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Synthesis of 2-alkenylfurans via a Ag(i)-catalyzed tandem cyclization/cross-coupling reaction of enynones with iodonium ylides.
Chemical Communications ( IF 4.9 ) Pub Date : 2020-01-08 , DOI: 10.1039/c9cc08561k
Haiyun Peng 1 , Yinbo Wan , Yu Zhang , Guisheng Deng
Affiliation  

A silver(i)-catalyzed tandem cyclization/cross-coupling reaction of enynones with iodonium ylides to construct carbon-carbon double bonds has been developed. The strategy provides a novel method for the synthesis of 2-alkenylfurans. This is the first cross-coupling reaction between metal-carbene complexes and iodonium ylides.

中文翻译:

通过Ag(i)催化的烯酮与碘鎓碘化物的串联环化/交叉偶联反应合成2-烯基呋喃。

已经开发了银(i)催化的烯酮与碘鎓碘化物的串联环化/交叉偶联反应,以构建碳-碳双键。该策略提供了合成2-链烯基呋喃的新颖方法。这是金属-卡宾配合物与碘鎓碘化物之间的第一个交叉偶联反应。
更新日期:2020-01-08
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