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Superior efficient rechargeable lithium–air batteries using a bifunctional biological enzyme catalyst
Energy & Environmental Science ( IF 32.5 ) Pub Date : 2019/12/17 , DOI: 10.1039/c9ee02652e
Linlin Wang 1, 2, 3, 4, 5 , Yarong Wang 6, 7, 8, 9 , Yu Qiao 6, 7, 8, 9 , Shichao Wu 6, 7, 8, 9 , Xuanzhao Lu 1, 2, 3, 4, 5 , Jun-Jie Zhu 1, 2, 3, 4, 5 , Jian-Rong Zhang 1, 2, 3, 4, 5 , Haoshen Zhou 1, 2, 3, 4, 5
Affiliation  

A biological enzyme – Laccase from Trametes versicolor (LacTv) – has been recognized as a highly efficient bifunctional catalyst in a rechargeable lithium–air battery system whose intrinsic pH change during discharge/charge can regulate the in situ recovery of the enzyme, making them an in situ synergistic match, enabling the battery to offer an extraordinarily flat discharge voltage of ∼3.75 V for 120 h, and remarkable durability (cycling steadily over 1100 h) with a narrow voltage gap of ∼0.24 V.

中文翻译:

使用双功能生物酶催化剂的优质高效可充电锂空气电池

一种生物酶-云芝(trametes versicolor)(LacTv)的漆酶-被认为是可充电锂-空气电池系统中的高效双功能催化剂,其在放电/充电过程中固有的pH变化可以调节酶的原位回收,使其成为原位协同匹配,使电池能够在120小时内提供约3.75 V的超平放电电压,并以约0.24 V的窄电压间隙提供出色的耐用性(稳定循环1100 h以上)。
更新日期:2020-02-13
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