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Rhodium(III)‐Catalyzed Direct C−H Alkylation of Ferrocenes with Diazo Compounds under Weakly Coordinating Approach
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2020-01-07 , DOI: 10.1002/adsc.201901193
Lulu Zhang 1 , Jiakai Zhao 1 , Qi Mou 1 , Dawei Teng 1 , Xiangtai Meng 2 , Bo Sun 1
Affiliation  

An efficient synthesis of ferrocene derivatives via rhodium(III)‐catalyzed direct C−H alkylation with diazo compounds under weakly coordinating group has been presented. This protocol provides an approach towards access to various ferrocene derivatives using carboxamides, giving alkylated ferrocenes in high yields (up to 87%).

中文翻译:

弱配位法铑(III)催化二茂铁与重氮化合物直接CH烷基化

提出了在弱配位基团下通过重氮与重氮化合物催化的铑(III)催化直接CH烷基化反应有效合成二茂铁衍生物的方法。该方案提供了一种使用羧酰胺获得各种二茂铁衍生物的方法,可以高产率(高达87%)获得烷基化的二茂铁。
更新日期:2020-01-07
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