Abstract

Polymers containing oligoether groups, amino acid fragments, and luminophore complexes of iridium(III) in side chains are synthesized by metathesis polymerization. The photophysical properties of the compounds obtained are studied. The iridium-containing copolymers show intense green, blue-green, and red photoluminescence, and the color is determined by the nature of the iridium(III) complexes contained in polymeric emitters. Polymeric products are soluble in water and form micelles with average sizes of 19–54 nm. The cytotoxicity of the polymers with respect to A431 human epidermoid carcinoma cells is determined.

中文翻译：

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基于降冰片烯和7-氧杂-降冰片烯单体的含铱聚合物：合成及其光物理和生物学特性

抽象的

通过易位聚合合成在侧链中含有低聚醚基，氨基酸片段和铱（III）发光体络合物的聚合物。研究了所得化合物的光物理性质。含铱共聚物显示出强烈的绿色，蓝绿色和红色光致发光，其颜色取决于聚合物发射体中所含铱（III）配合物的性质。聚合产物可溶于水，并形成平均尺寸为19–54 nm的胶束。确定了聚合物对A431人表皮样癌细胞的细胞毒性。