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Iodine-catalysed N-centered [1,2]-rearrangement of 3-aminoindazoles with anilines: efficient access to 1,2,3-benzotriazines†
Green Chemistry ( IF 9.8 ) Pub Date : 2019-11-29 , DOI: 10.1039/c9gc03567b
Jie Ren 1, 2, 3, 4, 5 , Xinxin Yan 1, 2, 3, 4, 5 , Xiaofan Cui 6, 7, 8, 9 , Chao Pi 1, 2, 3, 4, 5 , Yangjie Wu 1, 2, 3, 4, 5 , Xiuling Cui 1, 2, 3, 4, 5
Affiliation  

A straightforward and synthetically valuable approach for the synthesis of 1,2,3-benzotriazines has been developed via iodine-catalysed N-centered [1,2]-rearrangement of 3-aminoindazoles with anilines. This reaction tolerated a wide scope of substrates under simple reaction conditions employing I2 as a cheap catalyst.

中文翻译:

碘催化3-氨基吲唑与苯胺的N中心[1,2]重排:有效地获得1,2,3-苯并三嗪

通过碘催化的3-氨基吲唑与苯胺的碘催化的N-中心[1,2]重排,已经开发出一种合成1,2,3-苯并三嗪的简单而有价值的合成方法。在使用I 2作为廉价催化剂的简单反应条件下,该反应可耐受多种底物。
更新日期:2020-01-02
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