当前位置: X-MOL 学术Chinese. J. Polym. Sci. › 论文详情
Studies on Rheological, Thermal, and Mechanical Properties of Polylactide/Methyl Methacrylate-Butadiene-Styrene Copolymer/Poly(propylene carbonate) Polyurethane Ternary Blends
Chinese Journal of Polymer Science ( IF 2.804 ) Pub Date : 2019-06-20 , DOI: 10.1007/s10118-019-2276-2
Ji-Li Zhao, Hong-Wei Pan, Hui-Li Yang, Jun-Jia Bian, Hui-Liang Zhang, Ge Gao, Li-Song Dong

Polylactide (PLA), methyl methacrylate-butadiene-styrene copolymer (MBS), and poly(propylene carbonate) polyurethane (PPCU) were blended and subjected to blown film process. The rheological, mechanical, morphological, thermal, and crystalline properties of the PLA/MBS/PPCU ternary blends and the mechanical properties of the resulting films were studied. Results of mechanical test showed that PPCU and MBS could synergistically toughen PLA. The impact strength of 50/10/40 PLA/MBS/PPCU blend (74.7 kJ/m2) was about 7.5 times higher than that of the neat PLA (10.8 kJ/m2), and the elongation at break of 50/10/40 PLA/MBS/PPCU blend (276.5%) was higher by about 45 times that of PLA (6.2%). The tear strength of PLA/MBS/PPCU films was 20 kN/m higher than that of PLA, and the elongation at break (MD/TD) of 50/10/40 PLA/MBS/PPCU films was 271.1%/222.3%, whereas that of PLA was only 2.7%/3.0%. POM observations displayed that the density of spherulite nucleation increased and the size of crystalline particles decreased with the addition of MBS. With increasing PPCU content from 5% to 20%, the density of spherulite nucleation increased and the size of crystalline particles decreased continuously, but the nucleation density of spherulites was slightly lowered with increasing PPCU content from 30% to 40%. The PLA/MBS/PPCU films exhibited excellent mechanical properties, which expanded the application range of these biodegradable films.
更新日期:2019-12-11

 

全部期刊列表>>
化学/材料学中国作者研究精选
Springer Nature 2019高下载量文章和章节
《科学报告》最新环境科学研究
ACS材料视界
自然科研论文编辑服务
中南大学国家杰青杨华明
剑桥大学-
中国科学院大学化学科学学院
材料化学和生物传感方向博士后招聘
课题组网站
X-MOL
北京大学分子工程苏南研究院
华东师范大学分子机器及功能材料
中山大学化学工程与技术学院
试剂库存
天合科研
down
wechat
bug