Herein, recent developments of metal-organic frameworks (MOFs) structured into nanofibers by electrospinning are summarized, including the fabrication, post-treatment via pyrolysis, properties, and use of the resulting MOF nanofiber architectures. The fabrication and post-treatment of the MOF nanofiber architectures are described systematically by two routes: i) the direct electrospinning of MOF-polymer nanofiber composites, and ii) the surface decoration of nanofiber structures with MOFs. The unique properties and performance of the different types of MOF nanofibers and their derivatives are explained in respect to their use in energy and environmental applications, including air filtration, water treatment, gas storage and separation, electrochemical energy conversion and storage, and heterogeneous catalysis. Finally, challenges with the fabrication of MOF nanofibers, limitations for their use, and trends for future developments are presented.

中文翻译：

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用于能源和环境应用的金属有机框架的静电纺丝。

本文总结了通过静电纺丝构建纳米纤维的金属有机框架（MOF）的最新进展，包括所得 MOF 纳米纤维结构的制造、热解后处理、性能和用途。通过两种途径系统地描述了 MOF 纳米纤维结构的制造和后处理：i）MOF-聚合物纳米纤维复合材料的直接静电纺丝，以及 ii）用 MOF 纳米纤维结构的表面装饰。不同类型的 MOF 纳米纤维及其衍生物的独特性质和性能在能源和环境应用中的应用得到解释，包括空气过滤、水处理、气体储存和分离、电化学能量转换和储存以及多相催化。最后，介绍了 MOF 纳米纤维制造的挑战、其使用的限制以及未来的发展趋势。