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Microstructures and mechanical properties of high-entropy (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C ceramics with the addition of SiC secondary phase
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2020-01-02 , DOI: 10.1016/j.jeurceramsoc.2019.12.056
Kuan Lu , Ji-Xuan Liu , Xiao-Feng Wei , Weichao Bao , Yue Wu , Fei Li , Fangfang Xu , Guo-Jun Zhang

The relationships between microstructures and mechanical properties especially strength and toughness of high-entropy carbide based ceramics are reported in this article. Dense (Ti0.2Zr0.2Hf0.2Nb0.2Ta0.2)C (HEC) and its composite containing 20 vol.% SiC (HEC-20SiC) were prepared by spark plasma sintering. The addition of SiC phase enhanced the densification process, resulting in the promotion of the formation of the single-phase high-entropy carbide during sintering. The high-entropy carbide phase demonstrated a fast grain coarsening but SiC particles remarkably inhibited this phenomena. Dense HEC and HEC-20SiC ceramics sintered at 1900 °C exhibits four-point bending strength of 332 ± 24 MPa and 554 ± 73 MPa, and fracture toughness of 4.51 ± 0.61 MPa·m1/2 and 5.24 ± 0.41 MPa·m1/2, respectively. The main toughening mechanism is considered to be crack deflection by the SiC particles.



中文翻译:

添加SiC二次相的高熵(Ti 0.2 Zr 0.2 Hf 0.2 Nf 0.2 Nb 0.2 Ta 0.2)C陶瓷的组织和力学性能。

本文报道了高熵碳化物基陶瓷的微观结构与机械性能之间的关系,特别是强度和韧性。致密(Ti 0.2 Zr 0.2 Hf 0.2 Nb 0.2 Ta 0.2通过火花等离子体烧结制备C(HEC)及其包含20vol。%SiC的复合材料(HEC-20SiC)。SiC相的添加增强了致密化过程,从而促进了烧结过程中单相高熵碳化物的形成。高熵碳化物相显示出快速的晶粒粗化,但是SiC颗粒显着抑制了这种现象。在1900°C烧结的致密HEC和HEC-20SiC陶瓷的四点弯曲强度分别为332±24 MPa和554±73 MPa,断裂韧性为4.51±0.61 MPa·m 1/2和5.24±0.41 MPa·m 1 / 2。认为主要的增韧机理是SiC颗粒引起的裂纹挠曲。

更新日期:2020-01-02
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