The phthalocyanines were synthesized via phthalonitrile cyclotetramerization in the presence of lithium metal and/or zinc acetate in this study. New symmetric peripheral-tetra and non-peripheral-tetra substituted phthalocyanines were substituted with N-Boc-ethanolamine. All newly synthesized phthalocyanines and starting materials were characterized by spectroscopic methods such as FT-IR, MALDI-TOF, ¹H-NMR and UV–vis. Non-peripheral (3, 5, 5′) and peripheral (4, 4′, 6) phthalocyanine derivatives were determined aggregation, photophysical properties (such as fluorescence quantum yields and lifetimes) and photochemical properties (such as singlet oxygen generation and photostability) in dimethylsulfoxide (DMSO).

在这项研究中，在金属锂和/或乙酸锌的存在下，通过苯甲腈环四聚反应合成了酞菁。用N-Boc-乙醇胺取代新的对称的周边四和非周边四取代的酞菁。所有新合成的酞菁和起始原料均通过光谱法进行了表征，例如FT-IR，MALDI-TOF，¹ H-NMR和UV-vis。非外围（3，5，5' ）和外围设备（4，4' ，6）测定了二甲基亚砜（DMSO）中的酞菁衍生物的聚集，光物理性质（例如荧光量子产率和寿命）和光化学性质（例如单线态氧的产生和光稳定性）。