The synthesis and characterization of the new perfluorinated hypochlorite, undecafluoro-tert-pentyl hypochlorite, (C₂F₅)(F₃C)₂COCl, is reported. Its gas-phase infrared, UV/Vis and NMR spectra have been recorded and its spectroscopic properties are discussed and compared with quantum-chemical predictions and those of other known perfluorinated hypochlorites such as R^FOCl [R^F = F₃C, (F₃C)₃C, (C₂F₅)(F₃C)₂C]. A synthetic route to otherwise difficult to access perfluorinated dialkyl peroxides, R^FOOR^F, is also provided by low-temperature photolysis of the corresponding hypochlorite.

中文翻译：

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从次氯酸盐到全氟化二烷基过氧化物

据报道，新的全氟化次氯酸盐，十氟叔丁基戊基次氯酸盐（C ₂ F ₅）（F ₃ C）₂ COCl的合成和表征。已记录了其气相红外，UV / Vis和NMR光谱，并讨论了其光谱性质，并将其与量子化学预测以及其他已知的全氟化次氯酸盐如R ^F OCl [R ^F = F ₃ C，（F ₃ C）₃ C，（C ₂ F ₅）（F ₃ C）₂C]。相应的次氯酸盐的低温光解也提供了合成途径，以其他方式难以获得的全氟化二烷基过氧化物R ^F OOR ^F。