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Synthesis of anticorrosion nanohybrid films based on bioinspired dopamine, L-cys/[email protected] through self-assembly on 304 stainless steel in 3.5% NaCl
Bioelectrochemistry ( IF 5 ) Pub Date : 2018-11-30 , DOI: 10.1016/j.bioelechem.2018.11.012
Fatemeh Elmi , Elahe Valipour , Shahram Ghasemi

Nanohybrid films containing multiwalled carbon nanotubes (MWCNTs) were successfully coated on 304-stainless steel (304ss) for anti-corrosion use. The nanocompositewas made by a self-assembly of poly (dopamine), wrapped with MWCNTs ([email protected]) through a mussel inspired method. In order to enhance the corrosion protection, an inner layer of L-cysteine, an adhesive amino acid to 304ss surface through thiol (-SH) functional group were constructed through a dip-coating process. Potentiodynamic polarization measurements and electrochemical impedance spectroscopy revealed that the double nano-layer could act as a noble anticorrosive coating in 3.5% NaCl, which was assigned to the hydrophobicity, robustness, and dense double layer coating.



中文翻译:

通过在3.5%NaCl中在304不锈钢上自组装,基于生物启发的多巴胺L-cys / [受电子邮件保护]合成耐腐蚀纳米复合膜

包含多壁碳纳米管(MWCNT)的纳米复合薄膜已成功地涂覆在304不锈钢(304ss)上以防腐蚀。由聚多巴胺的自组装制成的纳米复合材料,通过贻贝启发法包裹了多壁碳纳米管([受电子邮件保护])。为了增强防腐性能,通过浸涂法构建了L-半胱氨酸的内层,该内层是通过硫醇(-SH)官能团与304ss表面形成粘附性氨基酸。电位动力学极化测量和电化学阻抗谱分析表明,该双层纳米层可在3.5%NaCl中用作高贵的防腐涂层,这可归因于其疏水性,坚固性和致密双层涂层。

更新日期:2018-11-30
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