当前位置: X-MOL 学术Organometallics › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Synthesis of 4,5-Dihydropyrazoles via Palladium-Catalyzed Cyclization Reactions of β,γ-Unsaturated Hydrazones with Aryl Iodides
Organometallics ( IF 2.8 ) Pub Date : 2019-12-09 , DOI: 10.1021/acs.organomet.9b00656
Rongcai Ding 1 , Rongmei Lu 1 , Zixuan Fang 1 , Yanjun Liu 1 , Shaoyu Wang 1 , Xiaoxia Liang 1 , Cheng Zhang 1 , Tianyi Huang 1 , Jinxing Hu 1
Affiliation  

A novel two-component cyclization toward the synthesis of polysubstituted 4,5-dihydropyrazoles was carried out: i.e., cyclization of β,γ-unsaturated hydrazones with aryl iodides catalyzed by Pd(0). The reaction forms new carbon–carbon bonds and carbon–nitrogen bonds with moderate to good reactivity.

中文翻译:

β,γ-不饱和Hy与芳基碘化物的钯催化环化反应合成4,5-二氢吡唑

对合成多取代的4,5-二氢吡唑类化合物进行了新颖的两组分环化反应:即,Pd(0)催化的β,γ-不饱和hydr与芳基碘化物的环化反应。该反应形成了具有中等至良好反应性的新碳-碳键和碳-氮键。
更新日期:2019-12-11
down
wechat
bug