当前位置：
X-MOL 学术
›
Eur. J. Org. Chem.
›
论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Stepwise Preparation of meso‐Tetraphenyl‐ and meso‐Tetrakis(4‐trifluoromethylphenyl)bacteriodilactones and their Zinc(II) and Palladium(II) Complexes
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-01-21 , DOI: 10.1002/ejoc.201901727 Christian Brückner 1 , Adewole O. Atoyebi 1 , Derek Girouard 1 , Kimberly S. F. Lau 1, 2 , Joshua Akhigbe 1 , Lalith Samankumara 1 , Dinusha Damunupola 1 , Gamal E. Khalil 2 , Martin Gouterman 2 , Jeanette A. Krause 3 , Matthias Zeller 4
European Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-01-21 , DOI: 10.1002/ejoc.201901727 Christian Brückner 1 , Adewole O. Atoyebi 1 , Derek Girouard 1 , Kimberly S. F. Lau 1, 2 , Joshua Akhigbe 1 , Lalith Samankumara 1 , Dinusha Damunupola 1 , Gamal E. Khalil 2 , Martin Gouterman 2 , Jeanette A. Krause 3 , Matthias Zeller 4
Affiliation
|
Stepwise oxidations of meso‐tetraphenyl or meso‐tetrakis(4‐trifluoromethylphenyl)‐porphyrin provide the corresponding bacteriodilactones, as mixtures of two inseparable regioisomers. The ratio of the two isomers is oxidant‐dependent. Examples of the free base dilactones and their metal complexes were also crystallographically characterized.
中文翻译：
分步制备中四苯基和中四（4-三氟甲基苯基）细菌二内酯及其锌（II）和钯（II）配合物
介孔-四苯基或介孔-四（4-三氟甲基苯基）-卟啉的逐步氧化可提供相应的细菌二内酯，这是两种不可分离的区域异构体的混合物。两种异构体的比例取决于氧化剂。游离碱双内酯及其金属配合物的实例也通过晶体学表征。
更新日期：2020-01-22
中文翻译：
分步制备中四苯基和中四（4-三氟甲基苯基）细菌二内酯及其锌（II）和钯（II）配合物
介孔-四苯基或介孔-四（4-三氟甲基苯基）-卟啉的逐步氧化可提供相应的细菌二内酯，这是两种不可分离的区域异构体的混合物。两种异构体的比例取决于氧化剂。游离碱双内酯及其金属配合物的实例也通过晶体学表征。
京公网安备 11010802027423号