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Bioinspired, ATP-driven co-operative supramolecular polymerization and its pathway dependence.
Chemical Communications ( IF 4.9 ) Pub Date : 2020-01-09 , DOI: 10.1039/c9cc08790g
Ananya Mishra 1 , Divya B Korlepara , Sundaram Balasubramanian , Subi J George
Affiliation  

A bio-inspired, ATP-driven nucleation growth assembly is demonstrated using an amphiphilic naphthalene diimide (NDI) derivative appended with guanidinium receptors to promote specific salt-bridge type interaction with nucleotide phosphates. Detailed spectroscopic and microscopic probing revealed a pathway-dependent co-operative self-assembly to yield two-dimensional and scrolled nano-tubular bilayer assemblies under kinetic and thermodynamic conditions, respectively.

中文翻译:

受生物启发的,ATP驱动的合作性超分子聚合及其途径依赖性。

使用两亲萘二酰亚胺(NDI)衍生物和胍盐受体来促进与核苷酸磷酸的特异性盐桥型相互作用,证明了具有生物启发性的ATP驱动的成核生长组件。详细的光谱和显微镜探测揭示了依赖于途径的协同自组装,分别在动力学和热力学条件下产生二维和滚动的纳米管双层组件。
更新日期:2020-01-09
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