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Temperature responsive polymer-supported TEMPO: An efficient and recoverable catalyst for the selective oxidation of alcohols
Tetrahedron Letters ( IF 1.8 ) Pub Date : 2018-12-23 , DOI: 10.1016/j.tetlet.2018.12.051
Tao Chen , Zhenkai Xu , Lei Zhou , Laiyu Hua , Shuo Zhang , Jiping Wang

This study aimed to combine the advantages of homogeneous catalysis and heterogeneous catalysis by immobilizing TEMPO into a water-soluble temperature responsive polymer. The supported TEMPO was water soluble and displayed excellent activity in the selective oxidation of alcohols below the LCST and can be easily recovered.



中文翻译:

温度响应性聚合物支撑的TEMPO:一种有效且可回收的催化剂,用于醇的选择性氧化

这项研究旨在通过将TEMPO固定在水溶性温度响应性聚合物中来结合均相催化和非均相催化的优势。负载的TEMPO是水溶性的,并且在LCST以下的醇的选择性氧化中表现出出色的活性,可以轻松回收。

更新日期:2018-12-23
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