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Recent applications of chiral phosphoric acids in palladium catalysis.
Organic & Biomolecular Chemistry ( IF 3.2 ) Pub Date : 2020-01-07 , DOI: 10.1039/c9ob02205h
Van T Tran 1 , Sri Krishna Nimmagadda 1 , Mingyu Liu 1 , Keary M Engle 1
Affiliation  

Through the combined action of palladium catalysts and chiral phosphoric acids (CPAs) a variety of catalytic asymmetric reactions have been realized during the past decade, including allylation, alkene functionalization, and C-H activation. This review surveys key examples across these various reaction types and examines the different mechanisms by which CPAs can affect stereoinduction in these reaction systems.

中文翻译:

手性磷酸在钯催化中的最新应用。

在过去的十年中,通过钯催化剂和手性磷酸(CPA)的共同作用,已经实现了多种催化不对称反应,包括烯丙基化,烯烃官能化和CH活化。这篇综述调查了各种反应类型中的关键实例,并研究了CPA可以影响这些反应系统中立体诱导的不同机制。
更新日期:2020-02-10
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