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Experimental and modeling study of CO2 absorption by L-Proline promoted potassium carbonate using hollow fiber membrane contactor
International Journal of Greenhouse Gas Control ( IF 3.9 ) Pub Date : 2019-11-16 , DOI: 10.1016/j.ijggc.2019.102877
M. Niknam , P. Zare , P. Keshavarz

Recently, it has been shown that solutions of amino acid salts are suitable absorbents for CO2 separation. Potassium carbonate is an economic solvent; however, it has a slow reaction rate with CO2. In this work, potassium carbonate promoted with l-Proline, as an amino acid, is applied as a CO2 absorbent using a hollow fiber membrane contactor. Experimental results showed that recovery can rise up by adding l-Proline. Effects of parameters such as gas and liquid flow rates and concentration of absorbents on CO2 recovery and CO2 molar flux were investigated. The effect of wetting parameters, CO2 percent in feed gas and temperature on CO2 recovery were investigated by mathematical model. Results show that CO2 recoveries near 100 % can be reached at the l-Proline concentration of 0.1 mol/l, which reveals the potential of this amino acid as promoter of K2CO3.



中文翻译:

中空纤维膜接触器L-脯氨酸促进碳酸钾吸收CO 2的实验与模型研究

最近,已经显示氨基酸盐的溶液是用于CO 2分离的合适吸收剂。碳酸钾是一种经济的溶剂。但是,它与CO 2的反应速率较慢。在这项工作中,使用中空纤维膜接触器将以l-脯氨酸作为氨基酸促进的碳酸钾用作CO 2吸收剂。实验结果表明,通过添加1-脯氨酸可以提高回收率。研究了诸如气体和液体流速以及吸收剂浓度等参数对CO 2回收率和CO 2摩尔通量的影响。润湿参数CO 2的影响通过数学模型研究了进料气中的百分数和温度对CO 2回收率的影响。结果表明,在l-脯氨酸浓度为0.1 mol / l时,CO 2的回收率可达到100%,这表明该氨基酸具有作为K 2 CO 3促进剂的潜力。

更新日期:2019-11-18
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