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Microwave-promoted solvent-free synthesis of para-quinone methides (p-QMs) derivatives
Journal of Saudi Chemical Society ( IF 5.6 ) Pub Date : 2019-11-06 , DOI: 10.1016/j.jscs.2019.10.001 Zhang-Qin Liu , Peng-Sheng You , Chuan-Hua Wu , Yang-Hong Han
中文翻译:
微波促进的无溶剂合成对醌甲基化物(p -QMs)衍生物
更新日期:2019-11-06
Journal of Saudi Chemical Society ( IF 5.6 ) Pub Date : 2019-11-06 , DOI: 10.1016/j.jscs.2019.10.001 Zhang-Qin Liu , Peng-Sheng You , Chuan-Hua Wu , Yang-Hong Han
A rapid and efficient methodology for the synthesis of polysubstituted para-quinone methides (p-QMs) from aldehyde and 2,6-di-tert-butylphenol has been achieved in solvent-free and microwave irradiation condition within 33 min. This strategy displays the advantages including high atom economy, good functional group tolerance, and environmentally friendly operation.
中文翻译:
微波促进的无溶剂合成对醌甲基化物(p -QMs)衍生物
在33分钟内无溶剂和微波辐射的条件下,已经实现了从醛和2,6-二叔丁基苯酚合成多取代对苯醌甲基化物(p -QMs)的快速有效方法。该策略显示出以下优点:高原子经济性,良好的官能团耐受性和环保操作。