当前位置: X-MOL 学术Commun. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Bioinspired networks consisting of spongy carbon wrapped by graphene sheath for flexible transparent supercapacitors
Communications Chemistry ( IF 5.9 ) Pub Date : 2019-11-29 , DOI: 10.1038/s42004-019-0238-9
Duc Dung Nguyen , Chung-Hsuan Hsiao , Teng-Yu Su , Ping-Yen Hsieh , Yu-Ling Chen , Yu-Lun Chueh , Chi-Young Lee , Nyan-Hwa Tai

Hierarchically ordered structures with low tortuosity, excellent mechanical flexibility, high optical transparency, and outstanding electrical conductivity are critically important in developing flexible transparent supercapacitor electrodes for innovative applications in electronics and displays. Here a CVD process is employed to fabricate leaf-skeleton inspired electrodes, which are reticulated monolithic networks consisting of carbon nanostructures serving as a 3D spongy core and graphene-based films as a protective/conductive shell. The network electrodes show optical transmittance of 85–88%, an electrical sheet resistance of ~1.8 Ω/sq, and an areal capacitance of 7.06 mF cm−2 (at 0.78 mA cm−2 in a three-electrode cell) in Na2SO4 aqueous electrolyte. Flexible transparent and symmetric supercapacitors, based on PVA/H3PO4 gel and the network electrodes, possess a stable working voltage of 1.6 V, energy and power density of 0.068 μWh cm−2 and 47.08 μW cm−2 at an optical transparency of ~80%, and no capacitance loss over 30,000 flat-bend-release cycles.



中文翻译:

生物启发性网络,由海绵状碳包裹,石墨烯护套包裹了这些网络,用于柔性透明超级电容器

具有低曲折度,出色的机械柔韧性,高的光学透明度和出色的导电性的分层结构对于开发用于电子和显示器创新应用的柔性透明超级电容器电极至关重要。在这里,采用CVD工艺来制造叶骨架启发性电极,这些电极是由碳纳米结构(用作3D海绵状芯)和基于石墨烯的膜作为保护性/导电性外壳组成的网状单片网络。网络电极在Na 2中显示出85-88%的透光率,〜1.8Ω/ sq的薄层电阻和7.06 mF cm -2的面电容(在三电极电池中为0.78 mA cm -2)SO 4水性电解质。柔性透明和对称超电容器,基于PVA / H 3 PO 4凝胶和网络电极,具有1.6 V,能量和0.068μWh厘米的功率密度稳定的工作电压-2和47.08μW厘米-2在的光学透明度约80%,在30,000个平坦弯曲释放周期内没有电容损失。

更新日期:2019-11-30
down
wechat
bug