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Building up of Prosopis juliflora carbon incorporated cardanol based polybenzoxazine composites with intensification of mechanical and corrosion resistance properties for adaptable applications
Polymer Bulletin ( IF 3.2 ) Pub Date : 2019-12-23 , DOI: 10.1007/s00289-019-03084-4
V. Selvaraj , T. R. Raghavarshini

In the present work, amine-functionalized Prosopis juliflora carbon (APJC)-reinforced diphenyldiaminomethane-based cardanol benzoxazine (DDCBz) composites have been developed and characterized with a view to utilizing them for possible load-bearing and corrosion-resistant applications. Chemical structure of the DDCBz was ascertained using Fourier transform infrared, Proton nuclear magnetic resonance and Maldi mass spectroscopy. The 5 wt% APJC/DDCBz composites exhibit good hydrophobic character, thermal stability and mechanical properties compared to those of neat matrix and other wt% of APJC-reinforced composites. Similarly, glass transition temperature (Tg) and water contact angle of composites are enhanced according to their weight percentage concentration. Results from corrosion studies indicate that the mild steel specimens coated with DDCBz matrix and APJC/DDCBz composites offer enhanced corrosion resistance. Data obtained from different studies infer that the APJC-reinforced DDCBz composites possess an improved thermal stability, thermomechanical behaviour, hydrophobic characteristics and corrosion-resistant properties, which make them suitable for high-performance thermal and corrosion-resistant applications.

中文翻译:

构建具有增强机械和耐腐蚀性能以适用于适应性应用的腰果酚基聚苯并恶嗪复合材料

在目前的工作中,已经开发并表征了胺官能化的胡杨碳(APJC)增强的二苯基二氨基甲烷基腰果酚苯并恶嗪(DDCBz)复合材料,以期将它们用于可能的承重和耐腐蚀应用。使用傅立叶变换红外光谱、质子核磁共振和马尔迪质谱法确定了 DDCBz 的化学结构。与纯基体和其他重量百分比的 APJC 增强复合材料相比,5 重量百分比的 APJC/DDCBz 复合材料表现出良好的疏水特性、热稳定性和机械性能。类似地,复合材料的玻璃化转变温度 (Tg) 和水接触角根据其重量百分比浓度而提高。腐蚀研究结果表明,涂​​有 DDCBz 基体和 APJC/DDCBz 复合材料的低碳钢试样具有增强的耐腐蚀性。从不同研究中获得的数据推断,APJC 增强的 DDCBz 复合材料具有改进的热稳定性、热机械行为、疏水特性和耐腐蚀特性,这使其适用于高性能的耐热和耐腐蚀应用。
更新日期:2019-12-23
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