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Poly(1,6-heptadiyne)/ABS functionalized microfibers for hydrophobic applications
Journal of Polymer Research ( IF 2.8 ) Pub Date : 2019-12-11 , DOI: 10.1007/s10965-019-1981-4
Pawan Kumar , Prakash M. Gore , RaviPrakash Magisetty , Balasubramanian Kandasubramanian , Raja Shunmugam

We report an electrospun & thermally stable micro-fibers of poly(1,6-heptadiyne) (PHD), modified with ABS. Developed micro-fibers demonstrated hydrophobicity (WCA~145o ± 2o), and exhibited hierarchical surface morphology (confirmed by FESEM analysis). Simulation study showed Chi parameter i.e. χc = 7.88, & free energy of mixing i.e. 4.67 kcal/mol, thereby demonstrating its feasibility for electrospinning. PHD/ABS microfibers demonstrated low ice-adhesion ability, where, it effectively removed frozen water droplets in 8 s from hydrophobic surface, under an air-stream rate of 78 kPa/s. High thermal stability (200 °C), hydrophobicity and low ice-adhesion ability, demonstrate that PHD/ABS microfibers can be effectively used for multifunctional engineering/industrial applications.

Fabrication of poly (1,6-heptadiyne)/ABS microfibers via electrospinning.



中文翻译:

聚(1,6-庚二炔)/ ABS功能化超细纤维,用于疏水性应用

我们报告了用ABS改性的聚(1,6-庚二炔)(PHD)的电纺和热稳定微纤维。发达的微纤维表现出疏水性(WCA〜145 o  ±2 o),并表现出分层的表面形态(通过FESEM分析证实)。模拟研究表明驰参数即χ Ç = 7.88,混合自由能为4.67kcal / mol,从而证明了其静电纺丝的可行性。PHD / ABS超细纤维显示出低的冰粘附能力,在78 kPa / s的气流速率下,PHD / ABS超细纤维可在8 s内有效地从疏水表面去除冷冻的水滴。高热稳定性(200°C),疏水性和低冰粘附能力证明PHD / ABS超细纤维可有效地用于多功能工程/工业应用。

通过静电纺丝制造聚(1,6-庚二炔)/ ABS超细纤维。

更新日期:2019-12-11
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