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Selective rhodamine–based probe for detecting Hg2+ and its application as test strips and cell staining
Journal of Photochemistry and Photobiology A: Chemistry ( IF 4.3 ) Pub Date : 2019-12-28 , DOI: 10.1016/j.jphotochem.2019.112302
Yuesong Wang , Haichang Ding , Zifan Zhu , Congbin Fan , Yayi Tu , Gang Liu , Shouzhi Pu

A novel probe 1 for detection of Hg2+ based on rhodamine platform was developed. The probe showed a high selectivity and anti–interference capability toward Hg2+ even in the presence of other metal ions (except Cu2+) in CH3CN–H2O (7/3, v/v) solution, and the low detection limits of 0.12 μM and 0.38 μM by using absorbance and fluorescence methods, respectively. Moreover, the mechanism of detecting Hg2+ was demonstrated due to the probe hydrolyzed to rhodamine acid in the presence of Hg2+ and exhibited a characteristic absorption band at 554 nm, which was recognized via the “naked–eye”. Noticeably, the probe was successfully applied to cell staining and the colorimetric detection for Hg2+ could realize by the test strips.



中文翻译:

用于检测Hg 2+的基于罗丹明的选择性探针及其在试纸和细胞染色中的应用

开发了基于罗丹明平台的新型Hg 2+探针1。即使在CH 3 CN–H 2 O(7/3,v / v)溶液中存在其他金属离子(Cu 2+除外)的情况下,该探针也对Hg 2+具有很高的选择性和抗干扰能力。通过使用吸光度法和荧光法分别可实现0.12μM和0.38μM的低检测限。此外,检测汞的机理2+是由于在汞的存在下水解成酸罗丹明探针证实2+和在554纳米,将其识别表现出特征吸收带通过“裸眼”。值得注意的是,该探针已成功应用于细胞染色,并且通过试纸条可以实现Hg 2+的比色检测。

更新日期:2019-12-28
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