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High-efficiency and stable silicon heterojunction solar cells with lightly fluorinated single-wall carbon nanotube films
Nano Energy ( IF 17.6 ) Pub Date : 2020-01-02 , DOI: 10.1016/j.nanoen.2019.104442
Xian-Gang Hu , Peng-Xiang Hou , Jin-Bo Wu , Xin Li , Jian Luan , Chang Liu , Gang Liu , Hui-Ming Cheng

High-quality single-wall carbon nanotube (SWCNT) films were lightly fluorinated by treatment with xenon difluoride at room temperature, which led to the formation of ionic C-F bonds on tube walls and controllable p-type doping of the nanotubes. The fluorinated SWCNT films showed improved electronic conductivity and a higher work function. In addition, the fluorination process increased the areal density of SWCNT films and decreased their surface roughness, leading to better interface contact between them and silicon. As a result, a heterojunction solar cell constructed using the lightly fluorinated SWCNT film has a high power conversion efficiency of 13.6% and excellent stability.



中文翻译:

带有轻氟化单壁碳纳米管薄膜的高效且稳定的硅异质结太阳能电池

高质量的单壁碳纳米管(SWCNT)薄膜通过在室温下用二氟化氙进行处理而轻微氟化,这导致在管壁上形成离子CF键和可控的p型掺杂。氟化的SWCNT薄膜显示出改善的电子导电性和更高的功函。此外,氟化过程增加了SWCNT薄膜的面密度,并降低了其表面粗糙度,从而导致它们与硅之间的界面接触更好。结果,使用轻氟化的SWCNT膜构造的异质结太阳能电池具有13.6%的高功率转换效率和优异的稳定性。

更新日期:2020-01-02
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