ABSTRACT The objective of this work is to propose a more effective way to prepare an in-house CO2 with known triple oxygen isotope compositions. The major experimental steps include: (1) the O2 is combusted to CO2 on a graphite rod at 750 °C with Pt-catalyst for 3–4 min; and (2) converted CO2 is subsequently purified by two cryogenic traps. The results show high reproducibility of δ13C and δ18O values

ABSTRACT The application of organic fertilizers (OF) can supply carbon (C) to the soil in crop fields. OF-derived C (OF-C) is often estimated using the differential method that can be biased due to indirect effects of OF on soil C. This study tested three methods to quantify OF–C: (i) the widespread differential method, (ii) the synchronic isotope method comparing plots with and without OF and (iii)

ABSTRACT The Upper Cibolo Creek (UCC) karst watershed in Central Texas, USA, represents a portion of the drainage area that supplies water to the recharge zone for the Edwards Aquifer. However, the surface water–groundwater interactions along the UCC are not well quantified, and the hydraulic interactions are important for water budget and water quality of the aquifer. In this study, we investigated

ABSTRACT Shallow groundwater and lake water are the dominant water resources in the Badain Jaran Desert. There are still controversial hypotheses related to the origin of groundwater in this desert. Few studies have been conducted to explore the Sr provenance of these waters and assess the water–rock interactions using a Sr isotope approach until now. In this text, the Sr isotope data of waters in

ABSTRACT Lake Sevan is a meso-eutrophic water body, which was severely impacted by anthropogenic level decrease, pollution and eutrophication during the last century. Starting in the 1970s, these processes resulted in the formation of an oxygen-depleted hypolimnion during summer–autumn stratification of the lake. In this work, we demonstrate for the first time that eutrophication of the lake leads

ABSTRACT In the present study, the radioactivity levels of water samples collected from the main water supply network in Trabzon province and districts and soil samples taken from the vicinity of the water network were measured. An Alphaguard-PQ2000 radon gas detector was used to determine the seasonal radon gas level in the water samples. An HPGe detector was used to determine the level of radioactivity

ABSTRACT During the past two decades, interest has developed in regard to the possibility that plant roots can take up organic N compounds directly, a concept which challenges the conventional wisdom that soil inorganic N forms ( NH4+ and NO3−) are the sole primary sources of N absorbed by plant roots. We reviewed the literature based on single or dual (15N, 13C) stable isotope labelling techniques

ABSTRACT Nitrate pollution has become an environmental problem of global concern. One effective way for controlling the nitrate pollution of water is to identify the pollution source and reduce the input of nitrate. This study traces and quantifies the sources of nitrate contamination to groundwater and surface water in the northeastern suburbs of Beijing, where an emergency groundwater source zone

ABSTRACT Water vapor, the most important greenhouse gas in the atmosphere, has four natural stable isotopologues (H216O, H217O, H218O and HD16O), and their isotopic compositions can be used as hydrological tracers. But the underlying processes and pattern-dynamics of the isotopic compositions of atmospheric water vapor and precipitation in response to various meteorological conditions during monsoon

ABSTRACT Iran is a semi-arid and arid country which always faces a water shortage crisis. Thus, the water resources in Iran should be studied by accurate methods such as stable isotope techniques. In precipitation sampling stations across Iran, the δ18O (ranges from −16.3 to −0.3 ‰, −4.9 ‰ average), δ2H (−114 to –13 ‰, −24.2 ‰ average) and d-excess (−2.1 to –22.7, 16.5 ‰ average) values are higher

ABSTRACT Isotopic tracing technique is one of the most effective methods to identify nitrogen source and fate in aquatic environments. Although dissolved organic nitrogen (DON) is a key component in nitrogen cycles, information on nitrogen stable isotope ratios in DON (δ15N-DON) is limitedly available for its low recovery through a direct measurement. Indirect measurement is based on mass balance calculations

ABSTRACT Crabs of the family Camptandriidae are the most dominant burrowing crabs inhabiting arid mangrove forests of the Persian Gulf. They play important roles in the structuring and functioning of mangrove ecosystems by modulating biogeochemical processes and cycling of nutrients, serving as important ecosystem engineers. We analysed stable carbon (13C) and nitrogen (15N) isotope values of three

ABSTRACT Understanding of nitrogen stable isotope variation in maize hybrids might help obtaining information on nitrogen absorption and distribution in different maize hybrids. In this study, we examined the nitrogen isotopic composition of different parts of maize hybrids under a laboratory culture experiment. The results showed that the δ15N values of different parts of the maize hybrid and its

ABSTRACT As demand for regional and organically produced foodstuff has increased in Europe, the need has arisen to verify the products’ origin and production method. For food authenticity tracking (production method and origin), we examined 286 samples of wheat (Triticum aestivum), potatoes (Solanum tuberosum), and apples (Malus domestica) from different regions in Germany for their stable isotope

ABSTRACT Emissions from traffic over the past few decades have become a significant source of air pollution. Among the pollutants emitted are nitrogen oxides (NOx), exposure to which can be detrimental to public health. Recent studies have shown that nitrogen (N) stable isotope ratios in tree-rings and foliage express a fingerprint of their major N source, making them appropriate for bio-monitoring

ABSTRACT Cosmogenic 7Be was used to evaluate soil loss in a mountainous micro-watershed near Belo Horizonte, Southwest Brazil. Two nearby sites were selected, a reference site in a flat area and an eroded site in a hill slope. At the reference site, soil samples were collected monthly throughout the year in order to evaluate seasonal variations of 7Be inventory in soil and its relation with the precipitation

ABSTRACT Atmospherically deposited hoarfrost is probably the least important quantitative component of the hydrosphere, yet in places acts as an important source of water. Although countless studies have investigated the stable isotope composition of virtually all other components of the global hydrosphere, little is known on its stable isotope composition. We addressed this gap in knowledge by investigating

ABSTRACT Mountains arid environments are vulnerable under climate change scenarios. Variations in the recharge sources and the rising temperature can affect the water availability, threaten the socio-productive systems on local and regional scales. In this sense, two hydrological systems were studied in the Andes Range, Argentina, by hydrochemical and isotope techniques, with the purpose to understand

ABSTRACT Water stable isotopes have been widely used as natural tracers to investigate soil–plant–atmosphere interactions. Recent developments in induction module cavity ring-down spectroscopy (IM-CRDS) have made it possible to rapidly complete isotope analyses, and to combust co-extracted organic compounds at the same time. However, the agreement between IM-CRDS and isotope ratio mass spectrometry

(2021). Dedicated to Professor Peter Krumbiegel on the occasion of his 85th birthday. Isotopes in Environmental and Health Studies: Vol. 57, No. 1, pp. 1-2.

ABSTRACT The Continental Intercalaire (CI) groundwaters of the Tidikelt (In-Salah region) are characterized by a high salinity and ion concentrations higher than the maximum standards for drinkability. The total dissolved solids range from 850 to 3390 mg L–1 for conductivities ranging from 1470 to 6780 μS cm–1. Their chemical facies is dominated by Cl–, SO4 2– and Na+, respectively. Alkali ions, Cl–

ABSTRACT The Continental Intercalaire (CI) groundwaters of the Tidikelt (In-Salah region) are characterized by a high salinity and ion concentrations higher than the maximum standards for drinkability. The total dissolved solids range from 850 to 3390 mg L–1 for conductivities ranging from 1470 to 6780 μS cm–1. Their chemical facies is dominated by Cl–, SO42– and Na+, respectively. Alkali ions, Cl–

ABSTRACT The Corumbataí River basin (São Paulo, Brazil) has a critical situation regarding water availability due to the intensive use to support agriculture and urbanization, requiring scientific information to face water demand. The aim of this study is to present a hydrological characterization based on the analysis of seasonal isotope variations (rainfall, groundwater, and surface water) and hydrometric

ABSTRACT The procedure of calibrating in-house water standards suitable for routine analyses of triple-isotope composition of water samples using Picarro L2140-i CRDS analyser is presented and discussed. Such standards are indispensable for achieving and maintaining high quality of isotope analyses of water in terms of their precision and accuracy. A set of seven different water standards consisting

(2021). Dedicated to Professor Peter Krumbiegel on the occasion of his 85th birthday. Isotopes in Environmental and Health Studies. Ahead of Print.

Our study aimed to assess the nutritional status by using body composition among young Tunisian adults through three measurement methods: body mass index (BMI), bioelectrical impedance analysis (BIA) and deuterium oxide dilution technique (2H2O) and to determine the accuracy of BMI and BIA in order to evaluate the overweight and obesity among young adults in Tunisia. Our study involved 144 young adults

Radiocarbon (14C) is useful for estimating groundwater ages for transport and water resource exploitation assessment. If the 14C content of dissolved inorganic carbon (14CDIC) is known, the age of groundwater can be estimated by applying a radiocarbon decay equation combined with an appropriate geochemical correction model. However, age determinations are subject to uncertainties caused by parameters

ABSTRACT Radiocarbon activity (a14C) and 13C composition (δ 13C) were measured in hygrophyte and mesophyte (land) mosses collected in the natural habitat of the Plitvice Lakes and along the Zrmanja and Krupa Rivers (typical continental and Mediterranean climates, respectively), Croatia. a14C and δ 13C values of mosses, of atmospheric CO2 and dissolved inorganic carbon (DIC) were compared with contemporary

Radiocarbon activity (a14C) and 13C composition (δ 13C) were measured in hygrophyte and mesophyte (land) mosses collected in the natural habitat of the Plitvice Lakes and along the Zrmanja and Krupa Rivers (typical continental and Mediterranean climates, respectively), Croatia. a14C and δ 13C values of mosses, of atmospheric CO2 and dissolved inorganic carbon (DIC) were compared with contemporary data

(2020). Environmental isotope applications in Latin America and the Caribbean region. Isotopes in Environmental and Health Studies: Vol. 56, Environmental isotope applications in Latin America and the Carribean region, pp. 387-390.

A comprehensive study was conducted to understand the radon (222Rn) distribution and associated radiation doses to the public in a small tropical river basin partly set in the western slope of the Southern Western Ghats of Kerala, India. Radon, though detected in all the 71 monitored wells (0.17-68.3 Bq L-1), exceeded the maximum contamination level (MCL) of 11.1 Bq L-1 for drinking water recommended

In the present study we investigated the isotope effects associated with water loss from closed low-density polyethylene (LDPE) bottles via diffusion at temperatures between 4 and 60 °C. While at low temperatures (4 and 10 °C) no substantial diffusional loss of water was observed within storage time, a pronounced loss was found for the experiments at room temperature and 60 °C. The latter was associated

This study monitored the isotopic compositions of precipitation in Guilin as well as the influence of El Niño-Southern Oscillation (ENSO) on the isotope ratios and water vapour sources from 2015 to 2016. The results indicate that the lower isotope values of precipitation from ocean water vapour source are affected by long transport distance and fractionation during summer and autumn. In contrast, the

Coupling isotope values of feathers and satellite tracking of individuals have the potential to reveal multi-season linkages between wintering habitat, diet and carry-over effects on reproductive parameters in migrating birds. Snowy owls Bubo scandiacus have multiple wintering tactics as they can use both terrestrial and marine resources during the non-breeding season, but their nomadic behaviour complicates

Since 1973, Kunene River water has been carried from the Calueque reservoir in Angola along a 160 km open concrete canal to the town of Oshakati in the central part of the Cuvelai-Etosha Basin and has been supplying drinking water to the most densely populated rural area of Namibia. Despite its importance for the region, intra-seasonal water quality and the technical condition of the canal are not

The water sources of the Sokoto Basin are mainly of interrelated origin. The groundwater is composed of old water recharged in different climate regimes and of recent meteoric water. The recharge source is influenced by both local and regional moisture circulation given the lower slope and intercept of the local meteoric water line (LMWL) relative to those of the global meteoric water line (GMWL) and

ABSTRACT Fluxes between fractured-karstified and detritic aquifers are commonly poorly understood in many environments. These two types of aquifers are in contact in the southeastern Pampean region in the Argentine Buenos Aires province, and the aim of this work is to analyze their relationship contributing to improve the hydrological model. A joint application of hydrochemical and multi-isotope (δ

ABSTRACT Carbon and nitrogen stable isotope compositions (δ13C and δ15N) of organic matter (OM) and total organic carbon to total nitrogen ratio (Corg/TN) in a sediment core collected in Sagua estuary (Cuba), were investigated to elucidate the origin of the Sedimentary OM (SOM) and changes in its main sources, over the last 100 years. Results showed almost constant values in the elemental and isotope

15N natural isotope abundance (NIA) is systematically higher in infants' hair than in that of their mothers at birth. This study aimed to investigate this difference in plasma pools. We compared 15N NIA values for plasma amino acid (AA) pools (free + protein-bound) in the umbilical cord artery (UCA) and vein (UCV) and in the maternal vein (MV) at birth. This preliminary study included 7 mother-infant

Micropollutants are frequently detected in groundwater. Thus, the question arises whether they are eliminated by natural attenuation so that pesticide degradation would be observed with increasing residence time in groundwater. Conventional analytical approaches rely on parent compound/metabolite ratios. These are difficult to interpret if metabolites are sorbed or further transformed. Compound-specific

The isotopic compositions of oxygen (δ 18O) and hydrogen (δ 2H) of precipitation were determined from three different locations in the western Niger Delta (Warri, Ughelli and Abraka) between 2014 and 2015. 18O and 2H in wet season precipitation were more depleted compared to the dry season. Similarly, d-excess computed for wet season precipitation is lower than that for the dry season. The δ 18O and

ABSTRACT The mid-latitude coastal area at the western South-Atlantic out of the tropics is under the combined effect of different atmospheric circulation patterns at different temporal scales, which can be shown by the isotope composition of precipitation. This pattern effect is more changing and complex than that for the well-studied tropical areas, the isotope studies being an interesting proxy for

ABSTRACT Glacial and periglacial basins contain the largest reserves of fresh water in the world. These areas are extremely sensitive to global warming and climate change. The dry Andes of South America are characterized by large periglacial areas. This study focuses on the water isotopic composition and hydrochemistry of a typical periglacial environment of the Andes, in the Vallecitos catchment (2400–5500

ABSTRACT Hosting the flattest sedimentary plains and highest Andean range of the continent, southern South America faces hydrological transformations driven by climate and land use changes. Although water stable isotopes can help understand these transformations, regional synthesis on their composition is lacking. We compiled for the first time a dataset of H and O isotopic composition for 1659 samples

ABSTRACT Intensive groundwater use has altered the local hydrological cycle within the Bajío Guanajuatense, Mexico. To improve the knowledge of this hydrogeological system and support water management in the area, groundwater end members were identified using multivariate statistical analysis. Pumped groundwater is composed of two well-mixed end members: (a) recent recharge, affected by a reuse cycle

ABSTRACT In the eastern region of central Costa Rica, land use in the sub-basins of the Maravilla-Chiz and Quebrada Honda rivers (47 km2) is dominated by agricultural and livestock production, while groundwater resources constitute the main drinking water supply. This study aimed to (a) evaluate the location of groundwater recharge areas and groundwater flow paths, and (b) provide a characterization

ABSTRACT The Guaraní Aquifer System (SAG) is the largest transboundary aquifer in Latin America, extending beneath parts of Brazil, Paraguay, Argentina, and Uruguay. This paper presents the results of recent hydrogeological studies in the southern portion of the SAG. Locally, the abundance of surface water bodies precluded the use of conventional hydrological tools to characterize groundwater flows

The carbon isotopic composition (δ13C) of foliage is often used as proxy for plant performance. However, the effect of N O 3 - vs. N H 4 + supply on δ13C of leaf metabolites and respired CO2 is largely unknown. We supplied tobacco plants with a gradient of N O 3 - to N H 4 + concentration ratios and determined gas exchange variables, concentrations and δ13C of tricarboxylic acid (TCA) cycle intermediates

ABSTRACT This work applied environmental isotope techniques to validate the results of previous studies on recharge sources in a rural area in central Chile (34.3° S and 71.3° W) and discern the origin of nitrate contamination in wells. Stream water and groundwater samples were taken during three surveys, two during spring snowmelt and one in low-water conditions. Chemical analyses included major cations

ABSTRACT Coastal ecosystems are under increasing stress from anthropogenic nutrient loading; which is most often assessed through water quality measurements. Here, 136 published studies on the use of δ15N to identify nutrient loading in coastal systems were analyzed to identify key strengths and challenges when using this isotope technique. δ15N has been used successfully for this purpose around the

ABSTRACT Water use by anthropogenic activities in the face of climate change invokes a better understanding of headwater sources and lowland urban water allocations. Here, we constrained a Bayesian mixing model with stable isotope data (2018–2019) in rainfall (N = 704), spring water (N = 96), and surface water (N = 94) with seasonal isotope sampling (wet and dry seasons) of an urban aqueduct (N = 215)

ABSTRACT In Chile, erosion processes (on-site and off-site impact) affect at least 36.9 million ha–1, representing 49% of the total land area. Different regions show severe soil degradation mainly caused by water erosion processes. The importance of sediment-associated transport and the key role of soil erosion affect the fertility of the land and the contamination of water bodies. The aim of this

ABSTRACT The estimation of lake hydrological characteristics such as evaporation/inflow ratios and water residence time becomes necessary for understanding cycling and potential retention of natural and anthropogenic substances into the lake. The aim of this work was to estimate the evaporation loss and the water residence time of a temperate shallow lake based on the water isotope mass balance approach

ABSTRACT This work presents a weekly carbon isotope composition analysis (June 2017–January 2018) of carbon dioxide (CO2) and methane (CH4) in a tropical urban atmosphere (Central Valley, Costa Rica). δ13C values of CO2 and CH4 ranged from –12.2 to –5.9 ‰, and from –51.6 to –46.3 ‰, respectively. Mixing ratios of CO2 and CH4 varied from 384.2 to 528.5 ppmv, and from 1.860 to 2.613 ppmv, respectively

ABSTRACT The Mendoza River streamflow, South America (∼32 °S), derives almost exclusively from winter snow precipitation falling in the Andes. Almost 70% of the water feeding the river originates in the Cordillera Principal geological province. In addition to the snow that precipitates in this area, there are 951 cryoforms providing meltwater to the upper catchment. Given the high inter-annual variability

ABSTRACT Sustainable groundwater management implies a good knowledge of recharge processes, especially in areas with water deficit, like the semi-arid region of Banabuiú watershed (Ceará State, Northeast of Brazil). In this zone, phreatic aquifers consist of Precambrian crystalline fractured reservoirs characterised by a high spatial anisotropy, both in terms of hydrodynamics and water quality. This

ABSTRACT The Tubarão aquifer system constitutes a very complex, multilayered aquifer enclosed in the Paraná basin (central-southern part of Brazil). Despite the relatively low productivity of wells, groundwater represents an important source of water for the very populated and industrialized zones of the State of São Paulo. An extensive water sampling campaign was carried out followed by hydrochemical

ABSTRACT The objective of this work is to enhance the conceptual hydrogeological model in the Río Cuarto River basin by using isotope and hydrochemical techniques. The precipitation pattern, as reflected in the average values of δ 2H and δ 18O in stations located in the plains and in the mountains, showed an isotope depletion from the East to the West, attributed to continental and altitude effects

ABSTRACT Monitoring of water quality over several years has revealed a persistent pesticide contamination of surface and groundwater in several Caribbean Islands, with pesticide concentrations locally over the drinking-water limit set in Europe, i.e. 0.1 µg L–1 per substance. For Martinique, mainly one pesticide, chlordecone (CLD), remains of major concern despite its withdrawal from the market in

In 2015 and 2016, groundwater samples were collected in Hanoi to analyse the isotopic composition (δ2H, δ18O and 3H) and elucidate the relationship between groundwater and surface water, as well as the origin of the groundwater. The values for δ18O and δ2H indicate that the groundwater originated from evaporated meteoric water and the isotope enrichment is due to the evaporation of shallow groundwater