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Experimental complemented with microscopic (electronic/atomic)-level modeling explorations of Laurus nobilis extract as green inhibitor for carbon steel in acidic solution
Journal of Industrial and Engineering Chemistry ( IF 6.1 ) Pub Date : 2020-04-01 , DOI: 10.1016/j.jiec.2019.12.019
Ali Dehghani , Ghasem Bahlakeh , Bahram Ramezanzadeh , Mohammad Ramezanzadeh

Abstract In the present study, comprehensive research efforts were made to experimentally/theoretically examine the corrosion protection capability of Laurus nobilis leaves extract for carbon steel in an acidic medium composed of 1 M HCl. The experimental EIS results evidenced that upon steel exposure to a corrosive electrolyte containing 400 ppm L. nobilis leaves extract the maximum protection performance of 92% was obtained after 2.5 h. The experiments of potentiodynamic polarization proposed a mixed-type anodic/cathodic anti-corrosion action along with small cathodic prevalence. The electronic features established by the DFT approach highlighted that the surface adsorption mechanism could be described by donor-acceptor interactions.

中文翻译:

实验补充了月桂提取物作为酸性溶液中碳钢绿色抑制剂的微观(电子/原子)级建模探索

摘要 在本研究中,综合研究工作从实验/理论上检验了月桂叶提取物在由 1 M HCl 组成的酸性介质中对碳钢的腐蚀保护能力。实验 EIS 结果证明,当钢暴露于含有 400 ppm L. nobilis 叶提取物的腐蚀性电解质时,2.5 小时后可获得 92% 的最大保护性能。动电位极化实验提出了混合型阳极/阴极防腐作用,同时阴极发生率很小。DFT 方法建立的电子特征突出表明,表面吸附机制可以通过供体 - 受体相互作用来描述。
更新日期:2020-04-01
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