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A review on binary alkaline‐earth trielides: an overview of compositions and structures, of their stabilities and energetics and of criteria for the validity of the Zintl‐concept. Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-03-12 Horst Philipp Beck
Omitting alloys with a compositional range we present a compilation of binary alkaline earth trielides AExTRy together with results of DFT calculations to estimate total energies and energies of formation in comparison and to analyse the distribution of charges at the atomic positions in a Bader analysis of the electron density. In a comparison of many structures, we furthermore analyse the effect
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On the equilibrium of mono‐ and dinuclear Cu(II) dimethylglyoxime complexes and its exploitation for the simple preparation of Cu(I) salts [Cu(CH3CN)4]X (X = ClO4‐, BF4‐, OTf‐) Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-03-12 Raphael Immanuel Petrikat, Thomas Frick, Sabine Becker
The reaction of Cu(OAc)2 with dimethylglyoxime (H2dmg) yields the mononuclear complex [Cu(Hdmg)2] (1), whereas the reaction of Cu(ClO4)2∙6H2O with H2dmg yields a dinuclear complex [Cu2(H2dmg)(Hdmg)(dmg)]ClO4 (2a). Systematic studies of the stoichiometric ratios of the reactants, the nature of the anion as well as pH value show that the pH value of the reaction solution/anion governs the nuclearity
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Gold(I) {2}-Metallacoronates derived from a Catechol-scaffolding Aroylbis(N,N-diethylthiourea): Syntheses and Structures Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-02-23 Chien Thang Pham, Thuy Thuy Pham, Ulrich Abram, Hung Huy Nguyen
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Front Cover: Dinucleating N-donor Ligands with 1,2-Diethynylbenzene Backbone for the Copper-Mediated Monooxygenation of Phenols (Z. Anorg. Allg. Chem. 4/2024) Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-02-15 Alexander Koch, Benjamin Herzigkeit, Küpra Yildiz, Christian Näther, Tobias A. Engesser, Felix Tuczek
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Crystal Structure and Optical Characteristics of K2Nd2O(BO3)2 Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-02-17 Jingcheng Feng, Jun Shen, Guochun Zhang
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A Tb(III) Complex Based on 3-Pyridylacetic Showing Luminescent Detection for Fe3+ Ion Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-02-16 Fang Liu, Ying-Bing Lu, Yu-Lin Zhou, Yu Lei, Bei-Bei Wang, Wei Yang, Wen-Tong Chen, Shui-Dong Zhu
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Reactions of Dichloroacetyl Fluoride in Superacidic Media Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-02-15 Sebastian Steiner, Alexander Nitzer, Christoph Jessen, Andreas J. Kornath
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Amino Imidazolin-2-imine Ligands in Magnesium Complexes: Approaches Towards Low-Valent Mg(I) Species Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-02-12 M.Sc.Lars Denker, Hadi Dolati, M.Sc.Mario Barthen, René Frank
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Reactivity of [ReOCl3(PPh3)2] towards substituted anilines Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-02-06 Olivera Cvetković, Johannes Theiner, Mariusz J. Wolff, Kai C. Hultzsch
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Well-defined Bis(imino)pyridine-Manganese(II) Complexes for Oxidation of Benzylic C−H Bonds Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-02-05 Jyotirmoy Dey, Ritu Raj Lakshkar, Deepika Sahil, Om Prakash Joshi, Seema Yadav, Ajeet Singh, Sriparna Ray, Chandrakanta Dash
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Preparation of Copper-containing Nanocomposites by Thermolysis of Copper (II) Complex and Their Use as Anti-friction and Anti-wear Additives to Lubricant Oils Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-01-31 Ekaterina G. Drogan, Marina A. Tautieva, Victoria E. Burlakova, Leonid D. Popov, Igor A. Estrin, Igor E. Uflyand
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A Versatile Comproportionation Route to Construct Mono-Imido Trichlorido Complexes of Molybdenum(V) and Tungsten(V) Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-01-30 Daniel Leitner, Klaus Wurst, Stephan Hohloch
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Synthesis of (Arylimido)niobium(V) Bis(diethylamide) Complexes Containing Phenoxide Ligands Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-01-26 Nonoka Nakashima, Sirichok Paosopa, Kotohiro Nomura
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Isolation of an Osmium(III) Hydrido Complex Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-01-23 Niyaz Alizadeh, Josh Abbenseth, Sarah Bete, Markus Finger, Matthias Otte, Christian Würtele, Sven Schneider
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Highly sensitive detection of ions and dopamine molecules by a hydrogen-bonded organic framework Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-01-23 Zuen Wang, Penglei Shen, Ni Zeng, Faqiang Chen, Hui Xu, Shiqing Xu
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Quantitative Scrolling into Microporous Nanotubes of the Hydrous Layered Silicate Ilerite Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-01-22 Felix Uhlig, Ingmar Pietsch, Alexander Stich, Ulrich Mansfeld, Sabine Rosenfeldt, Jürgen Senker, Josef Breu
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Influence of the Homoatomic and Multicenter Bonding on the Formation of CsCl-type RhCd Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-01-18 Nilanjan Roy, Sucharita Giri
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Front Cover: (Z. Anorg. Allg. Chem. 1/2024) Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-01-02 Simon Steinberg
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One-dimensional Polymers derived from a Sterically Demanding 1,3-Diphosphete Complex Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2024-01-05 Maria Parzefall, Eugenia Peresypkina, Eva-Maria Rummel, Mehdi Elsayed Moussa, Manfred Scheer
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Synthesis, Crystal structure, electronic structure, and Raman spectra of Li4Sr2SiP4 Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-12-29 Vincent Daiber, Sabine Zeitz, Viktor Hlukhyy, Dominik Dankert, Thomas F. Fässler
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Mass spectrometric analysis of transition metal complexes formed through contact of artificial sweat with circulating Euro coins Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-12-28 Azar Rezaei, Sven Heiles, Bernhard Spengler, Siegfried Schindler
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Modelling the Binding of Cytotoxic Dinuclear Copper Complexes to two Neighboring Phosphate Esters of DNA Using Glutarate: A Tetranuclear Metallo-Macrocycle vs a Dinuclear Model Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-12-27 Thomas Riediger, Züleyha Aydin, Anja Stammler, Jan Oldengott, Thorsten Glaser
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Dinucleating N-donor Ligands with 1,2-Diethynylbenzene Backbone for the Copper-Mediated Monooxygenation of Phenols Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-12-25 Alexander Koch, Benjamin Herzigkeit, Küpra Yildiz, Christian Näther, Tobias A. Engesser, Felix Tuczek
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Synthesis of the (Sn4Bi4)2− Anion by Mild Oxidation of (Sn2Bi2)2− Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-12-16 Yannick R. Lohse, Bastian Weinert, Benjamin Peerless, Stefanie Dehnen
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Front Cover: Syntheses, Structures, Structural Transformation, and Properties of Neodymium Sulfate Based Inorganic Networks (Z. Anorg. Allg. Chem. 24/2023) Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-12-14 Suwadee Jiajaroen, Songwuit Chanthee, Winya Dungkaew, Filip Kielar, Mongkol Sukwattanasinitt, Shinya Hayami, Kittipong Chainok
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Syntheses and Characterization of Ti(III)/Ti(IV) Triazenido Complexes Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-12-14 Kevin Schwitalla, Wing Lee, Iris Töben, Marcel Eilers, Marc Schmidtmann, Rüdiger Beckhaus
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Editorial Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-12-12
With volume no. 650, our journal ZAAC enters its 132nd year since the first issue appeared in 1892. Nowadays, the journal is available to readers from around 7,100 institutions worldwide. Thanks to Wiley's open access agreements with more than 2,700 institutions, authors affiliated with these institutions can publish their work open access without having to pay themselves. There is no development without
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Synthesis, structures and optical properties of mononuclear La, Eu and Tb complexes supported by calix[4]arene ligands bearing three pendant salicylaldiminato arms Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-12-11 Lennart Günzel, Martin Börner, Berthold Kersting
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Effective encapsulation of noble and small gases and molecules by tubularene molecule Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-12-06 Christopher Weinert, Dušan Ćoćić, Ralph Puchta, Rudi van Eldik
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Influence of the ancillary ligand on the crystalline structures and magnetic properties of mesaconato-bridged Mn coordination polymers Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-12-05 Rogelio Martínez-Domínguez, Iván García-Orozco, Diego Martínez-Otero, Raúl A. Morales-Luckie, Víctor Sánchez-Mendieta, Roberto Escudero
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bis-Silyl-triazenide ligands in alkaline-earth metal chemistry Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-12-05 Christian Knüpfer, Jens Langer, Sjoerd Harder
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Alkaline Metal Intercalates of VSe2 by Electrochemical Intercalation Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-11-29 Bastian Kannen, Bertold Rasche
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High-yield access to long-sought 1,8-bis[pinacolato(boryl)]naphthalene Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-11-29 Alexander Stefan Scholz, Alexander Virovets, Hans-Wolfram Lerner, Matthias Wagner
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Cytotoxic Activity of Some Half-sandwich Rhodium(III) Complexes Containing 4,4’-disubstituted-2,2’-bipyridine Ligands Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-11-27 Marion Graf, Jasmine Ochs, Peter Mayer, Nils Metzler-Nolte, Hans-Christian Böttcher
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Blue Emitting SrBe1−xSi2+xO3−2xN2+2x:Eu2+ (x≈0.1) Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-11-23 Tobias Giftthaler, Marwin Dialer, Philipp Strobel, Peter J. Schmidt, Wolfgang Schnick
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Synthesis, structure, photoluminescence and magnetism of a series of cobalt-lanthanide heterometallic complexes originated from 2,3-dichlorobenzoate and 1,10-phenanthroline Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-11-20 Yue Shen, Tian-Biao Qu, Fei-Yue Chen, Xin-Yue Zhang, Bin-Qiu Liu, Ju-Wen Zhang
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High-pressure/high-temperature synthesis of Nd3B5O11(OH)2 Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-11-17 Tobias A. Teichtmeister, Alexander Hugo Bernhart, Stefan Schwarzmüller, Klaus Wurst, Hubert Huppertz
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Construction of A sqc6 Topology Ni-Gd Framework Employing 2,2’-Phosphinico-dibenzoate and Oxalate: Structure and Magnetic Properties Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-11-14 Ning Tan, Wen-Gen Chen, Pengcheng Wu, Zhao-Xi Wang
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Synthesis and crystal structure of the new zinc borate Zn6.1B6O19H7.8 Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-11-13 Raimund Ziegler, Hubert Huppertz
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Front Cover: Synthesis and characterization of ternary trielides Na7KTr4 [Tr=In or Tl] including [Tr4]8− Tetrahedra (Z. Anorg. Allg. Chem. 21/2023) Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-11-04 Melissa Janesch, Vanessa F. Schwinghammer, Ilya G. Shenderovich, Stefanie Gärtner
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Cover Feature: Unravelling the mechanisms behind oxidative transformations of vivianite and parasymplesite into previously not recognized materials with unexpected oxidation states of iron – a systematic review (Z. Anorg. Allg. Chem. 21/2023) Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-11-04 Gerald Henkel
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Polycyclic aromatic hydrocarbon radical anions stabilized by a sodium diglyme cation complex Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-11-07 Natalie Eichstaedt, Ingmar Pietsch, Daniel Friedrich, Josef Breu
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Synthesis, crystal structure, and spectroscopic characterization of aminoguanidinium thiosulfate, (CN4H7)2S2O3 Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-11-07 Dmitri O. Charkin, Alexander M. Banaru, Semen A. Ivanov, Vadim E. Kireev, Dmitri N. Dmitriev, Sergey M. Aksenov
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Configuration of the dimolybdate in salt inclusion type of compounds, Cs2Mo2O7 ⋅ CsX (X=Cl, Br, and I) Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-10-26 Anna Katharina Weber, Ksenia Denisova, Peter Lemmens, Angela Möller
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Syntheses, Structures, Structural Transformation, and Properties of Neodymium Sulfate Based Inorganic Networks Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-10-25 Suwadee Jiajaroen, Songwuit Chanthee, Winya Dungkaew, Filip Kielar, Mongkol Sukwattanasinitt, Shinya Hayami, Kittipong Chainok
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Front Cover: Chromium Metal Nanoparticles, Their Reactivity and Reactions (Z. Anorg. Allg. Chem. 20/2023) Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-10-20 Andreas Reiß, Maximilian Kai Reimann, Radian Popescu, Dagmar Gerthsen, Rainer Pöttgen, Claus Feldmann
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Corrigendum: Synthesis, Characterization, and in vitro Cytotoxicity of Gold(I) Complexes of 2-(Diphenylphosphanyl) ethylamine and Dithiocarbamates Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-10-17
Conflict of interest The authors declare no conflict of interest.
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In Celebration of Michael Ruck on his 60 th Birthday Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-10-16
On November 23rd, Michael Ruck, Professor and Chair of Inorganic Chemistry at Dresden University of Technology (TU Dresden) celebrates his 60th birthday. Colleagues, alumni and friends cordially congratulate him on this occasion and dedicate this special issue of Zeitschrift für Anorganische und Allgemeine Chemie (ZAAC) to him. Michael studied chemistry at the University (TH) of Karlsruhe from 1984
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Synthesis of Organosilicon-Based Thioether Ligand Class Showing Defined S-Stereogenic Coordination in Crystalline Palladium(II) Complexes Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-10-12 Paul Erik Schneider, Jonathan Wattenberg, Jan Frederick Wappelhorst, Michael Knorr, Carsten Strohmann
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Crystal Structure of and Chemical Bonding in MoNi4 Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-10-11 Marc Armbrüster, Leonard Rößner, Yurii Prots, Lev Akselrud, Markus König, Denis Sheptyakov, Yuri Grin
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NMR spectroscopic investigations on the successive implementation of nickel and zinc ions to a NacNac-dibenzofuran-Br ligand precursor Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-10-06 Konstantin B. Krause, Beatrice Cula, André Dallmann, Christian Limberg
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Front Cover: K2BaSi4: Zintl Concept in Position Space (Z. Anorg. Allg. Chem. 19/2023) Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-10-02 Olga Sichevych, Lev Akselrud, Bodo Böhme, Matej Bobnar, Michael Baitinger, Frank R. Wagner, Yuri Grin
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Cover Feature: Microstructural evolution of layered K-doped RuCl3 during annealing traced by thermogravimetric analysis and 3D electron diffraction (Z. Anorg. Allg. Chem. 19/2023) Z. Anorg. Allg. Chem. (IF 1.4) Pub Date : 2023-10-02 Ekaterina Vinokurova, Monika Knorr, Anastasia Efimova, Alexander Ovchinnikov, Peer Schmidt, Bernd Büchner, Anna Isaeva, Maria Roslova