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Selective Degradation of End‐of‐Life Poly(lactide) via Alkali‐Metal‐Halide Catalysis
Advanced Sustainable Systems ( IF 7.1 ) Pub Date : 2019-11-20 , DOI: 10.1002/adsu.201900081
Christoph Alberti 1 , Nicole Damps 1 , Roderich R. R. Meißner 1 , Melanie Hofmann 1 , Desiree Rijono 1 , Stephan Enthaler 1
Affiliation  

The recycling of poly(lactide) (PLA) is studied. Using methanol and alkali‐metal‐halides as catalyst, PLA is degraded to produce methyl lactate, which is a suitable chemical for the regeneration of PLA. An excellent degree of degradation (conversions: >99%, yields: >99%) is achieved in less than 20 min utilizing microwave heating. Remarkably, PLA goods are successfully converted into methyl lactate.

中文翻译:

碱金属卤化物催化选择性降解报废聚丙交酯

研究了聚丙交酯(PLA)的回收利用。使用甲醇和碱金属卤化物作为催化剂,PLA降解生成乳酸甲酯,这是一种适合PLA再生的化学品。利用微波加热,在不到20分钟的时间内即可实现出色的降解度(转化率:> 99%,产率:> 99%)。值得注意的是,PLA产品已成功转化为乳酸甲酯。
更新日期:2020-01-17
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