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Synthesis and anticancer evaluation of new disulfides incorporating naphthalimide moiety Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-03-08 Lu Xu, Shuangyan He, Chunlan Chi, Caiwen Li, Peipei Cui, Hongying Wang, Baoquan Chen
A series of new disulfides incorporating naphthalimide moiety were designed, synthesized and biologically evaluated against three human cancer cell lines (MCF-7, SMMC-7721 and Hela). Most of target...
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Synthesis and antibacterial properties of alkyl substituted sulfonium salt Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-03-04 Jing Li, Xiaodong Zhou, Yue Lin, Bingling Liu, Wenyang Chen, Chengcai Liu
The development of new antibacterial agents is particularly important in the battle against pathogenic microorganisms. In this study, sulfonium ions were used as the structural core to synthesize a...
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Synthesis and in vitro carbonic anhydrase and acetylcholinesterase inhibitory activities of novel hydrazide–hydrazone compounds containing 1,2,4-triazole ring Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-02-29 Efe Doğukan Dincel, Ebru Didem Kuran, Beyza Onarer, Yusuf Fıstıkçı, İlhami Gülçin, Nuray Ulusoy-Güzeldemirci
In this work, 1,2,4-triazole derived hydrazide–hydrazones were synthesized with a five-step synthesis pathway. The novel derivatives were characterized by various analytical methods. Acetylcholines...
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Towards the synthesis of new sequestring hexadentate bisphosphonic ligands for iron ion chelation Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-02-28 Mouna Ouechtati, Christelle Kouame, Julia Deschamp, Thibaut Legigan, Soufiane Touil, Evelyne Migianu-Griffoni, Maelle Monteil, Marc Lecouvey
This work presents the design and the synthesis of precursors of hexadentate bisphosphonic ligands able to complex iron cation. This study describes coupling reaction between natural siderophore en...
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Design, synthesis and antibacterial evaluation of N-Substituted indole derivatives containing 1,3,4-thiadiazole and amide moieties Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-02-23 Chenghao Tang, Chou Si, Yidan Zhang, Shengzhou Yang, Xingju Chen, Pei Li, Xiang Wang
A total of eighteen novel 2-(1H-indol-1-yl)-N-(5-phenyl-1,3,4-thiadiazol-2-yl) acetamide derivatives were synthesized through the condensation reaction of 2-(1H-indol-1-yl) acetic acid and 5-phenyl...
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Promising way for enhancing light absorption in silicon via silver nanoparticles: Experimental and numerical study Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-02-19 Meriem Zineb Belmehdi, Fatiha Bechiri, Mohamed Amine Benali, Mokhtar Zerdali
Silver nanoparticles (Ag-Nps) were grown on the surface of a p-type crystalline silicon (C-Si) substrate using electroless metal deposition. It was found that the Ag-Nps distribution on C-Si was co...
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Spectroscopic constants and anharmonic force field of thiirane: a theoretical study Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-02-19 Wei-Xiu Pang, Yun-Bin Sun, Jian-Jun Zhao, Mei-Shan Wang, Xiao-Min Song
The potential interstellar medium molecule, thiirane, has received considerable attention of experimental and theoretical studies in recent years. The anharmonic force field and spectroscopic const...
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Removal of Ca(II) and Mg(II) ions from solutions to sulfonic cation exchanger based on plasticized polyvinylchloride Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-02-16 Davron Bekchanov, Mukhtar Mukhamediev, Murod Juraev, Rasim Alosmanov
The ion-exchange material was obtained by oxidation of the product of the interaction of polyvinyl chloride with an aqueous solution of calcium polysulfide. The structure of the resulting cation ex...
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Core-shell magnetic nanocomposite Fe3O4@SiO2@CS@POCl2-x for alcohols to alkyl halides transformation Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-01-30 Farzaneh Ebrahimzadeh, Arezoo Jamalain, Somaie Zaree
In this study, we examined the efficiency of a new magnetic core-shell nanocomposite, Fe3O4@SiO2@CS@POCl2-x (NCP@ POCl2-x), which carries POCl2-x functional groups (where X can be 0, 1, or 2) on it...
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Three-component reaction between 2-hydroxymethyl-5-phenylamino-pyran-4-one and aromatic acyl chlorides with potassium selenocyanate: Synthesis of 2-aryl-6-hydroxymethyl-1-phenyl-4-selenoxo-1,4-dihydro-pyrano[3,2-d]pyrimidin-8-one Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-01-30 Zahra Ayagh, Mohammad H. Mosslemin, Mohammad R. Nateghi, Alireza Hassanabadi
We report an efficient method for the synthesis of 2-aryl-6-hydroxymethyl-1-phenyl-4-selenoxo-1,4-dihydro-pyrano[3,2-d]pyrimidin-8-one from the condensation of potassium selenocyanate and aromatic ...
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Obtaining nano calcium fluoride and ammonium sulfate from phosphogypsum Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-01-30 Yassine Ennaciri, Mohammed Bettach, Hanan El Alaoui-Belghiti
This study presents an efficient and sustainable procedure for converting phosphogypsum (PG) waste, along with hydrofluoric acid (HF) and ammonia (NH3), into valuable materials. The results obtaine...
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Visible light photoredox-catalyzed phosphorylation of α-bromostyrenes: a mild synthesis of β-ketophosphine oxides Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-01-30 Rabin Kim, Dae Young Kim
Visible light-mediated photocatalytic phosphorylation of α-bromostyrenes is described. The β-ketophosphine oxide derivatives were conveniently synthesized from α-bromostyrene derivatives, which are...
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Metal–organic frameworks HKUST-1 embedded in amino-functionalized SBA-15: Efficient catalytic reduction of 4-nitrophenol to 4-aminophenol Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-01-30 Cheng Qian, Yibo Zhang, Xifeng Chen, Wei Wang, Jianglei Hu, Sara Khan
The amino-functionalized SBA-15 silicon carrier (PMO-pr-NH2) was prepared by the one-pot method, and then HKUST-1 functional composites were synthesized by adsorption combined with in-situ preparat...
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Synthetic methodologies and applications of chalcogen (S, Se, Te) ionic liquids: a review Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-01-30 Ekta Arora
Ionic liquids (ILs) have emerged as an environmentally friendly alternative to the volatile organic solvents. Though primarily used as solvents, ILs synthesized with specific desired chemical prope...
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Obituary Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-01-12 Kaleigh Sunday
Published in Phosphorus, Sulfur, and Silicon and the Related Elements (Vol. 199, No. 1, 2024)
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One-pot synthesis of (2,4,6-Trimethylbenzoyl)diphenylphosphine oxide from triphenylphosphine oxide Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-01-12 Xianyang Xu, Jian-Qiu Zhang, Xin Wang, Teng Wang, Yan Liu, Li-Biao Han
A simple one-pot preparation of (2,4,6-Trimethylbenzoyl)diphenylphosphine oxide (TPO) by employing the low-cost triphenylphosphine oxide (Ph3PO) as the starting material was described. Reaction wit...
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Potassium salts catalyzed oxidative coupling of alkanethiols with sulfur: the effect of solid-liquid phase transfer of crown ether Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-01-12 Zhaoyang Xu, Zihan Zhang, Rui Wang, Fei Li, Heng Jiang
Potassium salts (KA, A = anion) that catalyzed the oxidative coupling of alkanethiols (RSH) to dialkyl disulfide (R2S2) were investigated by using sulfur as oxidant and 18-crown-6 ether as phase tr...
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Synthesis and Wittig olefination of (2-methyl-3-oxoisoindolin-1-yl)triphenylphosphonium tetrafluoroborate: facile access to 3-alkylidene-2-methylisoindolin-1-ones Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2024-01-12 Wenhua Huang, Yan-Hong Wang
(2-Methyl-3-oxoisoindolin-1-yl)triphenylphosphonium tetrafluoroborate has been successfully synthesized from Ph3PHBF4 and 3-hydroxy-2-methylisoindolin-1-one. It undergoes smoothly Wittig olefinatio...
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A novel [4 + 2] cycloaddition reaction involving Lawesson’s reagent. Structure and specific fragmentations of a new cyclic 1,2-thiaphosphinane-4-one Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-11-30 Witold Przychodzeń, Barbara Kusznierewicz
A crude morpholine enamine of acetone treated with Lawesson’s reagent unexpectedly yielded a six-membered thiaphosphinane-4-one. This compound is the first example of a new class of heterocycles. I...
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Formation, functionalization and interconversion of sulfur containing functional groups in mechanochemical conditions Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-11-24 Kamil Bugaj, Patrycja Pokora-Sobczak, Grażyna Mielniczak, Luca Sancineto, Claudio Santi, Józef Drabowicz
In the recent three decades, a steadily growing interest in the use of ball milling in organic synthesis has developed. The purpose of this mini-review is to briefly present protocols showing the u...
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Synthesis, synthetic interests, and biological activities of β-substituted vinylphosphonates Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-11-25 Cécile Garzon, Mireille Attolini, Michel Maffei
β-Substituted vinylphosphonates constitute an original class of organophosphorus reagents of which several compounds exhibit attractive biological properties. The review exemplifies and discusses t...
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The chemical behavior of the different impurities present in Phosphogypsum: a review Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-11-17 Yassine Ennaciri, Mohammed Bettach
Phosphogypsum (PG) is an acidic by-product that is created during the production of phosphoric acid using the sulfuric acid route. The management of PG poses a significant environmental challenge w...
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Rh(I)-catalyzed enantioselective (3 + 2) transannulations of 1,2,3-thiadiazoles with P-chiral monodentate phosphines Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-11-17 Hao Wei, Cunzhi Chen, Aijun Gao, Zhanhui Yang
As a proof of concept, P-chiral monodentate phosphines, which were inactive in promoting the transannulations of 1,2,3-thiadiazoles, were proven viable in the asymmetric catalytic (3 + 2) transannu...
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Composition and structural identification of silicon particles in diamond wire saw silicon powder Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-09-13 Tian Zhang, Kuixian Wei, Shicong Yang, Wenhui Ma
In this study, the content and calculation equations of each substance in diamond wire saw silicon powder (DWSSP) were determined. Initially, the presence of amorphous SiO2 was proven by crystal tr...
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Nickel catalysis synthesis of 2,5-disubstituted furans from aryl (alkyl) iodide Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-08-31 Zhongqiang Sun
A new methodology using various aryl(alkyl)iodides and CaC2 as coupling partners has been developed for the successful preparation of 2,5-disubstituted furans in good to excellent yields. The broad...
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Synthesis and properties of methanesulfonyl derivatives of diethyl esters of 5-(hydroxyalkylamino)-1,3-oxazol-4-yl-phosphonic acids Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-08-31 O. V. Golovchenko, M. Yu. Brusnakov, Yu. O. Shabelko, V. S. Brovarets, R. M. Vydzhak, O. S. Bahrieieva, L. M. Potikha, S. V. Shishkina
A number of {[4-(diethoxyphosphoryl)-2-R-1,3-oxazol-5-yl]amino}alkyl methanesulfonates were synthesized and the peculiarities of their reaction with triethylamine were studied. The influence of the...
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Sulfur-based organofluorine reagents for selective fluorination, fluoroalkylation, and fluoroolefination reactions Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-08-27 Xiu Wang, Jinbo Hu
A good partnership between “soft” sulfur and “hard” fluorine creates a rich chemistry for the introduction of structurally diverse fluorine or fluoroalkyl groups into organic molecules. The combina...
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Synthesis and bioactivity evaluation of novel acetamide-derived compounds bearing a methylsulfonyl unit Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-08-24 Pei Li, Zhenchao Wang, Lei Yu
This study reports the synthesis and structural characterization of a series of novel acetamide-derived compounds containing a methylsulfonyl unit. The in vitro antibacterial activity results demon...
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New greener approach for the Se-N bond formation Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-08-21 Agata J. Pacuła-Miszewska, Magdalena Obieziurska-Fabisiak, Anna Laskowska, Halina Kaczmarek, Jacek Ścianowski
A new greener protocol that includes the rapid and quantitative conversion of diaryl diselenides, bearing an amido function, to corresponding N-substituted benzisoselenazolones by 254 nm wavelength...
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Design, synthesis, and antiproliferative investigation of novel quinazolinones incorporating 1,3,4-oxadiazole and 1,2,4-triazole thioether moieties Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-08-15 Zijian Li, Yanle Men, Suhua Gao, Peipei Cui, Hongying Wang, Baoquan Chen
In the current study, a series of 1,3,4-oxadiazole and 1,2,4-triazole derivatives linked to quinazolinone were designed and synthesized by using Phase Transfer Catalysis. The structures of the synt...
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Design, synthesis, and biological activity of new 8-decylthio-10-methylthio-pyrimido[5,4-e][1,2,4]triazolo[1,5-c]pyrimidine derivatives Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-08-15 Huixiang Nie, Linghui He, Anlin Zhao, Haijin Huang, Tao Wang, Jin Luo
A series of new 8-decylthio-10-methylthio-pyrimido[5,4-e][1,2,4]triazolo[1,5-c]pyrimidine derivatives was prepared and characterized by FTIR, 1H NMR, 13C NMR, and HRMS. The bioassay results reveale...
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Bis(2-furanylmethyl)monospiro(N/N)cyclotriphosphazenes: synthesis, structural characterization, antiproliferative, and antimigratory activity studies Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-08-10 Hüseyin Akbaş, Ayşegül Şenocak, Zeynel Kılıç, Seçil Erden Tayhan, Sema Bilgin, Aslı Yıldırım Kocaman, Tuncer Hökelek
In this study, the condensation reaction of hexachlorocyclotriphosphazene, N3P3Cl6 (HCCP) with N1,N3-bis(furan-2-ylmethyl)-1,3-diamino-propane (1) yielded tetrachlorobis(2-furanyl-methyl)monospiro(...
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Synthesis and applications of new chiral terpenyl organoselenium compounds Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-08-07 Jacek Ścianowski, Agata J. Pacuła-Miszewska, Anna Laskowska, Magdalena Obieziurska-Fabisiak
Terpenes create a substantial group of natural compounds differentiated due to the structure of the carbon skeleton, the presence of various functional groups and the number of stereogenic centers....
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Synthesis of γ-keto sulfones via sulfa-Michael reactions in Brønsted acidic deep eutectic solvent Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-08-02 Ya-Juan Fan, Dan Wang, Liang Wang
A facile sulfonylation of activated alkenes employing sodium arylsulfinates in Brønsted acidic deep eutectic solvent at room temperature has been developed. The choline chloride/p-toluenesulfonic a...
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Phospha-Mannich reactions of phosphinous acids R2P–OH and their derivatives Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-07-20 Dmitry V. Moiseev
Abstract Secondary phosphine oxides R2P(O)H are a relatively stable tautomeric form of secondary phosphinous acids R2P–OH that with imine/iminium species, or their donors, form compounds with a P(O)–Csp3–N linkage (the phospha-Mannich reaction). These can be referred to as (α-aminoalkyl)phosphine oxides, (α-phosphinoylalkyl)amines, or P(O),N-acetals. Compared to P–Csp3–N linkages of P,N-acetals, products
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Crystal structure of selenium-substituted acetylacetonates of boron difluoride Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-07-12 I. V. Svistunova, A. V. Gerasimenko, M. A. Zavodianskii
Abstract The molecular and crystal structure of boron difluoride acetylacetonates containing selenophenyl (1), diselenide (2) and selenocyanate groups (3) at the central carbon atom (γ) has been determined. As a result of comparing the structure of selenium- and sulfur-substituted complexes, it is shown that the replacement of a sulfur atom with a selenium atom practically does not change the relative
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Investigation of cytotoxic properties of some isoindole-related compounds bearing silyl and azide groups with in vitro and in silico studies Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-07-12 Ayşe Tan, Aytekin Köse, Derya Mete, Gülşah Şanlı-Mohamed, Nurhan H. Kishalı, Yunus Kara
Abstract This study aims to evaluate the synthesis of isoindole-1,3-dione analogues and their cytotoxic potential. A549 and HeLa cells exposed to 250–100–50–25 µM doses of each derivative were incubated for 24, 48, and 72 h. The cytotoxicity of the isoindole-1,3-dione derivatives was analyzed using the cell growth inhibition assay and the cell membrane damage test. (3aR,5R,6R,7aS)-5-Azido-2-benzyl
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Synthesis, crystal structure, spectroscopic, and Hirshfeld surface study of a new functionalized α-hydroxyphosphonate complex of tin(IV) chloride Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-07-10 Sondes Zairi, Wafa Selmi, Haitham Elleuch, Mohamed Faouzi Zid, Farhat Rezgui
A new octahedral [SnCl4L·H2O] complex (L = γ-keto allyl phosphonate) (1) was prepared and characterized by multinuclear (1H, 13C, 31P, and 119Sn) NMR spectroscopy, IR spectroscopy, and single-cryst...
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Substituent influence of heteroatom on the novel remote N-heterocyclic silylenes (RNHSis) using density functional theory Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-07-06 Masoud Ghaghaei, Mirzaagha Babazadeh, Farnaz Behmagham, Ladan Edjlali, Esmail Vessally
In this work, we have compared and contrasted the stability, polarity, polarizability, frequency, band gap, charge distribution, and global reactivity of singlet (s) and triplet (t) states of the f...
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Phosphorus transformation in acid soil as influenced by humic substance Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-07-05 R. Sagar, G. N. Thippeshappa, G. G. Kadalli, B. C. Dhananjaya
The purpose of the study was to assess the influence of humic substance on the transformation of phosphorus in acid soil, so an experiment was conducted in a lab setting using the same soil (Typic ...
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An improved efficient synthesis of new N-heterocylic, homocyclic and aliphatic dronic acids Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-06-21 Shahab Marooti, Nader Noroozi Pesyan, Somayeh Behrouz
New N-heterocylic, homocyclic and aliphatic dronic acids were synthesized through an improved facile and versatile route by the reaction of various carboxylic acids with Phosphorus trichloride (PC)...
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Polymorphism in pentaerythritol-derived ferrocenyl dithiophosphonates with intramolecular S-S coupling: a structural and computational study Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-06-20 Gwaza Eric Ayom, Sizwe J. Zamisa, Thishana Singh, Werner E. van Zyl
Abstract Four new polymorphs (1–4) of pentaerythritol-derived ferrocenyl S-S coupled dithiophosphonates were obtained. The four polymorphs all crystallized in the monoclinic system but different space groups. Notable differences between polymorphs 3 and 4 lie in their respective unit cell parameters; a fifth polymorph 5 of the same compound crystallized in the orthorhombic system and was previously
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Synthesis, spectral and structural characterization of iron chalcogenomalonato complexes CpFe(CO)2ECOCH2CO2R (E = S, Se) Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-06-15 Mohammad El-khateeb, Phil Liebing, Wolfgang Weigand
The synthesis of CpFe(CO)2ECOCH2CO2R [E = S (1), Se (2); R = Me (a), Et (b)] was achieved by treating (µ-Ex)[CpFe(CO)2]2 (E = S, x = 2–4, Se, x = 1) with alkyl malonyl chlorides at ambient temperat...
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Silicon and growth regulator induced defence against maize fall armyworm, Spodoptera frugiperda (J.E. Smith) Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-06-15 Srinivasan Chinnadurai, Periyakaman Chandramani, Mookiah Shanthi, Peyandi Paraman Mahendran, Raman Renuka
A microplot field experiment was conducted to study the effect of silicon sources and growth regulator against maize fall armyworm, Spodoptera frugiperda at Thoppur village of Virudhunagar district...
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Advances in the study of P(O)-N bond construction Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-06-08 Zixuan Zhang, Qiaoli Yan, Runli Gao, Hongmei Wang
Abstract Phosphoramides represent an important class of organophosphorus compounds that have widespread applications in industry, agriculture, chemical synthesis as well as biomedicine. Researchers have conducted intensive and extensive studies on the properties and synthetic methods of phosphamides, including optimization and improvement of the preparative procedures and expansion of compound types
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Study of porous silicon layer effect in optoelectronics properties of crystalline silicon Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-06-04 Mouna Jemli, Bilel Abdouli, Lotfi Khezami, Mohamed Ben Rabha
Abstract In this research, we experimentally and numerically demonstrate the beneficial effect of superficial porous silicon layer in the optoelectronics properties of multi-crystalline silicon. The hydrogen and oxygen-rich porous silicon layer was formed using vapor etching method. From laser beam induced current (LBIC) simulations, we found that the hydrogen and oxygen-rich porous silicon layer used
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AlC3 monolayer as an efficient adsorbent for removal of edifenphos molecule: a density functional theory study Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-05-16 Mustafa M. Kadhim, Zainab Talib Abed, Halah Mohammed Azeez, Safa K. Hachim, Sallal A.H Abdullaha, Mohammed Abdul Hadi, Ahmed Mahdi Rheima
Abstract In the current research study, the adsorbent efficacy of an aluminum carbide (AlC3) nanosheet for edifenphos fungicide is assessed for the first time. To explore the efficacy of AlC3 as an adsorbent system, several essential properties of edifenphos, AlC3, and the complex of edifenphos-AlC3 are investigated. Edifenphos has an interaction through its -P = O group with the Al atoms of AlC3 with
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Room-temperature wet synthesis of bismuth(III) nitrate from bismuthinite: a thermodynamics-based communication Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-05-16 Aliyar Mousavi
Abstract Bismuth(III) nitrate (Bi(NO3)3) has pharmaceutical applications and is usually produced from elemental bismuth dissolution in nitric acid (HNO3). However, if bismuthinite (Bi2S3), which is one of the main minerals of bismuth, is used to produce elemental bismuth, sulfur dioxide (SO2), carbon monoxide (CO), and nitrogen oxides (NOx) are produced, which are three of the air pollutants considered
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Environmentally benign synthesis, molecular docking study, and ADME prediction of some novel aryl sulfones containing cyclic imide moiety as antimicrobial agents Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-05-12 Chafika Bougheloum, Sabrina Alioua, Saida Meliani, Robila Belghiche, Abdelghani Djahoudi, Abdelrani Messalhi
Abstract Some new aryl sulfones containing a cyclic imide moiety were synthesized using a cesium salt of Dawson-type tungstophosphoric acid (Cs5HP2W18O62) as an efficient catalyst under ultrasound irradiation. This efficient method affords the desired products in one step with high chemical yields. All structures of the products were proven by mass spectrometry and 1H and 13C NMR spectroscopy. The
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The significant effect of K+ counterion in the enhancement of physicochemical and structural properties of amorphous aluminosilicates xerogels used as catalysts in the transesterification of waste frying oils Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-05-11 Boufellah Nassima, Aksas Hammouche
Abstract With the aim of better directing the polycondensation of oligomers during the synthesis of amorphous aluminosilicate xerogels by the sol-gel process using Na2SiO3, we reinforced the sols with K+ counterion and studied its effect on the physicochemical and structural properties of the xerogels using XRD, FTIR, N2 physisorption, SEM, EDX, and TGA techniques as well as quantitative analysis of
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Grafting of phosphorus-containing tetrahydroxy(thia)calixarenes on silica enhances europium(III) adsorption Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-05-08 Yuriy Boiko, Konstantin Belikov, Ekaterina Bryleva, Zinaida Bunina, Victoria Varchenko, Alexander B. Rozhenko, Andriy Drapailo, Roman Rodik, Alexander Golub, Alexander Katz, Vitaly Kalchenko
Abstract One pot sequential reactions of silica gel with tetrachlorosilane/triethylamine mixture and after with the conical upper rim tetraphosphorylated tetrahydroxy(thia)calixarenes yielded porous organo-inorganic sorbents modified by spatially ordered phosphonate, phosphinate or phosphine oxide groups capable of co-operative binding of metal cations. The grafting improves efficacy of europium(III)
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Ultrasound-assisted construction of novel diethyl {(4-oxo-1,4-dihydroquinolin-3-yl) (aryl/heteroarylamino)methyl}phosphonates using CdI2 nanoparticles as an efficient catalyst: Synthesis, characterization, and antifungal properties Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-05-08 Mohamed Hussien, Tarik E. Ali, Ibrahim El-Tantawy El Sayed, Abdelaleem Hassan Abdelaleem, H. M. Torkey
Abstract The synthesis of some novel diethyl {(4-oxo-1,4-dihydroquinolin-3-yl)(aryl/heteroaryl-amino)methyl}phosphonates, was achieved. The methodology is based on one-pot three-component reaction of 4-oxo-1,4-dihydroquinoline-3-carboxaldehyde (1), amine, and diethyl phosphite in the presence of CdI2 nanoparticles as an efficient catalyst under conventional heating at 80 °C or ultrasound irradiation
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Foreword for International Symposium on the Organic Chemistry of Sulfur Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-05-02 Adrian L. Schwan
Published in Phosphorus, Sulfur, and Silicon and the Related Elements (Ahead of Print, 2023)
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The potential – pH diagram for germanium Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-04-25 Pavel Anatolyevich Nikolaychuk
Abstract Thermodynamic properties of germanium species in aqueous solution are collected. The chemical and electrochemical equilibria between various forms of Ge (IV) are considered. The basic chemical and electrochemical equilibria for germanium are calculated. The potential – pH diagram for Ge–H2O system is revised. The possible cationic chemistry of Ge (IV) is discussed from the thermodynamic viewpoint
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Novel thiourea derivatives against Mycobacterium tuberculosis: synthesis, characterization and molecular docking studies Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-04-25 Emine Kutlu, Fatih Mehmet Emen, Kübra Yıldırım, Cemilenur Ataş, Ruken Esra Demirdogen, Tuncay Yesilkaynak, Neslihan Kaya Kinaytürk, Ece Şimşek, Ahmet Yılmaz Çoban
Abstract N-((2-chloropyridin-3-yl)carbamothioyl)thiophene-2-carboxamide (HL1), N-((6-methylpyridin-2-yl)carbamothioyl)thiophene-2-carboxamide (HL2), N-(allylcarbamothioyl)thiophene-2-carboxamide (HL3), 2-chloro-N-(methyl(1-phenylethyl)carbamothioyl)benzamide (HL4) and 2-chloro-N-(bis((R)-1-phenylethyl)carbamothioyl)benzamide (HL5) were synthesized and characterized via FT-IR, 1H-NMR, 13C-NMR and HR-MS
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Novel 4H-pyrimido[2,1-b]benzothiazoles derivatives: Camphorsulphonic acid catalyzed enantioselective synthesis, optimization, and biological study Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-04-15 Manoj N. Bhoi, Mayuri A. Borad, Ankita P. Solanki, Hitesh D. Patel
Abstract An efficient, highly convergent route for the synthesis of novel fourteen single isomer derivatives of ethyl-2-methyl-4-(pyridin-2-yl)-4H-benzo[4,5]thiazolo[3,2-a]pyrimidine-3-carboxylate have been developed by one-pot, three-component reaction between pyridine 2-aldehyde, β-ketoester and various derivatives of 2-amino benzothiazole in the presence of D-(+)-10-camphorsulphonic acid (D-(+)-10-CSA)
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In silico molecular docking study and nano TiO2-SiO2 catalyzed microwave facilitated synthesis of new bis(α-aminophosphonates) as potential anti-diabetic agents Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-04-14 Mahankali Pavan Phani Kumar, Anuradha Vejendla, C. Gladis Raja Malar, Subramanyam Chennamsetty, Subrahmanyam Talari, Nagalakshmi Vedula
Abstract In the present work, we have developed a greener approach to synthesize a series of novel bis(α-aminophosphonates) (bis(α-Aps)) via a microwave-mediated nano TiO2-SiO2 catalyzed Kabachnik-Fields (K-F) reaction under solvent-free conditions. An in silico molecular docking analysis was performed on all the designed molecules prior to their synthesis to get insight into their capacity to block
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Microwave assisted, Cu-catalyzed synthesis of sulfonamides using sodium sulfinates and amines Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-04-14 Anil Nikam, Jagannath Jadhav, Sagar Sankpal
Abstract An efficient procedure has been developed under microwave irradiation for the monosulfonylation of amines in acetonitrile:water. In this reaction, equimolar quantities of amines and sodium sulfinates were reacted in presence of CuBr2 and omitted the use of oxidants, ligands, additives, and bases. The developed methodology converts a wide array of sterically and electronically diverse sulfinate
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Design, synthesis, antibacterial, and antifungal evaluation of novel 4-chromanone-derived compounds incorporating carboxamide and 1,3,4-thiadiazole thioether moieties Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-04-14 Jie Li, Lu Yu, Lingling Xiao, Mingwei Yang, Tianli Wu, Liqun Zhang, Shuming Tan, Pei Li
Abstract A series of novel botanical active component 4-chromanone derivatives incorporating carboxamide and 1,3,4-thiadiazole thioether moieties were synthesized and evaluated for their in vitro antibacterial and activities antifungal against Xanthomonas axonopodis pv. citri (Xac), Xanthomonas oryzae pv. oryzicolaby (Xoc) and Mucor bainieri (M. bainieri), Mucor fragilis (M. fragilis), Trichoderma
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N-Heterocyclic carbene: thiazolylidene–Cu(I) complexes: microwave-assisted synthesis and use as catalyst in A3 reaction Phosphorus Sulfur Silicon Relat. Elem. (IF 1.3) Pub Date : 2023-04-13 Nosheen Beig, Varsha Goyal, R. K. Bansal
Abstract A simple method involving microwave-assisted reaction of 3-benzylthiazolium/benzothiazolium bromides with cuprous oxide has been developed for the synthesis of four new N-heterocyclic carbene (NHC): thiazolylidene/benzothiazolylidene–Cu(I) complexes. Structures of the complexes could be established on the basis of the IR, 1H, and 13C NMR studies and elemental analysis. A representative NH