Abstract The binary cooperative complementary phenomenon refers to two opposite but cooperative and complementary species or states, which can be observed from atom scale to universe. When binary cooperative complementary pairs in nanoscale are separated by a related characteristic physical distance, the electron and energy transfer through interface can be well tuned, consequently the macroscopic property of a nanomaterial can be highly enhanced, such materials are defined as binary cooperative complementary interfacial nanomaterials (BCCINMs). A variety of BCCINMs have been developed and exhibited outstanding performance. In this review, for fabrication, various binary cooperative complementary pairs are summarized, the obtained BCCINMs and building blocks are classified into 0D, 1D, 2D and 3D materials, some effective methods and advices are also given. In the following, various properties and applications of existing BCCINMs are introduced. In the next part, BCCINMs are extended, multiple binary cooperative complementary pairs and smart BCCINMs are introduced. Moreover, temporal and spatial regulation is also essential for BCCINMs such as bulk heterojunctions and core-shell quantum dots. There is plenty of room at the bottom for BCCINMs, in the future, more binary cooperative complementary pairs should be employed, effective methods should be created and applied to assemble binary cooperative complementary pairs with suitable distribution size and for spatial and temporal regulation.

中文翻译：

---

二元协同互补界面纳米材料研究进展

摘要 二元协同互补现象是指从原子尺度到宇宙都可以观察到的两个相反但合作互补的物种或状态。当纳米尺度的二元协同互补对被相关的特征物理距离隔开时，通过界面的电子和能量转移可以很好地调整，从而可以高度增强纳米材料的宏观性能，这种材料被定义为二元协同互补界面纳米材料（BCCINM）。已经开发了多种 BCCINM 并表现出出色的性能。在这篇综述中，为了制造，总结了各种二元协同互补对，获得的 BCCINMs 和构建块分为 0D、1D、2D 和 3D 材料，还给出了一些行之有效的方法和建议。下面介绍现有 BCCINM 的各种特性和应用。在下一部分中，扩展了 BCCINM，介绍了多个二元协作互补对和智能 BCCINM。此外，时间和空间调节对于体异质结和核壳量子点等 BCCINM 也是必不可少的。BCCINMs的底部空间很大，未来应该采用更多的二元协同互补对，创造并应用有效的方法来组装具有合适分布大小和时空调控的二元协同互补对。引入了多个二元合作互补对和智能 BCCINM。此外，时间和空间调节对于体异质结和核壳量子点等 BCCINM 也是必不可少的。BCCINMs的底部空间很大，未来应该采用更多的二元协同互补对，创造并应用有效的方法来组装具有合适分布大小和时空调控的二元协同互补对。引入了多个二元合作互补对和智能 BCCINM。此外，时间和空间调节对于体异质结和核壳量子点等 BCCINM 也是必不可少的。BCCINMs的底部空间很大，未来应该采用更多的二元协同互补对，创造并应用有效的方法来组装具有合适分布大小和时空调控的二元协同互补对。