Electropolymerisation of the novel polyoxotitanate (POT) hexamer [Ti(μ₃-O)(OⁱPr)(TA)]₆ (TA = thiophene-3-acetate) with 3,4-ethylenedioxythiophene (EDOT) gives films of hybrid conjugated copolymer, Poly-(EDOT-POT)s, the morphologies of which are, uniquely, influenced by the electropolymerisation potential. Nanoporous Poly-(EDOT-POT)-1 is a fast-ion electrode material and has improved electrochromic properties and significantly higher capacitance than that of the parent poly(3,4-ethylenedioxythiophene) (PEDOT).

中文翻译：

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基于新型聚氧钛酸酯单体的共轭杂化膜†

新颖polyoxotitanate的电聚合（POT）六聚体钛[Ti（μ ₃ -O）（O^我PR）（TA）] ₆（TA =噻吩-3-醋酸）与3,4-亚乙基（EDOT）给出混合的膜结合共聚物，聚（EDOT-POT），其形态独特地受电聚合势的影响。纳米多孔聚（EDOT-POT）-1是一种快离子电极材料，与母体聚（3,4-乙撑二氧噻吩）（PEDOT）相比，具有改善的电致变色性能和显着更高的电容。