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Palladium-Catalyzed Oxidative Allylic Alkylation of N-Hydroxy­imides
Synlett ( IF 2 ) Pub Date : 2019-11-29 , DOI: 10.1055/s-0039-1691508
Narasimham Ayyagari , Sunil Kumar Sunnam , Milind M. Ahire , Minxi Yang , Kevin Ngo , Jitendra D. Belani 1
Affiliation  

A palladium-catalyzed oxidative C–H allylic alkylation of N-hydroxyimides has been developed. This transformation provided valuable N-allyloxypyrrolidinediones in moderate to excellent yields using operationally simple, ligand free, and mild reaction conditions. The reaction tolerated broad and variable substituents on allylarenes and N-hydroxyimides.

中文翻译:

N-羟基酰亚胺的钯催化氧化烯丙基烷基化

已开发出钯催化的 N-羟基酰亚胺的氧化 C-H 烯丙基烷基化。这种转化使用操作简单、无配体和温和的反应条件以中等至极好的收率提供有价值的 N-烯丙氧基吡咯烷二酮。该反应耐受烯丙基芳烃和 N-羟基酰亚胺上广泛且可变的取代基。
更新日期:2019-11-29
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