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Alkenyl boost for Catellani
Nature Chemistry ( IF 21.8 ) Pub Date : 2019-11-18 , DOI: 10.1038/s41557-019-0361-3
Giovanni Maestri , Etienne Derat

The Catellani reaction is a multi-component cascade sequence, catalysed by palladium and norbornene, which typically uses aromatic starting materials. Now, through the use of a modified norbornene co-catalyst, the scope of this reaction has been extended to alkenyl reagents, enabling the preparation of all-carbon tetrasubstituted olefins.

中文翻译:

卡泰拉尼的烯基助推剂

Catellani反应是多组分级联序列,由钯和降冰片烯催化,通常使用芳族原料。现在,通过使用改性的降冰片烯助催化剂,该反应的范围已扩展至烯基试剂,从而能够制备全碳四取代烯烃。
更新日期:2019-11-18
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