当前位置: X-MOL 学术Biosci. Biotechol. Biochem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Asymmetric synthesis of trans-p-menth-3-ene-1,2,8-triol, the monoterpene isolated from herbal plants.
Bioscience, Biotechnology, and Biochemistry ( IF 1.6 ) Pub Date : 2019-10-03 , DOI: 10.1080/09168451.2019.1671789
Shunsuke Konishi 1, 2 , Yusuke Ogura 1 , Hirosato Takikawa 1 , Hidenori Watanabe 1
Affiliation  

The monoterpene, trans-p-menth-3-ene-1,2,8-triol, is a naturally occurring alcohol isolated from several herbal plants. In the present work, the asymmetric synthesis of both enantiomers of this natural product was achieved using Sharpless asymmetric dihydroxylation as the key step. A reversal of enantiofacial selectivity was observed in the asymmetric dihydroxylation.

中文翻译:

反式对薄荷脑3烯1,2,8-三醇(从草药植物中分离出来的单萜)的不对称合成。

单萜,反式-对-薄荷脑-3-烯-1,2,8-三醇,是从数种草药植物中分离得到的天然醇。在目前的工作中,使用Sharpless不对称二羟基化作为关键步骤,实现了该天然产物的两种对映异构体的不对称合成。在不对称二羟基化反应中观察到对面选择性的逆转。
更新日期:2019-12-04
down
wechat
bug