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Polymer bonded Graphene- LaNiSbWO4 nanocomposite (G-LaNiSbWO4-PPy) for CO2 sensing performance under normal temperature condition Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2021-01-21 Won-Chun Oh; Yin Liu; Suresh Sagadevan; Kamrun Nahar Fatema; Md Rokon Ud Dowla Biswas
Abstract Demand for the detection of carbon dioxide (CO2) is increasing in various fields, including air-quality monitoring, health care, and agriculture. Smart gas sensors, in which micromachined gas sensors are integrated with driving circuits, are desirable for the social development of the internet of things. In this study, CO2 sensors were fabricated and investigated. The sensors have LaNiSbWO4-G-PPy
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Efficient adsorbent for the removal of methyl orange and Congo red by calcined Zn-Al layered double hydroxide Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2021-01-10 H. Djezar; K. Rida; M. Salhi
Abstract In this study, calcined layered double hydroxides (ZnAl-cLDH) with Zn/Al molar ratio of 2:1 was prepared via coprecipitation method at constant pH of 9 and calcination at 500 °C. The resultant calcined (ZnAl-cLDH) were applied for the adsorption from Congo red and Methyl orange dye removal from aqueous phase. The adsorption kinetics fit the pseudo-second order kinetic models well and the Langmuir
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Hydrothermal synthesis, structure and variable temperature magnetic performance of polyferric sulfate with µ 3-O2- and µ 3-OH--centered Trinuclear Ferric(III) Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2021-01-07 Fang-Kuo Wang; Weiguo Liu; Hua-Ze Dong
Abstract A novel inorganic coordination polymers crystal is grown from ferric sulfate solution under hydrothermal condition in the presence of adipic acid. The single crystal structure analysis shows that 0.5[Fe6(μ3-O2-)2(μ3-OH-)2(SO4)6].2H2O 1 is composed of µ 3-O2- and µ 3-OH--centered Trinuclear Ferric(III) secondary building units (SUBs) to form two dimensional network, and the lattice parameters
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Constructions of seven noncovalent-bonded supramolecules from reactions of Cu(II)/Cd(II)/Zn(II) with isonicotinamide and carboxylates Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2021-01-05 Weiqiang Xu; KaiKai Hu; Shouwen Jin; Yuting Zhang; Daqi Wang
Abstract Transition metal carboxylates with O- and N-donor ligands are interesting for their structural features. Seven novel isonicotinamide(inic)-based metal complexes of [Cd(inic)2(L1)2(H2O)2] · 2H2O (1) (L1 = 2-chloronicotinate), [Cd(inic)2(L2)2(H2O)2] (2) (L2 = 2,4-dichlorobenzoate), [Cu(inic)2(L3)2] (3) (L3 = 4-chlorophenoxyacetate), [Cu3(inic)6(L4)2(HL4)2(H2O)2] · 2H2O (4) (L4 = azelate), [
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Two Co(II)-coordination polymers: reducing the inflammasome activation and exerting treatment activity on age-related macular degeneration Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2021-01-05 Ying Zhou
Abstract Two new cobalt(II) coordination polymers based on H4bpta (H4bpta = 3,3′,5,5′-biphenyltetracarboxylic acid) and N-donor ligands, namely [Co2(1,3-bimb)2(bpta)] n ·2nH2O (1) and [Co2(1,4-bib)2(bpta)] n ·2n(H2O·DMF) (2), (1,4-bib = 1,4-bis(imidazol-1-yl)benzene, 1,3-bimb = 1,3-bis((1H-imidazol-1-yl)methyl)benzene), have been obtained under solvothermal conditions. Series of biological experiments
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Two 3D metal(II)–organic coordination polymers constructed by semi-rigid imidazolium carboxylate ligand: synthesis, crystal structure and property Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2021-01-05 Jiu-Fu Lu; Mei-Ling Liu; Cai-Bin Zhao; Pei Huang; Yan-Hong Gao; Nan Zheng; Qin Wang; Ling-Xia Jin; Xiao-Hu Yu; Hong-Guang Ge
Abstract Two metal coordination polymers, namely {[Co(MIBA)2]·2H2O}n (SNUT-3) and {[Cu(MIBA)2]·2H2O}n (SNUT-4), where HMIBA = 4-(1H-2-methylimidazol-1-yl)benzoic acid, were prepared by hydrothermal methods. Single-crystal X-ray analysis revealed that the structure of SNUT-3 exhibits a 3D→3D fourfold interpenetrating structure with diamondoid frameworks, while SNUT-4 shows a 2D + 2D → 3D inclined polycatenation
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Syntheses, structures, and fluorescent and magnetic properties of four metal–organic coordination polymers constructed from dicarboxylate ligands Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2021-01-04 Yong-Hong Zhou; Yun Xu; Jun-Qing Shi; Yue Su; Mei-Ling Sun; Si-Hui Wang; Long-Long Wang; Qing-Qing Wang; Yuan-Jie Wei
Abstract Four new coordination polymers, namely [Cd(OBA)(H2O)3]n (1), [Zn2(OBA)2(PBHB)2]n (2), [Mn(OBA)(BBHB)2]n (3), and [Co(MIP)(BPP)]n (4) (H2OBA = 4-oxyacetate-benzoic acid, PBHB = 1,1′-(1,3-propanediyl)bis-1H-benzimidazole, BBHB = 1,1′-(1,4-butanediyl)bis-1H-benzimidazole, H2MIP = 5-methylisophthalic acid, and BPP = 1,3-bis(4-pyridyl)propane)), were prepared and structurally characterized by single-crystal
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Synthesis, crystal structure, theoretical calculation, and DNA binding of a copper (II) complex with 3,5-dibromo-L-tyrosine Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-29 Ziao Zong; Gui-Mei Huang; Xia Zhang; Yu-Hua Fan; Cai-Feng Bi; Dong-Mei Zhang; Xing-Chen Yan; Nan Zhang
Abstract A mononuclear complex Cu(L1)2·CH3OH·H2O (L1: 3,5-dibromo-L-tyrosine) was synthesized and characterized by IR, elemental analysis, and X-ray diffraction single-crystal analysis. Each Cu2+ ion is four-coordinated by two nitrogen atoms and two (carboxylic) oxygen atoms L1. Theoretical calculation of the title complex was performed by density functional theory (DFT) B3LYP method using the 6-3 l + G*
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Facile synthesis of nanostructured trirutile antimonates M(II)Sb2O6 (M = Co, Cu, Ni, Fe) and its visible photocatalytic studies Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-28 Nagarajan Arunkumar; Saraschandra Naraginti
Abstract A visible light active nanocrystalline trirutile antimonates CoSb2O6, CuSb2O6, NiSb2O6 and FeSb2O6 were prepared by solution combustion method and their visible light photocatalytic activity was reported for the first-time. The as prepared products were in nanocrystalline single phasic trirutile structure. These compounds were synthesized with different oxidant to fuel ratios (O/F = 1, O/F = 0
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Synthesis and crystal structure of a new three-dimensional cd(II) coordination polymer based on 5-(3′,4′-dicarboxylphenoxy)-isophthalic acid Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-28 Shi-Hui Li; Jia-Wei Tang; Jia Zang
Abstract Under hydrothermal conditions a new Cd(II) polymer [Cd(dic)]n 1 (H4dic = 5-(3′,4′-Dicarboxylphenoxy)-isophthalic acid) was synthesized. The compound crystallizes in the space group C2 and the Monoclinic system, with b = 8.0043(9), a = 18.523(2), c = 16.5238(19) Å, β = 118.742(2)°,α = 90°, γ = 90°, Z = 1, V = 2148.1(4) Å3, Mr = 2728.38, Dc = 2.109 Mg/m3, F(000) = 1332, μ = 2.059 mm−1, the final
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Synthesis and characterization of cryptomelane (α-MnO2) nanoparticles: Influence of phthalic acid adsorption and oxidation on the mineral structure Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-28 A. Naidja; A. Karaali; K. Mirouh; H. Stanjek
Abstract Cryptomelane (α-MnO2) nanoparticles synthesis was achieved via a Sol-Gel route in mild conditions. XRD analysis showed that the α-MnO2 phase was of high purity and crystallized in the monoclinic space group I2/m, with 12 nm average crystallite size (D). After interaction with an organic pollutant (Phthalic acid, PA), excepting the pronounced decrease in β angle, α-MnO2 cell parameters slightly
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Synthesis and crystal structure of a new three-dimensional Cd(II) coordination polymer based on 4,4′-bipyridine and 3,3′,4,5′-biphenyl tetracarboxylic acid Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-24 Shi-Hui Li
Abstract A new Cd(II) polymer [Cd(btc)(4,4′-bipyridine)] n 1 (H4btc = 3,3′,4,5′-biphenyl tetracarboxylic acid) was synthesized under hydrothermal conditions. The compound crystallizes with b = 20.223(3), c = 13.478(2) Å, a = 11.9134(18), β = 110.486(2)°, α = 90°, γ = 90°, V = 3041.8(8) Å3, Z = 4, in the monoclinic system, space group P2(1)/c, μ = 1.468 mm−1, M r = 690.33, F(000) = 1600, D c = 1.771 mg/m3
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A EuIII-based coordination polymer: crystal structure and anti-colon cancer activity Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-24 Wen-Long Xu; Qi Sun; Chun-Dong Gao; Neng-Wei Zhang
Abstract A novel coordination polymer (CP) {[Eu(HL)]·2(H2O)}n (1) contains luminescent EuIII ion as the metal node on the basis of a bis-(imidazole-4,5-dicarboxylate) ligand (H4L) was synthesized via reaction of H4L and Eu(NO3)3·6H2O using sodium hydroxide as pH regulator under the hydrothermal condition. The inhibitory activity of compound on SW16 (human colon cancer cells) with squamous shape was
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Biosynthesis, antimicrobial spectra and applications of silver nanoparticles: current progress and future prospects Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-22 Nimisha Tehri; Amit Vashishth; Anjum Gahlaut; Vikas Hooda
Abstract The importance of biological agents has been recognized as a promising tool for green synthesis of silver nanoparticles over conventional physiochemical methods that are laden with various type of drawbacks. The biomediated nanoparticles synthesis chiefly employing microorganisms and plants as nanofactories is gaining worldwide popularity over past few decades. Biosynthesized silver nanoparticles
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A review on green synthesis of iron (Fe) nanomaterials, its alloys and oxides Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-22 Muhammad Imran Din; Ayesha Zahoor; Zaib Hussain; Rida Khalid
Abstract In this study, we reviewed the biogenic route for the synthesis of iron nanomaterials (Fe-NMs) with special emphasis on recent progress. Natural products or its derivatives including extract of plants part, microorganisms, and various biomolecules have been used as stabilizing and reducing agents during synthesis. The greener methodology is quite simple, eco-friendly and generally followed
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Study of the improvement activity on the patients’ cognitive function after general anesthesia of two Co(II)-coordination polymers derived from an ether-bridged tricarboxylic acid Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-22 Hai-Feng Zhu; Jing-Hua Liu; Fu-Tao Tian
Abstract In this study, an ether-bridged aromatic carboxylic acid, 2-(2-carboxyphenoxy)terephthalic acid (H3cpta), was applied as the building block for the generation of two new Co(II)-based coordination polymers (CPs) with the chemical formulae of [Co3(μ5-cpta)2(2,2′-bipy)2] n (1, 2,2′-bipy = 2,2′-bipyridine) [Co3(μ3-cpta)2(phen)3(py)3(H2O)3] n (2, phen =1,10-phenanthroline, py = pyridine) by reaction
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Comparison of efficacy of nanoparticles synthesized from leaves and flowers of Russelia equisitiformis Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-22 Sabiha Sulthana H. B.; Ranjani S.; Hemalatha S.
Abstract The present study was focused on synthesis of silver nanoparticles using Russelia equisitiformis plant (RelAgNps) and flower extracts (RefAgNps). Thus, the nanoparticles synthesis was confirmed using UV spectrometry and the FT-IR results showed the presence of similar compounds in the plant extract and FESEM-EDAX reveals the size, shape, and elemental composition of synthesized nanoparticles
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In vitro investigation of swelling triggered release of 5-fluorouracil from gelatin coated gold nanoparticles Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-22 Nishi Verma; Alka Tiwari; Neha Sonker; Jaya Bajpai; Anil Kumar Bajpai
Abstract In the present study gelatin coated-gold nanoparticles were synthesized and release study of the drug “5-fluorouracil” (5-FU) was carried out in a controlled manner. Gelatin nanoparticles were prepared by single water in oil (W/O) emulsion crosslinking technique and gold (Au) nanoparticles by Turkvitch method. For preparing gelatin coated-Au nanoparticles, in situ method was adopted. The release
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A mixed-ligand Cu(II)-coordination polymer: analgesic activity and nursing application after total knee arthroplasty Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-21 Yi-Ming Sun; Shi-Qing Liu; Yue-Qin Yu
Abstract Based on 5-dimethylamino-isophthalic acid (H2dia) and 1,2-bis(4-pyridyl)ethylene (bpe) mixed linkers, a new Cu(II) coordination polymer material, [Cu(dia)(bpe)(H2O)]n (1), has been successfully prepared under the hydrothermal reaction conditions. As the disadvantages about current therapy method, new compound with novel mechanism was developed for the analgesic treatment after total knee arthroplasty
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Synthesis and application of silver nanoparticles using Cissus quadrangularis Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-20 Sai Nivetha S.; Ranjani S.; Hemalatha S.
Abstract This current study mainly focuses on synthesis of silver nanoparticles in an eco-friendly method using Cissus quadrangularis (CqNp), its characterization and understanding its potential biomedical applications. The CqNp’s were confirmed using UV-vis spectroscopy, FT-IR and the structure of the nanoparticles were analyzed by FESEM and EDAX. Anti-oxidant assay conducted with the plant and the
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Development of nanoemulsion gel based formulation of terbinafine for the synergistic antifungal activity: Dermatokinetic experiment for investigation of epidermal terbinafine deposition enhancement Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-20 Prabhu Raut; Shobhit Kumar; Babar Iqbal; Javed Ali; Sanjula Baboota
Abstract Objective of study was to develop and optimize nanoemulsion gel of terbinafine using Melaleuca alternifolia (tea tree) oil for synergistic antifungal activity against Candida albicans. Permeation coefficient of nanoemulsion gel and marketed cream was found to be 2.54 × 10−3 cm/h and 1.64 × 10−3 cm/h, respectively. Cskin max, AUC0–5h, AUC0-∞, and penetration constant (Kp) were found to be significantly
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Enhanced safety electrolyte mixture of ionic liquids and lithium salt for Li-ion transference number (Li-T) in Li-Li symmetric coin cell Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-17 T. V. M. Sreekanth; J. Kim; K. Yoo
Abstract In lithium-ion batteries (LiBs), electrolyte plays an essential role in leading the performance of the cell. Room-temperature (RT) ionic liquids (ILs) are currently the utmost attractive research in the area of LiBs, owing to their intrinsic properties, like low volatility, non-flammability, good thermal stability, and electrochemically stable. In this present study, we report the electrochemical
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Assessment of structural and cytotoxic properties of cobalt ferrite nanoparticles for biomedical applications Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-17 Banu Süngü Mısırlıoğlu; Öznur Çakır; Hilal Calik; Rabia Cakir-Koc
Abstract Cobalt ferrite (CoFe2O4) has numerous desirable features such as high anisotropy, good magnetic saturation, large coercivity and high mechanical strength. These remarkable characteristics provide extensive employment for their wide application from industrial to biomedical. The present study aims to evaluate the crystal properties, particle size, and morphology of CoFe2O4 nanoparticles prepared
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A one-dimensional chiral gadolinium complex based on a tartaric acid derivative: crystal structure, thermal behavior and magnetic properties Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-17 Han-tao Zhang; Ling Ma; Mei-rong Han; Si-si Feng; Miao-li Zhu
Abstract A new chiral one-dimensional gadolinium coordination polymer [Gd(HDTTA)3(CH3OH)3]n (1) (D-H2DTTA = (+)-Di-p-toluoyl-D-tartaric acid) was synthesized at room temperature, and fully structurally characterized by Infrared (IR), elemental analysis (EA), single-crystal and powder X-ray diffraction (PXRD). The structure analysis shows that complex 1 belongs to the trigonal system with R3 space group
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Lanthanide coordination polymers: prevention activity on the hypotension after anesthesia by regulating the α receptor expression on the peripheral blood vessels Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-16 Ai-Jie Huang; Li-Hong Leng; De-Qian Xin; Su-Chun Ding
Abstract Two lanthanide coordination polymers (CPs) with the chemical formulae of [Pr(HPIDC)(C2O4)0.5(H2O)] n (1, H3PIDC = 2-(pyridine-2-yl)-1H-imidazole-4,5-dicarboxylic acid and H2C2O4 = oxalic acid) and [Tm2(HPIDC)(C2O4)2(H2O)3] n ·2nH2O has been prepared under hydro-solvothermal conditions and characterized by single crystal X-ray diffraction, elemental analysis, IR spectroscopy, and thermogravimetric
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Microwave-assisted fabrication of CQDs/ZnIn2S4 nanocomposites for synergistic photocatalytic removal of Cr(VI) and rhodamine B Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-16 Yan-Hong Gao; Xiao-Hui Ji; Dan Zhang; Zhi-Feng Liu; Jiu-Fu Lu
Abstract CQDs/ZnIn2S4 (CQDs represents carbon quantum dots) nanocomposites were prepared via a microwave-assisted hydrothermal method. The photocatalytic activity for the reduction of Cr(VI) to Cr(III) over the as-prepared CQDs/ZnIn2S4 nanocomposites under visible light irradiations was studied. The study found that the reduction of Cr(VI) to Cr(III) over hexagonal ZnIn2S4 can be significantly increased
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Gas-phase DFT studies, quantum chemical calculation and 3D energy framework analysis of novel copper complex of sulfadimethoxine in the presence of secondary ligand 3-methyl pyridine Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-15 Bhavesh N. Socha; Sachin B. Pandya; Bhavin R. Chavda; Kaushik P. Chaudhary; Taruna J. Padariya; Mohammed Dawood Alalawy; Rahul P. Dubey; Urmila H. Patel; R. H. Patel
Abstract Synthesis and crystal structure with extensive biological activity of the copper sulfadimethoxine complex in the presence of secondary ligand 3-methyl pyridine (title molecule) has been reported earlier. Crystal structure of the title molecule crystallizes in monoclinic space group P21/n. The extension of this work, stability, and reactivity of the title molecule are carried out in the DFT
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Nickel oxide nanoparticles: biosynthesized, characterization and photocatalytic application in degradation of methylene blue dye Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-14 Abdolhossein Miri; Fatemah Mahabbati; Ahmad Najafidoust; Mohammad Javad Miri; Mina Sarani
Abstract In the present study, nickel oxide nanoparticles were prepared using the aqueous extract of Zizyphus jujuba. The temperature and time calcination was studied on size and morphology of synthesized nanoparticles. In addition, the obtained nanoparticles were identified through PXRD, UV-Vis, Raman, FESEM, and EDX methods. The results of PXRD, which were surveyed through Debye-Scherrer and Rietveld
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Spectroscopic evidence of chirality in tetranuclear Cu(II)-Schiff base complexes, catalytic potential for oxidative kinetic resolution of racemic benzoin Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-10 Dipali Sadhukhan; Prithwi Ghosh; Susanta Ghanta
Abstract Two chiral Schiff base ligands 2-((1-hydroxy-3-phenylpropan-2-ylimino)methyl)-6-methoxyphenol (L1H2 ) and 2-(4-hydroxy-3-isopropylbut-1-enyl)-6-methoxyphenol (L2H2 ) have been synthesized by the condensation of l-phenylalaninol/l-valinol and o-vanillin (2-hydroxy-3-methoxy benzaldehyde). A tetranuclear homometallic Cu(II) complex [Cu4(L1H)2(L1)2] (ClO4)2 (C1) and a hexanuclear heterometallic
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One-pot, aqueous synthesis of multifunctional biogenic Ag NPs for efficient 4-NP reduction, Hg2+ detection, bactericidal, and antioxidant activities Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-10 Dasari Ayodhya; Guttena Veerabhadram
Abstract We have developed a green and environmentally friendly approach for the synthesis of silver nanoparticles (Ag NPs) using Pithecellobium dulce seeds (PDS) extract via a simple route and characterized by several techniques. Ag NPs have an average particle size is 8 nm and used as a catalyst for the reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) within 3 min of reaction. Ag NPs could
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Plant mediated synthesis of AgNPs and its applications: an overview Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-09 Aswathi Shyam; Smitha Chandran S.; Bini George; Sreelekha E.
Abstract Plant mediated synthesis of nanoparticles is a path breaking approach to fabricate ecologically friendly nanoparticles which can be utilized in various applications. The majority of the existing procedures used for nanoparticles synthesis rely up on chemical and physical methods, these methods are sometimes harmful and potentially dangerous to the environment and living organisms. But synthesis
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Microwave-assisted deposition synthesis, characterization and photocatalytic activities of UV-light-driven Ag/BiOCl nanocomposites Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-07 Anukorn Phuruangrat; Titipun Thongtem; Somchai Thongtem
Abstract Ag/BiOCl nanocomposites used for photodegradation of methylene blue (MB) and methyl orange (MO) under UV and visible light were synthesized by a combination of hydrothermal method and microwave-assisted deposition method. The as-prepared samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), selected area electron
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Effect of cobalt content on electrodeposition and properties of Co–Ni alloy thin films Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-06 S. Tebbakh; L. Mentar; Y. Messaoudi; M. R. Khelladi; H. Belhadj; A. Azizi
Abstract Co–Ni thin films alloys were deposited on ruthenium substrates by the electrochemical method from chloride bath at pH 3.8. The effect of cobalt content on the composition, morphology, electrochemical and microstructural properties of the electrodeposited thin films was investigated. Effectively, the conditions of electrodeposition of Ni–Co deposits were determined using the cyclic voltammetry
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Green synthesis, characterization and antimicrobial activity of zinc oxide nanoparticles using Artemisia pallens plant extract Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-04 R. Gomathi; Harindran Suhana
Abstract The green synthesis of zinc oxide nanoparticles from plant extract is attracting great interest owing to the cost effectiveness and ecofriendly method of synthesis. Crystalline hexagonal shape zinc oxide (ZnO) nanoparticles of approximately 50-100 nm were synthesized through a one-step solution-based technique using alcohol free Artemisia pallens plant extract as a reducing agent. Analysis
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Heterogeneous sono-photo-Fenton degradation of methyl violet 10B using Fe2O3-Al2O3-Ga2O3 as a new photocatalyst Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-03 Hamida Bekakria; Hacene Bendjeffal; Abdelkrim Djebli; Hadjer Mamine; Toufek Metidji; Zahia Benrdjem
Abstract This study focuses on the use of Fe2O3-Al2O3-Ga2O3 as a new photocatalyst for the sono-photo-Fenton degradation of Methyl violet 10B. Fe2O3-Al2O3-Ga2O3 was prepared using the chemical precipitation method and characterized by various techniques, such as BET, FTIR, SEM, and XRD. The optical properties of the photocatalyst were investigated, and the optical band gap was found to be 2.25 eV.
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Myco-nanocolloids manipulate growth, biofilm formation and virulence genes in UTI causing E. coli Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-03 Ranjani S.; Rumelee Das; Shariq Ahmed M; Esther Lalnunmawii; Senthilkumar Nachimuthu; Ruckmani K.; Hemalatha S.
Abstract The existing antibiotics are incapable of killing resistant pathogens including E. coli. Extended-spectrum beta-lactamases (ESBL) genes are found as one of the main causes of the resistance as it degrades the β- lactam ring of the antibiotics. This study aims at the green synthesis of silver nanocolloids from endophytic fungi Lasiodiplodia theobromae (LtNc’s), isolated from traditional medicinal
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Two mixed-ligand coordination polymers: reducing the inflammatory response and exerting protective activity on the periodontitis Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-03 Xue Zhang; Yuan Qin; Qing-Xia Zhao; Chun-Shan Yang; Yun-Cong Liu
Abstract By a bifunctional organic ligand 2-(benzimidazol-1-yl)terephthalic acid (H2bitp) featuring both imidazol-carboxylate groups, two new Cu(II)-containing coordination polymers (CPs) with the chemical formulae of {[Cu(bitp)(bpa) 0.5(H2O)2]·0.5bpa} n (1, bpa = 1,2-bis(4-pyridyl)ethylane) and {[Cu1.5(bitp)(Hbitp)(2,2′-bpy)(H2O)]·3H2O} n (2, 2,2′-bpy = 2,2′-bipyridine) have been successfully prepared
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In situ generation of antibacterial silver nanocomposite cotton fabrics by bio route Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-02 Prasad Akepogu; Umamahesh Mallavarapu; Venkata Subbareddy Gopireddy; Jaswanth Seetha; Arundathi Mesa; Varaprasad Duddela; Varada Rajulu Anumakonda
Abstract Antibacterial silver nanocomposite cotton fabrics were generated by in situ method using Senna auriculata (SA) leaf broth as reductant. Silver nanoparticles (AgNPs) synthesized on cotton fabrics (nanocomposite cellulose fabrics [NCCFs]) were analyzed by different spectral characteristics like FTIR, SEM correlated with EDX and XRD. The SEM analysis revealed that the generated AgNPs on NCCFs
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A new symmetrical nickel(II) complex with isothiocyanate coordination: synthesis, crystal structure, Hirshfeld surface analysis, DFT calculation and antibacterial activities Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-02 Ji-Fa Wang; Ya-Juan Li; Shuang-Zhu Guo; Li Zhao
Abstract The metal salts KSCN, Ni(CH3COO)2·4H2O, and auxiliary ligand pyridine were added respectively to the salamo-like ligand H2L, and it is expected that the Ni(II) complex coordinated by H2L will be obtained. X-ray analysis of the obtained blue bulk single crystal revealed that the ligand H2L did not participate in the coordination, and a mononuclear Ni(II) complex [Ni(Py)4(NCS)2] contained four
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A new Cu(II) complex: treatment activity on ICH via reduction the ROS production and inflammatory response in vascular endothelial cells Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-02 Yu Yang
Abstract A new Cu(II) coordination polymer (CP), [Cu(1,3-BDC)Dptztz]·DMF (DMF = dimethylformamide) was synthesized by reaction of the Cu(NO3)2·3H2O with the 2,5-di(4-pyridyl)thiazolo[5,4-d]thiazole (Dptztz) in the presence of the isophthalic acid (1,3-H2BDC). The as-prepared complex 1 has been structurally studied via single crystal X-ray diffraction and further characterized by elemental analysis
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The effect of nitrogen concentration on N-doped diamond-like carbon films prepared by plasma-electrolytic method Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-02 S. Sarihi; S. Padervand; S. M. Mousavi khoei; N. Shakiba
Abstract Nitrogen-doped diamond-like carbon films were deposited on tool steel substrate througha plasma electrolytic technique. These coatings were fabricated using the hydrocarbons containing nitrogen vapor as a nitrogen and source. The formation of films was proved by Raman spectroscopy, X-ray diffraction patterns, and cross-section scanning electron microscopy. According to the results, by increasing
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Hydrothermal synthesis, structure and properties of a new 3D two-fold Co-based coordination framework Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-02 Man-Sheng Chen; Xiao-Jie Li; Yi-Fang Deng; Chun-Hua Zhang; Liang-Bing Sheng; Wei-Hong Lu
Abstract A new 3D coordination polymer, [Co2(MIP)2(BMIP)] n (1), [H2MIP = 5-methyl-isophthalic acid, BMIP = 1,5-bis-(2-methyl-imidazol)pentane] has been synthesized and characterized by single crystal X-ray diffraction analysis. The results of structural analyses show that 1 has a two-fold interpenetrated 3D network with a pcu topology. In addition, the luminescent, electrochemical properties and degradation
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Nanomaterials and nanotechnology for water treatment: recent advances Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-02 Siavash Iravani
Abstract Water disinfection processes such as sedimentation, filtration, and chemical or biological degradation are not fully capable of destroying emerging contaminants or certain types of bacteria. Nanotechnology can potentially be employed to address these challenges posed by various contaminants and microorganisms. This paper highlights the advanced nanomaterials and approaches for the removal
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Synthesis and characterization of a manganese(II) complex containing N(sp 2)4-donor Schiff base ligand and interaction toward biomacromolecules Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-02 Mohammad Hakimi; Behjat Tarani; Zahra Mardani; Hassan Hassani; Monika Kučeráková; Eliska Skorepova
Abstract In this work, an N4-donor Schiff base ligand, N,N'-(propane-1,2-diyl)bis(1-phenyl-1-(pyridin-2-yl)methanimine) (PPPM) and its Mn(II) complex, [Mn(PPPM)(OAc)2]·3H2O (1), were prepared and identified by elemental analysis, FT-IR, 1H NMR spectroscopy as well single-crystal X-ray diffraction. X-ray structure analysis of 1 revealed a distorted square-face bicapped trigonal prism geometry around
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Preparation, spectral characterization, ESR measurements and DFT calculations of Schiff base copper(II) complex Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-02 Sibel Tokdemir Öztürk; Perihan Aksu; Nevin Turan; Kenan Buldurun; Emine Tanış; Naki Çolak
Abstract The title compound ([CuClL(H2O)]·2H2O) were synthesized. The copper(II) complex in square planar geometry were identified by using elemental analysis, magnetic susceptibility, mass spectra, FT-IR, UV-Vis. and ESR techniques. DFT calculations at the UB3LYP/LANL2DZ level of theory were conducted to obtain vibrational and electronic properties of the copper(II) complex. Vibrational assignments
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Avicennia marina mediated synthesis of TiO2 nanoparticles: its antibacterial potential against some aquatic pathogens Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-01 Mina Shahin Lefteh; Iman Sourinejad; Zahra Ghasemi
Abstract This study reports the synthesis of TiO2 nanoparticles through a bio-approach by Avicennia marina leaf extract to titanium source ratios of 0.03, 0.06, 0.125, 0.20, 0.25 and 0.5, and examines its antibacterial activity against some aquatic bacterial pathogens. XRD confirmed the synthesis of crystalline anatase TiO2NPs and showed the increase of crystallite size with increasing the ratio from
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Structural characterization and anti-cancer activity of a Cu(II)-based coordination polymer Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-12-01 Huichao Chang; Yuehua Yang
Abstract By using a mixed-ligand approach, a new Cu(II)-based coordination polymer (CP) with the chemical formula of {[Cu2(ptd)2(IPA)2]·2H2O} n (1, ptd = 4′-(4-pyridine)4,2′:2′,4′′-terpyridine, H2IPA = isophthalic acid) has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, IR spectroscopic, elemental and thermogravimetric analyses. Furthermore, the
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Synthesis, catalytic, cytotoxic, and antibacterial properties of new Ru(II) and Pd(II) complexes bearing bidentate Schiff base ligand Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-11-30 Gizem Selvi; Fethi Ahmet Ozdemir; Gurkan Aykutoglu; Namık Özdemir; Zafer Şerbetçi; Muharrem Dinçer; Osman Dayan
Abstract In the present study, new Ru(II) and Pd(II) complexes with sulfonated bidentate Schiff base ligand were synthesized and structurally characterized by NMR, FT-IR, MS spectroscopic methods. Additionally, the solid-state structure of the Schiff base ligand was determined with a single crystal-XRD technique. Then, the antibacterial properties and in vitro cytotoxicity of the synthesized compounds
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Enhancing mechanical properties of hydroxyapatite-reduced graphene oxide nanocomposites by increasing the spark plasma sintering temperature Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-11-30 Hassan Nosrati; Rasoul Sarraf-Mamoory; Reza Zolfaghari Emameh; Amir Aidun; Maria Canillas Perez
Abstract In this study, the reduced graphene oxide (rGO)-Hydroxyapatite (HA) powders were first synthesized by a hydrothermal method. The amount of graphene in these powders was 1.5% by weight. Subsequently, these powders were consolidated at 900, 930, and 950 °C by spark plasma sintering (SPS) method, while the pressure applied in the process was 50 MPa. The sintered samples were characterized by
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Nanomaterials against pathogenic viruses: greener and sustainable approaches Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-11-28 Ghazaleh Jamalipour Soufi; Siavash Iravani
Abstract Nanostructured materials and nanosystems have garnered attention against viral infections owing to their unique physicochemical properties such as significant catalytic activity, high physicochemical/thermal stability, large specific surface area, remarkable chemical reactivity, and strong electron transfer ability, etc. These materials are broadly fabricated through chemical, physical and
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Mimosa pudica floral nanoparticles: a potent antibiotic resistance breaker Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-11-25 Ranjani S.; Faridha Begum I.; Santhoshini J.; Senthil Kumar N.; Ruckmani K.; Hemalatha S.
Abstract Aqueous extract of Mimosa pudica flowers have been used for the synthesis of silver nanoparticles (MpFNp). MpFNp were characterized by UV–Visible spectroscopy, field emission scanning electron microscopy, Fourier transform infrared spectroscopy, zeta potential, energy dispersive X-ray spectroscopy, and particle size distribution by dynamic light scattering. MpFNp showed bactericidal activity
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Two transition metal coordination polymers: inhibitory effect on Staphylococcus aureus biofilms formation and prevention against spine surgery incision infection Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-11-24 Lin Zhang; Wei Yuan; Pei Zhai; Wei-Dong Ten; Li-Xiang Ding
Abstract In the current research, two new Cu(II)-containing coordination polymers with the chemical formulae of [Cu2(L)2]·2DMA·3H2O (1) and [Cu2(L)2]·H2O (2, H2L = 2-(imidazol-1-yl)terephthalic acid) have been solvothermally synthesized by reaction of Cu(NO3)2·3H2O with the H2L ligand in different solvent systems (DMA/H2O for 1 and NMP/H2O for 2), which have been well characterized by elemental analysis
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Cytotoxic effect, apoptotic activity, hematological and histological alterations induced by green synthesized ZnO nanoparticles applying Hyssopus officinalis leaves Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-11-19 Ghasem Rahimi Kalateh Shah Mohammad; Masoud Homayouni-Tabrizi; Atefeh Ghahremanloo; Navid Yazdanbakhsh
Abstract The synthesis of zinc oxide nanoparticles (ZnO-NPs) provides interesting biological characteristics and therapeutic applications in a particular method, which evolve the versatile platform for the essential development of the new anticancer agents. Cytotoxic effect of ZnO-NPs was evaluated by MTT assay on A549 cell line. Besides, the anti-apoptotic effects of ZnO-NPs were investigated using
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Synthesis, structural characterization, fluorescence properties, and DFT calculations of a novel hetero-hexanuclear [CuII 4GdIII 2] bis(salamo)-like complex involving bidentate chelating and bridging nitrate groups Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-11-18 Ya-Juan Li; Xin Xu; Ruo-Nan Bian; Ke-Feng Xie; Yang Zhang
Abstract A novel hetero-hexanuclear [CuII 4GdIII 2] complex with a symmetrical bis(salamo)-like tetraoxime ligand (H4L), [{Cu2(L)(MeOH)Gd(NO3)2(μ 2-NO3)}2]·2CH3OH was obtained after careful design and synthesis. The structure of the [CuII 4GdIII 2] complex was adequately characterized by elemental analysis, FTIR, and UV–vis spectroscopy. The [CuII 4GdIII 2] complex crystallized in the monoclinic system
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Biosynthesis of (MWCNTs)-COOH/CdO hybrid as an effective catalyst in the synthesis of pyrimidine-thione derivatives by water lily flower extract Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-11-12 Shahrbano Kaveh; Navabeh Nami; Banafsheh Norouzi; Ali Mirabi
Abstract Pink Water lily flower, with the scientific name of Nymphaea alba in the family of Nymphaeaceae, was collected from North of Iran, Mazandaran in spring, dried in shade and powdered. The powdered flower material was extracted in 70% (vol/vol) ethanol. Acid functionalized multi-walled carbon nanotubes/CdO (MWCNTs-COOH/CdO) was fabricated by using the Water lily flower extract. The presence of
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Effect of nitro substitution of azo-chalcone derivatives nano film on electrical memory properties Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-11-11 Quan Liu; Jiu-Fu Lu; Ling-Xia Jin
Abstract A nitro substituted azo-chalcone derivative 3-(4-(dimethylamino) phenyl) diazenyl)phenyl)-1-(4-nitrophenyl) prop-2-en-1-one (AZOC-4N) and a reference compound 3-(4-(dimethylamino) phenyl) diazenyl) phenyl)-1-phenylprop-2-en-1-one (AZOC-H) were synthesized by Claisen Schmidt reaction. Thermogravimetry, UV-vis and cyclic voltammetry were used to study the influence of the introduction of nitro
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Removal of methyl orange from aqueous solutions by a novel, high efficient and low cost copper-modified nanoalum Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-11-11 Roya Mohammadzadeh Kakhki; Soghra Yaghoobi Rahni; Azam Karimian
Abstract In this work, copper-modified nanoalum as a new natural-based sorbent was synthesized and characterized. Then, it was applied for methyl orange removal from water samples. The effect of some parameters such as initial dye concentration, pH, adsorbent dose and temperature on the removal efficiency was investigated. Under optimal condition, the maximum removal was obtained about 90%. The studies
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A new Cu (II)-coordination polymer: inhibiting bcl-2 gene expression in retinal cells and exerting treatment activity on diabetic retinopathy Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-11-09 An-Dai Wu; Hai-Long Lu
Abstract In the current research, a new Cu(II)-containing coordination polymer with the chemical formula of [Cu(IPT)2] n (1) has been successfully prepared by reaction of the Cu(NO3)2·3H2O with a heterotopic imidazole-tetrazole-bifunctional ligand 5-[3-(1H-imidazol-1-yl)phenyl]-1H-tetrazolate. Furthermore, its treatment activity on the diabetic retinopathy was assessed and the related mechanism was
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Combined experimental and computational studies on molecular structure of nickel complex of 4-amino-N-(1, 3-thiazol-2-yl) benzenesulfonamide with coordinated pyridine Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-11-06 Sachin B. Pandya; Bhavesh N. Socha; Kaushik P. Chaudhary; Rahul P. Dubey; Bhavin R. Chavda; Urmila H. Patel; Maheshkumar K. Patel; Nikita J. Patel; Bhupesh S. Bhatt
Abstract Synthesis of the Ni(II) complex of sulfathiazole was carried out and the crystal structure was determined independently. The various vibration patterns of ligand and its Ni(II) complex are studied by IR spectroscopy. Also, the optimized geometry of the complex is derived from DFT/B3LYP calculations and the results are compared with the experimental one. Bond strengths and first hyperpolarizability
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Two Zn(II) carboxylate-terpyridine coordination compounds: crystal structures and biological activity Inorg. Nano-Metal Chem. (IF 0.839) Pub Date : 2020-11-05 Liying Xuan; Dongsong Bai; Luer Bao; Fulong Bi; Yan Jiang
Abstract Two new metal-organic coordination compounds with the chemical formulae of [Zn(Htpt)]n (1) and {[Zn(H2tpt)(H2O)]·1/2SO4·2H2O}n (2) based on a multidentate 4-(2,4,6-tricarboxyphenyl)-2,2′,6,2″-terpyridine ligand (H3tpt) have been prepared by hydrothermal synthesis method and structurally characterized. The treatment activity of the compounds on the peripheral artery disease was further explored
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