In this paper, a new methodology replacing the typical sequential layer-by-layer immobilization, i.e., simultaneous co-electrodeposition protocol is proven eminent for assembling efficient binary nanoelectrocatalysts for formic acid (FA) electro-oxidation (FAO). This strategy is successful to integrate homogeneously Pt nanoparticles (nano-Pt; essential component for FA adsorption/oxidation) with manganese oxide nanowires (nano-MnOx; a CO poisoning alleviator) in a single blend avoiding the poisoning CO adsorption at the catalyst surface. The molar ratio of the catalyst's ingredients (Pt:Mn) in the deposition bath is critical in identifying the catalyst's composition of the prepared binary catalyst and thus, a molar ratio of (1:8) is optimum yielding the highest catalytic activity. It is believed that adjusting the catalyst's composition could preferably act against the adsorption of poisoning CO intermediate and/or providing an electronic support to the desired (low over potential) direct dehydrogenation pathway of FAO to CO₂.

在本文中，一种新的方法取代了典型的顺序逐层固定，即事实证明，同时共电沉积方案可用于组装甲酸（FA）电氧化（FAO）的高效二元纳米电催化剂。该策略成功地将Pt纳米颗粒（纳米Pt； FA吸附/氧化的基本成分）与氧化锰纳米线（纳米MnOx； CO中毒缓解剂）均匀混合在一起，避免了催化剂表面的CO吸附中毒。沉积浴中催化剂成分的摩尔比（Pt：Mn）对于确定制得的二元催化剂的催化剂组成至关重要，因此（1：8）的摩尔比最适合产生最高的催化活性。据信，调整催化剂₂。