当前位置: X-MOL 学术Metall. Mater. Trans. A. › 论文详情
Nanocrystalline NiWO 4 -WO 3 -WO 2.9 Composite Strings: Fabrication, Characterization and their Electrocatalytic Performance for Hydrogen Evolution Reaction
Metallurgical and Materials Transactions A ( IF 1.985 ) Pub Date : 2019-12-19 , DOI: 10.1007/s11661-019-05596-0
Shaheen Fatima Anis, Ahmad O. Mostafa, Nidal Hilal, Raed Hashaikeh

In this study, novel nano crystalline composite strings made from mixed nickel-tungsten oxides (NiWO4-WO3-WO2.9) have been fabricated. The NiWO4-WO3 fibers produced by the electrospinning method were post treated in an argon atmosphere at 800 °C which yielded NiWO4-WO3-WO2.9 nanocrystals attached together forming a string-like structure. The presence of WO2.9 phase was confirmed by both the XRD and TEM diffraction pattern analysis. String morphology and structure were found to change with different post treatment conditions such as by changing the calcination temperature from 550 °C under oxygen to 800 °C under pure argon atmosphere. This material was investigated for electrocatalytic hydrogen evolution reaction (HER) in 0.5 M H2SO4 and 0.1 M KOH electrolytes. These composite strings showed good electrocatalytic activity compared to the NiWO4-WO3 fibers reported previously (Anis et al. in J. Mater. Sci. 52:7269–7281, 2017). It was concluded that the presence of WO2.9 phase increases the electrocatalytic activity of the catalyst as compared to the NiWO4-WO3 fibers with overpotentials as low as 40 and 50 mV in 0.5 M H2SO4 and 0.1 M KOH, respectively.
更新日期:2019-12-19

 

全部期刊列表>>
化学/材料学中国作者研究精选
ACS材料视界
南京大学
自然科研论文编辑服务
剑桥大学-
中国科学院大学化学科学学院
南开大学化学院周其林
课题组网站
X-MOL
北京大学分子工程苏南研究院
华东师范大学分子机器及功能材料
中山大学化学工程与技术学院
试剂库存
天合科研
down
wechat
bug