Reactive & Functional Polymers ( IF 5.1 ) Pub Date : 2019-12-17 , DOI: 10.1016/j.reactfunctpolym.2019.104456 Shengjin Yan , Qing An , Ling Xia , Shuang Liu , Shaoxian Song , Jose René Rangel-Méndez
The porous La(III)- montmorillonite hydrogel beads (La-MMT_hb) with stable structure were fabricated via hydrogen-bond and electrostatic interactions for arsenic removal from water. The structural characteristics of La-MMT_hb and its sorption performances for As(V) were evaluated. The results showed that porous La-MMT_hb were clearly observed by scanning electron microscopy, and the addition of lanthanum significantly increased the specific surface area. The maximum adsorption capacity of La-MMT_hb for As(V) was 58.75 mg/g, reached within 4 h, at the optimum pH of 4 with optimum La dosage of 1%. The mechanism of adsorption can be attributed to the electrostatic forces between La(III) and H2AsO4− at pH 4, ion exchange of OH groups on the surface of adsorbent with H2AsO4− and complex chelate formation as.-NH3-H2AsO4 and -La-O-As.
中文翻译:
使用La(III)-蒙脱土水凝胶珠从水中去除As(V)
通过氢键和静电作用制备了具有稳定结构的多孔La(III)-蒙脱土水凝胶珠(La-MMT_hb),以去除水中的砷。评价了La-MMT_hb的结构特征及其对As(V)的吸附性能。结果显示,通过扫描电子显微镜清楚地观察到多孔La-MMT_hb,并且镧的添加显着增加了比表面积。La-MMT_hb对As(V)的最大吸附容量为58.75 mg / g,在4的最佳pH和1%的最佳La剂量下,在4小时内达到最大吸附容量。吸附的机理可以在La(III)和H之间归因于静电力2 ASO 4 -在pH 4,O的离子交换吸附剂具有H的表面上H基2 ASO 4 -和复杂的螯合形成as.-NH 3 -H 2 ASO 4和-La-O-为。