over the traditional materials used like, metal, ceramics, or polymer alone. Polymer composites provide tailor-made facilities to design required physiological and mechanical properties in biomedical products. Poly(lactic acid) (PLA) is a popular aliphatic polyester used in various biomedical products because they have a renewable source

Exfoliated organo-montmorillonite (O-Mt) layers were successfully encapsulated in a terpolymer microsphere (PAAA) of acrylamide (AM)/acrylic acid (AA)/2-acrylamido-2-methylpropanesulfonic acid (AMPS) via in situ inverse suspension polymerization, with the aid of the organic modification by cetyltrimethylammonium bromide (CTAB) and sodium lauryl sulfonate (SLS). The chemical structure and properties

Haze (H) is not an accumulative property based on the addition of internal haze (Hi) and surface haze (Hs) parameters, though the relation (Hs = H − Hi) is widely accepted and used nowadays in research and development of plastic films. To evaluate the correct relation, the analytical relation between the total haze (H) and the haze of a single film (hi) in the film superposition model was firstly concluded

This study focuses on the influence of cryogenic temperature on the interface of carbon fiber reinforced plastics (CFRPs). Results of interfacial shear strength (IFSS) and mode II interlaminar fracture toughness (GIIC) at −196°C increased by 15.3% and 27.6% compared to the condition at room temperature (RT). By measuring the IFSS at −196°C, a new experimental method was designed based on microbond

Polymeric membranes have been widely considered as one of the next-generation technologies for CO2 capture from fossil fuel-derived flue gases. This separation modality requires novel polymeric materials that possess efficient CO2/N2 separation properties, as well as chemical and mechanical stability for a multiyear membrane lifetime. In this paper, recent developments in polymeric membranes tailored

In this research, we successfully fabricated a novel closed pore polyacrylonitrile (PAN)/polyvinyl pyrrolidone (PVP) composite nanofibrous membrane (PCNM) on the substrate of a commercial polypropylene window mesh. First, smooth and uniform PAN/PVP composite nanofibers (PCNs) were manufactured by blending PAN and PVP with a mass ratio of 5:5 during electrospinning. Subsequently, the prepared PCNs were

The production of biomethane from the biogas purification process depends on the capacity of the separation technique employed to separate methane from carbon dioxide. Mixed matrix membranes (MMMs) combine the benefits of polymeric and inorganic materials, and it is believed that the trade-off between gas permeability and selectivity in polymeric membranes can be hampered by MMMs. Until recently, the

A synthesized Schiff base 2-acetylthiophene semicarbazone (3) was used for the preparation of Ni2+ selective polyvinyl chloride (PVC) membrane electrode. The prepared electrode with the optimized composition, PVC:3:sodium tetraphenylborate:di-n-butylphthalate as 33:6:3:58 exhibited a Nernstian response over the working range of 5.0 × 10−6–5.0 × 10−2 mol l−1 with a slope of 29.0 ± 0.3 mV/concentration

One of the most significant issues, when thin parts have to be obtained by injection molding (i.e. in micro-injection molding), is the determination of the conditions of pressure, mold temperature, and injection temperature to adopt to completely fill the cavity. Obviously, modern computational methods allow the simulation of the injection molding process for any material and any cavity geometry. However