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Interaction of perfluoropolyether peroxide PFPEP-4 with polyfluoroaromatic compounds
Russian Chemical Bulletin ( IF 1.7 ) Pub Date : 2019-10-01 , DOI: 10.1007/s11172-019-2645-6
A. A. Glazkov , A. A. Yarosh , A. M. Sakharov

The interaction of perfluoropolyether peroxides with perfluoro- and polyfluoroaromatic compounds (C6F6, C6F5H, C6F5Cl, and C6F5CF3) was investigated. It was found that branched and cross-linked perfluoropolymers with a glass transition temperature below −110 °C and the destruction onset temperature 400 °C were generated under the thermolysis of perfluoropolyperoxides and polyfluorinated aromatic compounds at 280–290 °C. DSC and DTGA data were provided.

中文翻译:

全氟聚醚过氧化物 PFPEP-4 与多氟芳族化合物的相互作用

研究了全氟聚醚过氧化物与全氟和多氟芳族化合物(C6F6、C6F5H、C6F5Cl 和 C6F5CF3)的相互作用。研究发现,在全氟聚过氧化物和多氟芳族化合物在 280-290°C 下热解时,生成了玻璃化转变温度低于 -110°C 且破坏起始温度为 400°C 的支化和交联的全氟聚合物。提供了 DSC 和 DTGA 数据。
更新日期:2019-10-01
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