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  • Systems for accumulation, storage and release of hydrogen
    Russ. Chem. Rev. (IF 4.75) Pub Date : 2020-08-03
    Leonid M. Kustov, Alexander N. Kalenchuk and Viktor I. Bogdan

    ##IMG## [http://ej.iop.org/images/0036-021X/89/9/897/rc4940c.gif] The results of studies on the hydrogen accumulation, storage and release systems differing in the type of hydrogen interaction with the material (medium) used for hydrogen storage are analyzed. Published data on the use of polycyclic hydrocarbons as the basis for hydrogen storage in a chemically bound state are summarized. Substrate

    更新日期:2020-08-20
  • Mono- and binuclear complexes of group 5 metals with diimine ligands: synthesis, reactivity and prospects for application
    Russ. Chem. Rev. (IF 4.75) Pub Date : 2020-08-03
    Iakov S. Fomenko and Artem L. Gushchin

    ##IMG## [http://ej.iop.org/images/0036-021X/89/9/966/rc4949c.gif] Published data on the coordination compounds of group 5 metals with diimine type ligands are surveyed. Methods of synthesis, structural types, reactivity and properties of these compounds are summarized and systematized. Particular attention is paid to the redox, magnetic and catalytic properties and to biological activities of these

    更新日期:2020-08-20
  • Syntheses of polyfunctional aromatic compounds from non-aromatic precursors
    Russ. Chem. Rev. (IF 4.75) Pub Date : 2020-08-03
    Thomas Mies, Tsz-Kan Ma and Anthony G. M. Barrett

    ##IMG## [http://ej.iop.org/images/0036-021X/89/9/917/rc4931c.gif] Syntheses of polyfunctional benzene derivatives from both cyclic and acyclic non-aromatic precursors are reviewed. Such aromatizations include transformations that use Diels – Alder reactions, transition metal-catalyzed reactions, base mediated aldol or Michael addition reactions or electrocyclic and pericyclic reactions. This review

    更新日期:2020-08-20
  • 11 C- and 18 F-labelled tryptophans as PET-tracers for imaging of altered tryptophan metabolism in age-associated disorders
    Russ. Chem. Rev. (IF 4.75) Pub Date : 2020-08-03
    Boris D. Zlatopolskiy, Heike Endepols, Raisa N. Krasikova, Olga S. Fedorova, Johannes Ermert and Bernd Neumaier

    ##IMG## [http://ej.iop.org/images/0036-021X/89/9/879/rc4954c.gif] The ageing of the world’s population is the result of increased life expectancy observed in almost all countries throughout the world. Consequently, a rising tide of ageing-associated disorders, like cancer and neurodegenerative diseases, represents one of the main global challenges of the 21st century. The ability of mankind to overcome

    更新日期:2020-08-20
  • Molecular basis of COVID-19 pathogenesis
    Russ. Chem. Rev. (IF 4.75) Pub Date : 2020-07-05
    Fedor N. Novikov, Viktor S. Stroylov, Igor V. Svitanko and Vladimir E. Nebolsin

    ##IMG## [http://ej.iop.org/images/0036-021X/89/8/858/rc4961c.gif] The review summarizes the publications, available at the time it was written, addressing the chemical and biological processes that occur in the human body upon exposure to coronaviruses, in particular SARS-CoV-2. The mechanisms of viral particle entry into the cell, viral replication and impact on the immune system and on oxygen transport

    更新日期:2020-08-20
  • Natural and synthetic cytokinins and their applications in biotechnology, agrochemistry and medicine
    Russ. Chem. Rev. (IF 4.75) Pub Date : 2020-07-05
    Maxim S. Oshchepkov, Antonida V. Kalistratova, Ekaterina M. Savelieva, Georgy A. Romanov, Natalia A. Bystrova and Konstantin A. Kochetkov

    ##IMG## [http://ej.iop.org/images/0036-021X/89/8/787/rc4921c.gif] The review is devoted to cytokinins — classical plant hormones known for more than six decades. Nevertheless, different aspects of the action of cytokinins are still being investigated. Relevant studies produced interesting, often unexpected, results, which cast doubt on the old paradigms and open new prospects for the use of these phytohormones

    更新日期:2020-08-20
  • Stability of polymer jets in extension: physicochemical and rheological mechanisms
    Russ. Chem. Rev. (IF 4.75) Pub Date : 2020-07-05
    Alexander Ya. Malkin, Andrey V. Subbotin and Valery G. Kulichikhin

    ##IMG## [http://ej.iop.org/images/0036-021X/89/8/811/rc4941c.gif] The review is devoted to the fundamental problems of physical chemistry and rheology posed in the analysis of stability loss of polymer jets in extension. Studies of phenomena occurring in deformation of polymeric fluids are of considerable applied interest because extension of polymeric fluids underlies many industrial processes, first

    更新日期:2020-08-20
  • New advances in the catalysis of organic reactions by iron compounds
    Russ. Chem. Rev. (IF 4.75) Pub Date : 2020-07-05
    Ravil I. Khusnutdinov and Alfiya R. Bayguzina

    ##IMG## [http://ej.iop.org/images/0036-021X/89/8/824/rc4943c.gif] The review summarizes and systematizes the literature data on a new promising application area of iron compounds, that is, catalysis of organic reactions. The considered reactions include halogenation, formation of C−C bonds with the participation of various substrates, new methods for the synthesis of ethers and aromatic and heteroaromatic

    更新日期:2020-08-20
  • Sensory effects of fluorescent organic dyes
    Russ. Chem. Rev. (IF 4.75) Pub Date : 2020-06-10
    Valerii F. Traven and Dmitrii A. Cheptsov

    ##IMG## [http://ej.iop.org/images/0036-021X/89/7/713/rc4909c.gif] Organic dyes are very promising substrates for modern sensing technologies. Their utility is based on the ‘push-pull’ polarization of a π-electron system, as well as their polyfunctionality. These properties make organic dyes capable of fluorescent sensory response to many analytes and provide different mechanisms of both fluorescence

    更新日期:2020-06-10
  • From spin-labelled fused polyaromatic compounds to magnetically active graphene nanostructures
    Russ. Chem. Rev. (IF 4.75) Pub Date : 2020-06-10
    Yury A. Ten, Nadezhda M. Troshkova and Evgeny V. Tretyakov

    ##IMG## [http://ej.iop.org/images/0036-021X/89/7/693/rc4923c.gif] Molecular design of magnetically active graphene nanoscale structures is an emerging field of research. The key goal of this research is to produce graphene nanoribbons and graphene quantum dots with specified electronic, optical and magnetic properties. The review considers methods for the synthesis of spin-labelled polycyclic aromatic

    更新日期:2020-06-10
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