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As(V) removal from water using the La(III)- Montmorillonite hydrogel beads
Reactive & Functional Polymers ( IF 5.1 ) Pub Date : 2019-12-17 , DOI: 10.1016/j.reactfunctpolym.2019.104456
Shengjin Yan , Qing An , Ling Xia , Shuang Liu , Shaoxian Song , Jose René Rangel-Méndez

The porous La(III)- montmorillonite hydrogel beads (La-MMT_hb) with stable structure were fabricated via hydrogen-bond and electrostatic interactions for arsenic removal from water. The structural characteristics of La-MMT_hb and its sorption performances for As(V) were evaluated. The results showed that porous La-MMT_hb were clearly observed by scanning electron microscopy, and the addition of lanthanum significantly increased the specific surface area. The maximum adsorption capacity of La-MMT_hb for As(V) was 58.75 mg/g, reached within 4 h, at the optimum pH of 4 with optimum La dosage of 1%. The mechanism of adsorption can be attributed to the electrostatic forces between La(III) and H2AsO4 at pH 4, ion exchange of Osingle bondH groups on the surface of adsorbent with H2AsO4 and complex chelate formation as.-NH3-H2AsO4 and -La-O-As.



中文翻译:

使用La(III)-蒙脱土水凝胶珠从水中去除As(V)

通过氢键和静电作用制备了具有稳定结构的多孔La(III)-蒙脱土水凝胶珠(La-MMT_hb),以去除水中的砷。评价了La-MMT_hb的结构特征及其对As(V)的吸附性能。结果显示,通过扫描电子显微镜清楚地观察到多孔La-MMT_hb,并且镧的添加显着增加了比表面积。La-MMT_hb对As(V)的最大吸附容量为58.75 mg / g,在4的最佳pH和1%的最佳La剂量下,在4小时内达到最大吸附容量。吸附的机理可以在La(III)和H之间归因于静电力2 ASO 4 -在pH 4,O的离子交换单键吸附剂具有H的表面上H基2 ASO 4 -和复杂的螯合形成as.-NH 3 -H 2 ASO 4和-La-O-为。

更新日期:2019-12-17
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