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Synthesis and structure of a new complex of mercury(II) with an organoantimony ligand – tris(2,6-dimethoxyphenyl)stibane
Journal of Organometallic Chemistry ( IF 2.3 ) Pub Date : 2019-12-17 , DOI: 10.1016/j.jorganchem.2019.121077
Irina Egorova , Vladimir Zhidkov , Irina Zubakina , Natalya Rodionova , Ilia Eltsov

The new heterometallic complex [HgI2(SbAr3)], Ar = 2,6-(MeО)2C6H3 has been obtained by the interaction of tris(2,6-dimethoxyphenyl)antimony with mercury(II) iodide. SbAr3 and [HgI2(SbAr3)] have been characterized using single crystal X-ray diffraction. Structures of them are compared. Elemental analysis, IR and NMR spectroscopies have also been used for characterization.



中文翻译:

新型汞(II)与有机锑配体–三(2,6-二甲氧基苯基)二b烷的合成与结构

通过三(2,6-二甲氧基苯基)锑与碘化汞(II)的相互作用,获得了新的杂金属配合物[HgI 2(SbAr 3)],Ar = 2,6-(MeО)2 C 6 H 3。使用单晶X射线衍射对SbAr 3和[HgI 2(SbAr 3)]进行了表征。比较它们的结构。元素分析,IR和NMR光谱也已用于表征。

更新日期:2019-12-18
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