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Degradation of indigo carmine by coupling Fe(II)-activated sodium persulfate and ozone in a rotor-stator reactor
Chemical Engineering and Processing: Process Intensification ( IF 4.3 ) Pub Date : 2019-12-23 , DOI: 10.1016/j.cep.2019.107791
Ziye Zhao , Lei Wang , Jinmeng Fan , Yunhua Song , Guangwen Chu , Lei Shao

Rotor-stator reactor (RSR), a novel high-gravity device, was employed in the O3/persulfate (PS)/Fe2+ process to enhance the degradation of indigo carmine (IC) in simulated wastewater. It was found that IC degradation efficiency increased with the increase of Fe2+ concentration, RSR rotation speed, O3 concentration and gas-liquid ratio, but decreased with the increase of IC concentration and temperature. When the rotation speed of RSR increased from zero to 1200 rpm, IC degradation efficiency increased from 25.6% to 64.2%. Because of the synergetic effects of the oxidative species (O3, radical dotOH, SO4radical dot etc.), IC degradation efficiency in the O3/PS/Fe2+ process was significantly higher than that in the O3 or PS/Fe2+ process. The high IC degradation efficiency can also be attributed to the good micromixing effect of the RSR. When the O3/PS/Fe2+ process in the RSR was adopted before the sequencing batch reactor activated sludge process, both IC and COD degradation efficiencies increased significantly as a result of the improved biodegradability of the IC wastewater. Furthermore, a possible degradation mechanism of IC in the O3/PS/Fe2+ process was proposed.



中文翻译:

在转子-定子反应器中偶合Fe(II)活化的过硫酸钠和臭氧降解靛蓝胭脂红

O 3 /过硫酸盐(PS)/ Fe 2+工艺中采用了新型的高重力装置转子-定子反应器(RSR),以增强模拟废水中靛蓝胭脂红(IC)的降解。结果表明,随着Fe 2+浓度,RSR转速,O 3浓度和气液比的增加,IC降解效率增加,但随着IC浓度和温度的升高IC降解效率降低。当RSR的转速从零增加到1200 rpm时,IC降级效率从25.6%增加到64.2%。由于氧化性物质的协同效应(O的3激进点OH,SO 4 -激进点在O,IC降解效率等)3/ PS / Fe 2+工艺显着高于O 3或PS / Fe 2+工艺。高IC降解效率还可以归因于RSR的良好微混合效果。当在测序间歇反应器活性污泥工艺之前采用RSR中的O 3 / PS / Fe 2+工艺时,由于提高了IC废水的生物降解性,IC和COD的降解效率均显着提高。此外,提出了在O 3 / PS / Fe 2+工艺中IC可能的降解机理。

更新日期:2019-12-23
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