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Relative Reactivity of Dicyclopentadiene and 2,3-Dicarbomethoxy-5-norbornene in Metathesis Copolymerization and the Properties of the Copolymer
Polymer Science, Series C ( IF 2.2 ) Pub Date : 2019-11-01 , DOI: 10.1134/s1811238219010119
A. A. Lyapkov , G. S. Bozhenkova , N. A. Smirnova , N. I. Prokudina , M. S. Yusubov , F. Verpoort

Abstract

In this paper, Fourier transform infrared spectroscopy (FTIR) was applied to examine the metathesis copolymerization of dicyclopentadiene with a mixture of exo,exo- and endo,endo-2,3-dicarbomethoxy-5-norbornene using a Hoveyda-Grubbs II type catalyst. The obtained data allowed us to calculate the monomer reactivity ratios of dicyclopentadiene and the isomers of 2,3-dicarbomethoxy-5-norbornenes. The relative reactivity of dicyclopentadiene was around eight times lower than the reactivity of the isomer mixtures.



中文翻译:

二环戊二烯与2,3-二碳甲氧基-5-降冰片烯在复分解共聚中的相对反应及其性能

抽象的

本文采用傅里叶变换红外光谱法(FTIR),使用Hoveyda-Grubbs II型催化剂研究了双环戊二烯与外,内,外,内,内,2,3-二苯甲氧基-5-降冰片烯的混合物的复分解共聚反应。 。获得的数据使我们能够计算二环戊二烯的单体反应率和2,3-二苯甲氧基-5-降冰片烯的异构体。二环戊二烯的相对反应性比异构体混合物的反应性低约八倍。

更新日期:2019-11-01
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